贵金属元素电分析化学研究(Ⅳ)——纯Pt中微量Pd的阳极溶出伏安法测定

本文研究了在玻炭电极上用阳极溶出伏安法测定纯铂中微量钯的方法。发现事先从酸性介质中以Pd-丁二肟络合物萃取后,最适宜测定Pd~(2+)的电解质体系为:0.15mol/L H_2SO_4-0.25mol/LNaNO_3-4.9×10~7mol/L Tt~(3+)(pH=1.2)。本法结果与比色法相近。回收率在96—101％,5次测定结果的变异系数为1.96％。     

Thermal Stability and Humidity Resistance of ScTaO4 Modified （K0.5Na0.5）NbO3 Ceramics

Lead-free （Na0.5K0.5）NbO3-xmol% ScTaO4 （x=0-1.5） ceramics are prepared using the conventional solid-state reaction method and their properties are investigated in detail. The results indicate that the piezoelectric properties and density are improved by the introduction of ScTaO4. Due to the high orthorhombic-tetragonal phase transition temperature TO-T （around 200°C）, stable piezoelectric properties against temperature are obtained. In a wide temperature range of 15-160°C, kp of the （Na0.5K0.5）NbO3-0.5mol% ScTaO4 ceramic remains almost unchanged and d31 increases slightly from 59pC/N to 71pC/N. The deliquescent problem is effectively solved by the addition of ScTaO4. The piezoelectric properties of ScTaO4 modified （Na0.5K0.5）NbO3 ceramics show no obvious reduction and dielectric loss increases slightly after 120h of immersion. From the analysis, it is suggested that the density is an important factor that improves the humidity resistance of the specimens.     

铅于旋转银盘电极上欠电位沉积的计时库仑法研究

用计时库仑法研究了Ｐｂ２＋于旋转Ａｇ盘电极（Ａｇ－ＲＤＥ）上的欠电位沉积（ＵＰＤ）性质。实验证明,支持电解质（０．０１ｍｏｌ／Ｌ　ＨＮＯ３＋０．０１　ｍｏｌ／Ｌ ＮａＣＩ）中Ｃｌ－离子的存在有利于取得稳态条件下ＵＰＤ Ｐｂ的电量值。其氧化过程电量（Ｑａ）,代表Ｐｂ２＋吸附单层被定量转化为ＵＰＤ Ｐｂ单层的量,Ｑａ的平均值为３９３．３μＣ／ｃｍ２,相应于２×１０－９ｍｏｌ／ｃｍ２Ｐｂ２＋表面复盖量。     

弹簧系统振动周期的近似公式

通过变量转换导出一个精度较高、应用范围较大的弹簧系统振动周期的近似公式.     

立足本科生实际实事求是地进行创新教育改革

针对本科生在创新动力、创新基础、现有实验室环境、创新教育方法方面的实际情况,制定了有一定特色、操作性较强的高年级学生创新性教学改革措施,出台了以学生自主创新项目申请、教学指导委员会评审立项、统一实验室管理、三阶段滚动资助的办法。     

贵金属元素电分析化学研究Ⅹ Ⅵ铱(Ⅳ)-半胱氨酸络合物催化极谱氢波的研究

本文研究了Ir(Ⅳ)-半胱氨酸(Cys)-HCl体系的催化极谱氢波的反应机理,证明Ir(Ⅳ)与Cys形成的络合物可催化氢在电极上放电,并提出了测定实际样品的方法。     

Ag活化的p型硅(111)表面化学镀Ag膜表面形貌研究

A method of electroless silver deposition on silver activated p-type silicon（111） wafer was proposed. The silver seed layer was deposited firstly on the wafer in the solution of 0.005 mol/L AgNO3 ＋0.06 mol/L HE Then the silver film was electrolessly deposited on the seed layer in the electroless bath of AgNO3＋NH3＋acetic acid＋NH2NH2 （pH 10.2）. The morphology of the seed layer and the silver films prepared under the condition of the different bath composition was compared by atomic force microscopy. The reflectance of the silver films with different thickness was characterized by Fourier transform infrared spectrometry. The experimental results indicate that the seed layer possesses excellent catalytic activity toward electroless silver deposition and rotating of the silicon wafer during the electroless silver deposition could lead to formation of the smoother silver film.     

