N_2H~+的非谐性力场与振动光谱常数的计算

质子化氮N_2H~+是星际云中关键的分子离子。在星际云,实验室与理论上已作了很多研究。尤其是,Woods等使用微波技术精确地测定不N_2H~+离子及其同位素离子的转动光谱,得出N_2H~+有效转动常数B_(eff)=46.5867GH_z及其它有关常数。N_2H~+是线型结构,他们分析得到r_(NN)=1.095A,r_(NH)=1.032A。最近,Gudema与Foster分别用3.lum,5um的光,研究了N_2H~+的红外激光光谱,得到振动频率V_1和V_3。然而,N_2H~+的光谱数据,特别是振动光谱十分不全,到目前为止,还没有在实验上测得N_2H(?)的角弯曲振动频率V_2。在理论上,Botschwina使用CEFA方法,也仅计算出N_2H~+的键伸缩的非谐性力场,没有包括N_2H~+的角弯曲力常数,此外,朱正和和俞华根使用大基组6—31G~*及组态     

Multi-physics analysis of the RFQ for Injector Scheme II of C-ADS driver linac

A 162.5 MHz, 2.1 MeV radio frequency quadruples （RFQ） structure is being designed for the Injector Scheme Ⅱ of the China Accelerator Driven Sub-critical System （C-ADS） linac. The RFQ will operate in continuous wave （CW） mode as required. For the CW normal conducting machine, the heat management will be one of the most important issues, since the temperature fluctuation may cause cavity deformation and lead to the resonant frequency shift. Therefore a detailed multi-physics analysis is necessary to ensure that the cavity can stably work at the required power level. The multi-physics analysis process includes RF electromagnetic analysis, thermal analysis, mechanical analysis, and this process will be iterated for several cycles until a satisfactory solution can be found. As one of the widely accepted measures, the cooling water system is used for frequency fine tunning, so the tunning capability of the cooling water system is also studied under different conditions. The results indicate that with the cooling water system, both the temperature rise and the frequency shift can be controlled at an acceptable level.     

五环[5.4.0.02,6.03,10.05,9]十一烷-内-8-醇的合成新方法

五环[5.4.0.02,6.03,10.05,9]十一烷-内-8-醇是合成抗流感病毒医药、抗发炎药物、高能量燃料和燃料添加剂的关键中间体,本研究以环戊二烯和对苯醌为起始原料,经过Diels-Alder、光环化、羰基保护、氢化铝锂还原、水解、黄鸣龙还原等6步反应合成五环[5.4.0.02,6.03,10.05,9]十一烷-内-8-醇,总产率达44.9%.本方法操作简便,分离纯化容易,成本低廉,收率高,为五环[5.4.0.02,6.03,10.05,9]十一烷-内-8-醇的规模化合成奠定了基础.     

Synthesis of the p-keto acids from benzimidazolium iodides and ethyl malonate

The reaction of benzhnidazole methiodide with ethyl malonate in the existence of base was studied,and a new convenient synthetic method of the β-keto acid was provided.     

由硬币自转几周引发的思考

一、实验明辨是非题目有两个大小相同的硬币,其中一个硬币固定不动,另一个硬币在其外侧相切滚动一周,且不发生滑动,则这个滚动的硬币自转几周? (江西省2003年中考样卷试题) 很多同学首次解答这道题时,都认为这个     

一类正值线性过程的参数估计

在研究水质污染问题时,文[1]提出了非负一阶自回归模型:X_t=(?)X_(t-1)+ξ_t,其中{ξ_t}为独立同分布非负随机序列,0<(?)<1.此模型中 X_t 表示在时刻 t 时净化池中的污水量,1-(?)_1表示在单位时间间隔内被净化污水的比例,ξ_t 表示在时刻 t 注入净化池中的污水量.文[1]给出了模型参数的极为简便的强相合估计和相应的模拟结果.文[2]把[1]的结果推广到二阶自回归情形,克服了本质上的困难获得相应的结果.本文提出一类更为广泛的正值线性模型     

一种化学反应快速跟踪实验技术——GC-Ampoule联用技术

一种化学反应快速跟踪实验技术——ＧＣ┐Ａｍｐｏｕｌｅ联用技术蒋毅程极源何展荣（中国科学院成都有机化学研究所６１００４１）在非稳态反应，快速反应和个别自催化反应研究中，要求人们能及时了解体系组成和产物分布的迅速变化，跟踪反应对于认识反应机理也是至关重要...     

Structure and Wettability Engineering of Polycrystalline Diamond Films Treated by Thermally Oxidation,Second Growth and Surface Termination

High-quality polycrystalline diamond films with dominated(100)-oriented grains are realized by combining the thermally oxidation and the homogeneous second growth processes. Moreover, we investigate the wettability property of the polycrystalline diamonds in various stages. Different surface structures(with various grain sizes,voids, and orientations, etc.) and terminations(hydrogen or oxygen) have significant effects on the wettability of polycrystalline diamond films. The wettability is furthe...