全文获取类型
收费全文 | 1008篇 |
免费 | 54篇 |
国内免费 | 47篇 |
专业分类
化学 | 833篇 |
晶体学 | 1篇 |
力学 | 19篇 |
数学 | 90篇 |
物理学 | 166篇 |
出版年
2024年 | 11篇 |
2023年 | 28篇 |
2022年 | 41篇 |
2021年 | 29篇 |
2020年 | 18篇 |
2019年 | 11篇 |
2018年 | 13篇 |
2017年 | 6篇 |
2016年 | 14篇 |
2015年 | 10篇 |
2014年 | 16篇 |
2013年 | 19篇 |
2012年 | 48篇 |
2011年 | 52篇 |
2010年 | 47篇 |
2009年 | 46篇 |
2008年 | 75篇 |
2007年 | 84篇 |
2006年 | 114篇 |
2005年 | 54篇 |
2004年 | 24篇 |
2003年 | 27篇 |
2002年 | 34篇 |
2001年 | 63篇 |
2000年 | 37篇 |
1999年 | 56篇 |
1998年 | 47篇 |
1997年 | 8篇 |
1996年 | 3篇 |
1995年 | 14篇 |
1994年 | 6篇 |
1993年 | 16篇 |
1992年 | 7篇 |
1991年 | 14篇 |
1990年 | 5篇 |
1989年 | 1篇 |
1988年 | 5篇 |
1987年 | 3篇 |
1978年 | 2篇 |
1977年 | 1篇 |
排序方式: 共有1109条查询结果,搜索用时 531 毫秒
21.
Shi Liang HUANG Yi LUO Zhi Shu HUANG Xian Zhang BU Pei Qing LIU Lin MA Yue Ming LI Albert S. C. CHAN Lian Quan GU 《中国化学快报》2006,17(6):769-772
Mansonone compounds represent a series of naturally occurring o-quinones mainly isolated from the heartwood of Mansonia Altissima1 and Ulmus Glabra2. Mansonone F contained oxaphenalene skeleton which was a relatively novel structure and rarely existed in … 相似文献
22.
Yao Zu Liao Mei Hua Xin Ming Chun Li Sheng Su College of Materials Science Engineering Huaqiao University Quanzhou China 《中国化学快报》2007,18(2):213-216
O-Lauroyl chitosan/poly(L-lactide) (OCS/PLLA) blend membranes with different compositions were prepared by solution-casting approach using chloroform as common solvent. The experimental results of FT-IR, DSC and WAXD indicated that inter-association hydrogen-bond interactions existed between OCS and PLLA in the blend membranes. And SEM observation confirmed that the blend membranes with suitable compositions were compatible. 相似文献
23.
Mao Xiang Wang Xiang Ming Meng Man Zhou Zhu Qing Xiang Guo 《中国化学快报》2007,18(11):1403-1406
A novel fluorescence enhancement Cu~(2 ) chemosensor derived from coumarin was prepared.Emission study found that it exhibits evident Cu~(2 )-amplified fluorescence prior to Co~(2 ),Pb~(2 ),Mg~(2 ),Mn~(2 ),Ni~(2 ),Zn~(2 ),Fe~(3 ),Ag~ and Cd~(2 ),and the largest emission enhancement factor is about 9 at a ratio of 2:1 (chemosensor 1/Cu~(2 )). 相似文献
24.
Solid-phase methodology has been rapidly and extensively applied to the preparation of small organic molecules recently1. It might be argued that selenoxide syn-elimination provided the principal impetus for the development of organoselenium chemistry. In addition, the required selenoxides are readily available from the oxidation of the corresponding selenides, which in turn can be prepared by the reaction of selenium-stabilized carbanions with various electrophilic substrates2. However, or… 相似文献
25.
Cheng Chu Zeng Li Ming Hu Jia Zeng Ru Gang Zhong College of Life Science & Bioengineering Beijing University of Technology Beijing China 《中国化学快报》2007,18(2):130-132
The anodic oxidation of caffeic acid in the presence of acetylacetone or methyl acetoacetate in aqueous solution has been studied by cyclic voltammetry and controlled-potential electrolysis techniques. The result showed that caffeic acid was oxidized to the corresponding o-benzoquinone, which underwent further Michael-addition with acetylacetone or methyl acetoacetate to produce caffeic acid derivative 3,4-dihydroxy-6-(1-acetylacetone)-yl cinnamic acid 4a or 3,4-dihydroxy-6-(1-acetyl-methylacetate)-yl cinnamic acid 4b. 相似文献
26.
Ming Xian LIU Li Hua GAN Gen CHEN Zi Jie XU Zhi Xian HAO Long Wu CHEN 《中国化学快报》2006,17(8):1085-1088
Recently the research on structures with an ordered two-dimensional(2D) pattern has attracted great attention due to its versatile applications in the fields of microelectronic and optoelectronic devices, displays, biochips and sensors, enzymatic immobilization, drug carriers, and photonic band gap materials. Various well-arrayed 2D structures have been made by the modern technique such as laser writing pattern fabrication, photoetching technique, micro-electromechanical systems based on scann… 相似文献
27.
Synthesis and characterization of new soluble poly(aryl ether nitrile)s containing phthalazinone moiety 总被引:1,自引:0,他引:1
Ming Jing Wang Cheng Liu Li Ming Dong Xi Gao Jian 《中国化学快报》2007,18(5):595-597
A series of novel poly(aryl ether nitrile)s containing phthalazinone moiety were synthesized by the nucleophilic displacement reaction of bisphenol-like monomers (I) with 2,6-difluorobenzonitrile. The inherent viscosities ranged from 0.46 to 1.07 dL g^-1. The glass transition temperatures were in the range of 277-295℃, and the temperatures for 10% weight loss in nitrogen atmosphere were found between 495 and 527 ℃. The structures of these resultant polymers were confirmed by FT-IR and 1^H NMR. Moreover, the properties of poly(aryl ether nitrile)s including solubility and crystallinity were also studied. 相似文献
28.
YU Ming XU Qiang School of Materials Science Engineering East China University of Science Technology Shanghai China 《Chinese Journal of Reactive Polymers》2006,(1)
1. INTRODUCTIONThese years, HCFC-141b may be the most used blowing agent for its useful properties. But, because of its high global warming effect leading to the destruction of the ozone layer, production of HCFC141b has been forbidden. However, there are… 相似文献
29.
A novel molecular probe for identifying properties of supported transitionmetals and metal oxides catalysts was established.The catalytic mechanism oftransition metals was proposed. 相似文献
30.
ULTRASONICALLY DISPERSED POTASSIUM AS DEPROTONATING AND COUPLING AGENT──SYNTHESIS OF 1,6-DINITRILES IN SITUULTRASONICALLYDISP... 相似文献