蔗糖辅助制备大比表面积氧化铝

The preparation of alumina with large surface area, certain phase and porosimetry has always been one of important researches. A new method using much less sucrose (the molar ratio of sucrose to Al^3 =0.5) was developed to prepare γ-Al2O3 with large surface area and high thermal stability. Firstly, ammonium hydroxide was dropped to aqueous solution of aluminum nitrate and sucrose. The resulted precipitate in suspension washeated until a homogeneous gel was ohtained. Then the gel was dehydrated at 110℃ to get a fluffy black precursor. Finally, γ-Al2O3 with A=345m^2/g was prepared by calcining the preeursor at 600℃ for 24h. The precursor and the obtained γ-Al2O3 were characterized by DTA-TG, N2 adsorption-desorption isotherms, XRD and TEM, According to the dispersion behaviors of organic compounds on supports, the related mechanism was discussed.     

低压电子水处理方法的阻垢特性

通过静态和动态两种方法对低压电子阻垢性能进行了实验研究.在静态实验中选用了不同波形的电压信号进行实验,结果表明,阻垢效果最好的为恒压直流,其后依次是三角波、正弦波、方波.恒压直流的动态实验结果表明,增大处理电流,污垢热阻降低,阻垢率增大.低压电子阻垢方法通过电化学反应使成垢离子减少以产生阻垢效果.     

甘肃当归新品系DGA2000-02的选育研究

当归新品系DGA2000 02是采用重离子束55 MeV/u 40Ar+15 离子辐照甘肃当归90 01干种子, 按新品种选育程序多年选育而成的。 2005—2007年, 在定西市岷县、 渭源县、 漳县、 陇西县等地当归品系区域试验中, 甘肃当归DGA2000 02平均产鲜当归10 621.5 kg/hm2, 较对照品种（甘肃当归90 01）平均增产鲜当归1 386.0 kg/hm2, 增产率15.0%。 生育期790 d, 茎秆深紫色, 根系黄白色。 测定结果: 总灰分4.2%, 酸不溶性灰分0.4%, 分别优于对照品种16%和33.3%; 浸出物61.4%, 较规定指标提高4.4%; 阿魏酸0.148%, 较规定指标提高2.96倍。 质量显著优于对照品种和2005年版《中国药典》规定指标。 适宜在海拔2 000—2 600 m 、 年降水量500—600 mm的二阴及高寒阴湿生态区栽培。 Angelica sinensis（Oliv）Diels new strain DGA2000 02 was selected successfully by Institute of Modern Physics, Chinese Academy of Sciences, Dryland Farming Research and Extension Center of Dingxi Prefecture, etc. According to the program of new strain selection, this new strain was selected for several years after the dry seeds of Gansu Angelica sinensis（Oliv）Diels 90 01 was irradiated by ions of 55 MeV/u 40Ar+15. During the period of year 2005—2007, region experiments of Angelica sinensis（Oliv）Diels new strain DGA2000 02 were developed in Minxian, Weiyuan, Zhangxian and Longxi etc. Average yield of the fresh DGA2000 02 Angelica was 10 621.5 kg/hm2, and 15.0% production was increased more than control (for 1 386.0 kg/hm2 of 90 01).The growth stage of the DGA2000 02 was 790 d, and it has deep purple stem and yellow white root. The quality analysis results are as follows: total ash content is 4.2% and acid fast ash content is 0.4%, 16% and 33.3% better than control, respectively; the lixivium is 61.4%, i.e., 4.4% more than the standard of Pharmacopoeia of People’s Republic of China (2005 edition); the ferulic acid content is 0.148%, i.e., 2.96 times ligher than the standard. All these results showed that the quality of the DGA2000 02 was better significantly than both control and the standard. It can be grown appropriately at the high, cold and dankness regions at the altitude of 2 000—2 600 m and with a annual precipitation of 500—600 mm.