5-氨基-5,6,7,8-四氢-2(1H)-喹啉酮的简便合成

改进了合成5-氨基-5,6,7,8-四氢-2(1H)喹啉酮(5)的方法。以环己二酮为原料,通过亚胺化,Michael反应-环化反应,成肟反应和碱性条件下镍铝合金催化还原共四步反应合成了5,总收率19.6%,其结构经1HNMR,IR和MS确证。     

低浓缩铀靶辐照后溶液中铀的化学种态及主要裂变元素的影响

利用化学种态分析软件CHEMSPEC计算了低浓缩铀靶辐照后溶液中铀(U)的化学种态分布及其主要裂变元素对U化学种态的影响。结果表明,在单组分体系中,pH值和铀酰浓度都会显著影响U的化学种态分布。随着铀酰浓度的增大,溶液中将会生成多核配合物;在较高的NO₃^-浓度下,U在溶液中主要以UO₂²⁺和UO₂NO³⁺的形式存在。CO₂对不同浓度铀的种态分布影响结果表明,当铀酰浓度较低时,铀的化学种态多以碳酸铀酰的形式存在;当铀酰浓度较高时,铀的化学种态多以氢氧铀酰或柱铀矿沉淀的形式存在。计算发现,当裂片元素Tc、I、Mo的浓度小于0.01mol·L^-1并分别以TcO₄^-、I^-、MoO₄^2-的种态存在时,这些裂片元素不改变铀的各化学种态的分布。     

Reply to Comment on “Permanent Electric Dipole Moment of an Rb Atom”

The result of our experiment on Rb atoms is interesting and surprising .To affirm or to refuse the result should not be by conjectures but by experiments.     

A waveguide polarizer based on Si-coated Ti:LiNbO3 planar structure

A novel design of a transverse magnetic(TM)-pass waveguide polarizer based on Si on an X-cut,Y-propagatiou Ti:LiNbO3 planar waveguide is presented.The eigenvalue functions of such structure havebeen obtained by using Wenzel-Kramers-Brillouin(WKB)method with modified Airy functions.Theintervals of the silicon thickness have been found which result in transverse electric(TE)light sufferingstrong attenuation while TM wave propagating with fairly low loss.A planar waveguide polarizer isfabricated and its polarization-dependent measurements lead to the best polarization extinction ratio～34dB and the insertion loss<0.4 dB.     

再论用逐差法处理实验数据

指出了现行教材引入逐差法存在的问题，再论用逐差法处理实验数据的必要性，并以“拉伸法测钢丝杨氏模量”实验为例。对逐差法的应用进行了分析。     

铯原子永久电偶极矩实验研究

圆柱形电容器中充铯蒸气,测量不同温度下电容量的变化,这变化与铯原子数度成正比。本实验得出铯原子永久电偶极矩edCs>2.4e×10-8cm。     

电弧喷涂铁基非晶涂层的磨粒磨损性能研究

用电弧喷涂技术在Q235钢基体上制备一种高非晶含量的Fe基合金涂层.用MLS-225型湿砂橡胶轮磨损试验机评价铁基复合涂层的磨粒磨损性能,利用光学显微镜、扫描电子显微镜和X射线衍射仪对涂层的显微组织结构、磨损表面进行分析.结果表明,涂层中含有一定量的非晶相,通过Verdon方法对XRD图谱进行Pseudo-Voigt函数拟合,计算得出涂层的非晶相含量约为49%.涂层呈典型的层状组织结构,结构致密,孔隙率低,具有很高的硬度和耐磨性,显微硬度在HV900~1 050范围内,属于硬质涂层.涂层耐磨粒磨损性能为Q235钢的12.2倍.其磨损机制主要为脆性剥落.     

光子统计特性对原子能级AC Stark移动的影响

以相干态单模场和单模热光场引起的原子能级ACStark移动为例,分析了光子统计特性对能级移动规律的影响,能级AC Stark移动中包含了光场统计特性信息,这表明可以通过AC Stark效应研究场的统计性质。     

The experiment on the saturation polarization of Rb vapour

A cylindrical capacitor containing rubidium vapour is made. The capacitance of it at different voltages is measured under a certain Rb vapour pressure. The experimental C－V curve shows that the saturation polarization of Rb vapour is easily observed. The experiment further supports the idea that the Rb atom has a large permanent electric dipole moment.