Negative Thermal Expansion of GaFe(CN)_6 and Effect of Na Insertion by First-Principles Calculations

We study the negative thermal expansion(NTE) properties and effect of Na insertion on the NTE of the framework material GaFe(CN)_6 by first-principles calculations based on density functional theory within the quasi-harmonic approximation. The calculated results show that the material exhibits NTE due to the low transverse vibrational modes of the CN groups. The modes demonstrate larger negative values of the mode Grüneisen parameters. Once Na is introduced in the framework of the material, it prefers to locate at the center of the quadrates of the framework material and binds to the four N anions nearby. As a consequence, the transverse vibrational mode of the CN group is clearly hindered and the NTE of the material is weakened. Our theoretical calculations have clarified the mechanisms of NTE and the effect of the guest Na on the NTE of the framework material.     

极端高温环境下空气源热泵冷热水机组制冷实验研究

针对现有空气源热泵冷热水机组高温环境运行效果差、效率低、排气温度过高导致停机等问题,设计一套基于准双级压缩循环理论,以R410A为制冷剂的中压补气型空气源热泵冷热水机组。在50℃极端环境温度下,采用中压补气技术,对系统的制冷性能进行实验研究。结果表明:(1)系统出水温度由10℃增至15℃时,制冷量增加77.28%,EER提高59.02%,系统的制冷量、功率和EER均随出水温度的升高而增加;(2)相较不补气模式,系统排气温度由111.9℃降至106.23℃,制冷量由14.14 kW增至16.05 kW,可有效降低排气温度,提升制冷量,能更好提高系统超高温制冷时的稳定性。     

带有初应力磁电弹覆盖层的介质中Love波的波速方程

研究了均匀半空间上含有有限厚度的初应力磁电弹覆盖层结构中Love波的波动方程问题.基于初应力下磁电弹材料的运动方程,应力自由的表面条件和连续的界面条件,得到了电磁学开路和短路时Love波的波速方程.结果对新型磁电弹表面波器件的理论研究具有重要的意义.     

Neutron star cooling in various sets of nucleon coupling constants

The influences of nucleon coupling constants on the neutrino scatting and cooling properties of neutron stars are investigated. The results in the GM1, GPS250 and NL-SH parameter sets show that the magnitude of the neutrino emissivity and density ranges where the dUrca process of nucleons is allowed differ obviously between the three parameter sets in nucleon-only and hyperonic matter. Furthermore, the neutron stars in the GPS250 set cool very quickly, whereas those in the NL-SH set cool slowly. The cooling rate of the former can be almost three times more that of the latter. It can be concluded that the stiffer the equation of state, the slower the corresponding neutron stars cool. The hyperon Λ makes neutrino emissivity due to the direct Urca process of nucleons lower compared with nucleon-only matter, and postpones the dUrca process with muons. However, these Λ effects are relatively weaker in the GPS250 set than in the GM1 set.     

苯丙酮尿症新生儿血斑中辅酶及葡萄糖等物质的分析

苯丙酮尿症(PKU)是新生儿先天性苯丙氨酸羟化酶缺陷所引起的苯丙氨酸代谢障碍疾病.本研究采用超高效液相色谱-质谱联用技术, 测定了5例PKU新生儿出生3天和出生30天后的血斑与20例年龄相仿的正常新生儿血斑中辅酶Q10的绝对含量和辅酶Q9的相对含量,其中,健康新生儿血斑中辅酶Q10的含量为(122.1±24.9) ng/mL,PKU新生儿组的含量为(59.0±12.0) ng/mL.采用气相色谱-质谱联用技术测定了胆固醇和葡萄糖的相对含量.研究结果表明,与对照组相比,PKU新生儿血斑中辅酶Q10、Q9、胆固醇和葡萄糖的含量均显著降低,辅酶Q10的降低与血斑中苯丙氨酸含量升高呈现显著反向相关.本研究结果为PKU患儿的饮食治疗方案提供了依据.     

