Re effects in model Ni-based superalloys investigated with first-principles calculations and atom probe tomography

The phase partition and site preference of Re atoms in a ternary Ni-Al-Re model alloy,including the electronic structure of different Re configurations,are investigated with first-principles calculations and atom probe tomography.The Re distribution of single,nearest neighbor(NN),next-nearest neighbor(NNN),and cluster configurations are respectively designed in the models withγandγphases.The results show that the Re atoms tend to enteringγphase and the Re atoms prefer to occupy the Al sites inγphase.The Re cluster with a combination of NN and NNN Re-Re pair configuration is not preferred than the isolated Re atom in the Ni-based superalloys,and the configuration with isolated Re atom is more preferred in the system.Especially,the electronic states are analyzed and the energetic parameters are calculated.The electronic structure analyses show there exists strong Ni-Re electronic interaction and it is mainly contributed by the d-d hybridization.The characteristic features of the electronic states of the Re doping effects are also given.It is also found that Re atoms prefer the Al sites inγside at the interface.The density of states at or near the Fermi level and the d-d hybridizations of NN Ni-Re are found to be important in the systems.     

超高效液相色谱-串联质谱法测定化妆品中6种生物碱

建立了一种同时测定化妆品中6种生物碱(秋水仙碱、萝芙碱、藜芦定、西伐丁、麦角胺、麦角克碱)的超高效液相色谱-串联质谱分析方法。试样用0.1%甲酸-乙腈混合溶剂超声提取,Cleanert PCX固相萃取柱净化,经Thermo Hypersil GOLD色谱柱分离后在多反应监测模式下检测。结果表明:6种生物碱在0.2~20μg/L范围内线性关系良好(r20.999 0),方法定量下限为2.0~5.3μg/kg,3个加标水平下的平均回收率为83.9%~101.1%,相对标准偏差为0.7%~6.6%。该方法快速准确、灵敏度高,适用于化妆品中生物碱的安全性评价。     

915 nm单频Nd∶YAG晶体衍生光纤激光器

报道了一种基于Nd∶YAG晶体衍生光纤(NYDF)的915 nm单频光纤激光器.使用掺杂原子数分数为2.5％的Nd∶ YAG晶体作为纤芯材料,高纯度石英管作为包层材料,利用熔芯法制备Nd∶ YAG晶体衍生光纤,其传输损耗为8 dB/m,在915 nm处其增益系数为1.16 dB/cm.基于Nd∶YAG晶体衍生光纤,实现了一个稳定的915 nm单频光纤激光器,信噪比大于50 dB.实验结果表明Nd∶ YAG晶体衍生光纤有潜力应用于890～920 nm单频激光器.     

S+C band optical amplification in Er~(3+)-Tm~(3+) co-doped fiber

A new type of optical amplifier based on co-doping erbium in thulium doped fiber is proposed to realize S C band gain by dual-wavelength (800 1410 nm) pumping scheme which is obtainable from laser diode. A novel model is established for the co-doped fiber considering the Er3 to Tm3 energy transfer process. Using appropriate fiber parameters and energy transfer parameters, the coupled rate equations are analyzed and solved; the concentrations of Er3 and Tm3 and fiber length were optimized to get more uniform gain. The results predicted that the S C band gain can be achieved at the same time by co-doping erbium in thulium doped fluoride fiber.     

Ultrafast Photoelectric Effects in Heterojunctions of La0.7Sr0.3MnO3 and Si

Ultrafast photoelectric effects have been observed in p-n heterojunctions of La0.7Sr0.3MnO3(LSMO)/Si and LSMO/SrTiO3_/Si for the first time. The rise time was about 1 ns and the full width at half maximum was about 2ns for the photovoltaic pulse when the heterojunction was irradiated by a laser of -25 ps pulse duration and 1064 nm wavelength. The photovoltaic sensitivity was as large as 435 mV//mJ for a 1064 nm laser pulse. No such pulse was observed with irradiation from a pulsed 10.6 μm CO2 laser.     

对于2002年高考数学第21题的一点思考

原题　 ( )给出两块面积相同的正三角形纸片 ,要求用其中一块剪拼成一个正三棱锥模型 ,另一块拼成一个正三棱柱模型 ,使它们的全面积都与原三角形的面积相等 ,请设计一种剪拼方法 ,分别用虚线标示在图中并作简要说明 .( )试比较你剪拼的正三棱锥与正三棱柱的体积的大小 .( ) (略 )标准答案是一种解法 ,摘要如下 :解　 ( )剪法如图 1、图 2所示图 1　　　　　　图 2( )设给出正三角形的边长为 2 ,则V锥 - V柱 =( 13h锥 - h柱 ) . 34=( 69- 36 ) . 34<0 .所以 V柱 >V锥 .这道题另一种迥然不同的剪法 (如图 3) ,先把正三角形拼成一个长…     

A compact electro-absorption modulator based on graphene photonic crystal fiber

A compact electro-absorption modulator based on graphene photonic crystal fiber is proposed. To enhance the graphene–light interaction efficiency, the innermost six air-holes of photonic crystal fiber are replaced by two large semicircular holes, and monolayer graphene is deposited on the two large semicircular holes. By optimizing the structure parameters, a strong graphene–light interaction is obtained. Moreover, the switch on–off point of the modulator is unchangeable,which is only related to the frequency of the incident light. The influence factors of this composite structure have been analyzed. The proposed modulator is compared with other graphene-based modulators, and the results show that it is filled without dielectric spacer. There are some excellent performances, such as an extinction ratio 7 dB of y-polarization mode,3-dB modulation bandwidth of 70 GHz with small footprint of 205 μm, and a consumption of energy per bit 59 pJ/bit.