Ag修饰氟化二氧化钛的制备及光催化性能研究

以硫酸钛为钛源、氟化氢为氟源、氨水为沉淀剂,通过简单沉淀法制备了氟化二氧化钛(F-TiO2).并用超声的方法将Ag沉积在氟化二氧化钛表面制得Ag沉积的氟化二氧化钛(Ag-F-TiO2).通过场发射扫描电镜(FESEM)、X射线衍射仪(XRD)、比表面积分析仪(BET)、红外光谱仪(IR)、紫外可见吸收光谱(UV-Vis-Abs)、X射线光电子能谱(XPS)分别对样品的表面形貌、晶相组成、比表面积和孔结构、官能团结构、紫外吸收带边、元素组成及化合价态进行了分析.以甲基橙为目标降解物,研究了样品的光催化性能.结果 表明:相同条件下,300 W金卤灯照射40 min,P25、Ag-F-TiO2 、F-TiO2、纯二氧化钛对甲基橙的降解率分别达到98.62;、90.78;、86.95;、68.65;.氟化使二氧化钛比表面积增大,而Ag沉积会减小比表面积.氟化使二氧化钛光吸收带边发生明显的红移,Ag沉积使氟化二氧化钛的光吸收带边发生一定的蓝移.     

CuO掺杂对KNN-LS-BF无铅压电陶瓷性能的影响

采用传统固相合成法和制备工艺,在1040℃制备了{0.996 [0.95( Na0.5 K0.5)NbO3-0.05LiSbO3 ]-0.004FeBiO3}+x mol; CuO(KNN-LS-BF+x mol; CuO)无铅压电陶瓷,研究了CuO掺杂量对陶瓷结构和性能的影响.结果表明,CuO的低温促烧作用明显,微量CuO的掺入并没有改变陶瓷体系的相结构,但对陶瓷的压电和介电性能有明显影响.随CuO掺杂量的增加,陶瓷的d33、kp、εr均是先升高后降低,并在x=0.15时,d33、kp、εr分别达到最大值222 pC/N、0.36、1223.14;Qm也是先升高后降低,不过是在x=0.3时达到了最大值66.02.而tanδ则是先降低,在x=0.45达到最小值2.5;后又开始回升.在x=0.15时,所制备压电陶瓷有最好的综合性能:d33=222pC/N,kp=0.36,εr=1223.14,tanδ=3.3;,Qm =52.27.     

RPC箱型桥墩抗震性能的试验研究与数值分析

以RPC箱型桥墩为研究对象,拟定合理结构形式和尺寸,设计了3个RPC箱型墩试件。通过对试件施加常轴力以及水平反复荷载,研究了水平荷载加载方向角对RPC箱型墩抗震性能的影响,分析了各试件的韧性、滞回曲线、骨架曲线、荷载退化曲线和刚度退化曲线等方面的特征,并得出了各试件的位移延性系数和耗能系数。作者编制并验证了单向荷载作用下的全过程非线性数值分析程序。实验与数值结果表明:RPC箱型墩具有较好的抗震性能,水平荷载加载方向角是影响箱型墩抗震性能的一个重要因素;斜向受力构件的抗震性能要弱于主轴受力构件。     

1∶1内共振悬索的二维奇异性分析

对1∶1内共振悬索系统的二维分岔方程进行了研究．根据奇异性理论得到了3种情况下开折系统的转迁集．转迁集将整个参数空间分成了不同的保持域,得到了各个保持域上的分岔图．     

Singularity analysis of a two-dimensional elastic cable with 1：1 internal resonance

A two-degree-of-freedom bifurcation system for an elastic cable with 1：1 internal resonance is investigated in this paper. The transition set of the system is obtained with the singularity theory for three cases. The whole parametric plane is divided into several different persistent regions by the transition set. The bifurcation diagrams in different persistent regions are obtained.     

Singularity analysis of Duffing-van der Pol system with two bifurcation parameters under multi-frequency excitations

Bifurcation properties of a Duffing-van der Pol system with two parameters under multi-frequency excitations are studied. Three cases are discussed： （1） λ 1 is considered as bifurcation parameter, （2） λ 2 is considered as bifurcation parameter, and （3） λ 1 and λ 2 are both considered as bifurcation parameters. According to the definition of transition sets, the whole parametric space is divided into several different persistent regions by the transition sets for different cases. The bifurcation diagrams in different persistent regions are obtained, which provides a theoretical basis for optimal design of the system.     

异戊烯基取代的黄烷酮衍生物的合成及杀菌活性

异戊烯基溴;异戊烯基取代的黄烷酮衍生物的合成及杀菌活性     

世界各国绿色化学奖介绍

自1991 年美国环保局提出绿色化学这一新术语以来, 绿色化学已逐渐成为世界各国普遍接受和大力实施可持续发展方针的重要组成部分, 引起了化学界和工业界的新变革。     

Numerical solutions of singular integral equations for planar rectangular interfacial crack in three dimensional bimaterials

Stress intensity factors for a three dimensional rectangular interfacial crack were considered using the body force method. In the numerical calculations, unknown body force densities were approximated by the products of the fundamental densities and power series; here the fundamental densities are chosen to express singular stress fields due to an interface crack exactly. The calculation shows that the numerical results are satisfied. The stress intensity factors for a rectangular interface crack were indicated accurately with the varying aspect ratio, and bimaterial parameter.     

Studies on high-moment soft magnetic FeCo/Co thin films

The dependences of soft magnetic properties and microstructures of the sputtered FeCo (=FeFeCo薄膜 溅射条件 软磁性 高饱和磁化强度FeCo film, sputtering conditions, high saturation magnetization, soft magnetic properties2005-10-263/7/2006 12:00:00 AMThe dependences of soft magnetic properties and microstructures of the sputtered FeCo （=Fe65Co35） films on Co underlayer thickness tCo, FeCo thickness tFeCo, substrate temperature Ts and taxget-substrate spacing dT-s are studied. FeCo single layer generally shows a high coercivity with no obvious magnetic anisotropy. Excellent soft magnetic properties with saturation magnetization μ0Ms of 2.35 T and hard axis coercivity Hch of 0.25 kA/m in FeCo films can be achieved by introducing a Co underlayer. It is shown that sandwiching a Co underlayer causes a change in orientation and reduction in grain size from 70 nm to about 10 nm in the FeCo layer. The magnetic softness can be explained by the Hoffmann＇s ripple theory due to the effect of grain size. The magnetic anisotropy can be controlled by changing dT-S, and a maximum of 14.3 kA/m for anisotropic field Hk is obtained with dT-S=18.0 cm.