折反式超短焦投影镜头设计

针对国内外市场对近距离、大屏幕投影系统中需降低投影镜头加工难度及成本的要求,该文设计了一款超短焦投影镜头。设计过程中选用折反式结构,利用物、像关系原理,结合物方视场计算反射镜面型参数,得出反射镜面型。该方法便于校正大视场畸变、抵消折射镜组的像散和场曲,整个光学系统包括15片球面透镜和一片非球面反射镜,系统总长286 mm,投影距离500 mm,投射画面尺寸254 cm(100英寸),系统投射比0.22,相对照度大于85%,MTF(modulation transfer function)在0.4 lp/mm时大于0.5,水平TV畸变小于0.55%,垂直TV畸变小于0.65%。该系统的多项设计指标均优于市面上现有的产品指标,采用同轴球面设计易于加工、装调,可有效降低生产成本。     

Entropy Corrections to Three-Dimensional Black Holes and de Sitter Spaces

It has been shown that non-rotating black holes Recently study showed that thermal fluctuations would give in three or four dimensions possess a canonical entropy. rise to logarithmic corrections to Bekenstein Hawking entropy in area with a model-dependent uncertain coefficient. In this paper, the thermal fluctuations on Bekenstein-Hawking entropy in three-dimensional AdS black holes, Schwarzschild-de Sitter space and Kerr-de Sitter （KdS） spacetime with J = 0 will be considered based on a uniformly spaced area spectrum approach. Our conclusion shows that there is the same correction form in all cases we considered.     

火控性能参数静态测试系统

为提高武器火控静态性能指标的测试精度,设计了火控性能参数静态测试系统,用于对火炮炮身松动量、过渡过程品质、刚性、漂移速度及最大调炮速度等参数进行测试。通过相对测试的方法,运用光学测量头拍摄炮口在坐标靶上的相对运动图像,计算出相关参数。采用弹性胀套的连接方式,实现了静态测量头的可靠安装及方便拆卸。结果表明:在-30℃～+50℃环境温度下,光学系统的MTF值可达0.6以上,接近系统的衍射极限;当2=9.15,f＝50 mm时,静态测角精度0.2 mil。安装夹具适应100 mm、105 mm、125 mm火炮的固联安装,测试系统可对某型坦克炮管的相关指标进行实测,也可广泛应用于高炮、装甲车辆、舰载火控系统、坦克等多种武器装备。     

新型有序介孔磺酸化酚醛树脂FDU-16-SO3H的合成与酸催化性能

通过氯磺酸磺化有序介孔酚醛树脂(FDU-16)制备了新型有序介孔固体酸催化剂FDU-16-SO₃H. X射线衍射(XRD)、氮气吸附以及透射电镜(TEM)等表征结果表明, 经过磺化后的固体酸催化剂依然保持了高度有序性, 大量的磺酸根基团存在于材料的骨架之中. 在酯化反应和酰基化反应中, 这种新型有序介孔固体酸催化剂表现出比工业树脂和磺酸化介孔二氧化硅等材料更高的催化活性, 这主要归因于它具有较大的比表面积、较强的酸性以及骨架的疏水性.     

基于主成分和支持向量机浓度参量同步荧光光谱油种鉴别

基于浓度参量同步荧光光谱技术,对不同溢油类型不同油源原油样品集、引入外扰相似油源样品集进行光谱数据采集,获取其浓度同步荧光光谱矩阵Concentration-Synchronous-Matrix-Fluorescence(CSMF),利用主成分分析方法对两套不同层次的原油相关样品集进行了多类分类识别。结果表明:主成分载荷图可以很好地反映各个原油相关样品在油源上的相似程度,结合支持向量机可以实现不同溢油类型及不同油源原油的准确分类,对于引入风化和海水外扰相似油源溢油样品集,两类分类区分的结果远远高于多类分类识别的结果。通过详细的主成分分析讨论,为溢油油种鉴别提供了一种利用多类分类识别,逐步缩减嫌疑样本数量,最后通过两两分类实现溢油样品准确识别的新思路。