全文获取类型
收费全文 | 187篇 |
免费 | 89篇 |
国内免费 | 60篇 |
专业分类
化学 | 121篇 |
晶体学 | 17篇 |
力学 | 5篇 |
综合类 | 2篇 |
数学 | 10篇 |
物理学 | 181篇 |
出版年
2023年 | 5篇 |
2022年 | 10篇 |
2021年 | 8篇 |
2020年 | 6篇 |
2019年 | 14篇 |
2018年 | 12篇 |
2017年 | 8篇 |
2016年 | 9篇 |
2015年 | 14篇 |
2014年 | 21篇 |
2013年 | 20篇 |
2012年 | 17篇 |
2011年 | 26篇 |
2010年 | 11篇 |
2009年 | 21篇 |
2008年 | 11篇 |
2007年 | 11篇 |
2006年 | 22篇 |
2005年 | 12篇 |
2004年 | 17篇 |
2003年 | 15篇 |
2002年 | 11篇 |
2001年 | 8篇 |
2000年 | 4篇 |
1999年 | 1篇 |
1998年 | 2篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 4篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1987年 | 1篇 |
1985年 | 2篇 |
1960年 | 1篇 |
排序方式: 共有336条查询结果,搜索用时 15 毫秒
81.
82.
83.
Generation of self-oscillations from a singly resonant periodically poled potassium titanyl phosphate crystal frequency doubler
下载免费PDF全文
![点击此处可从《中国物理 B》网站下载免费的PDF全文](/ch/ext_images/free.gif)
We report on the generation of self-oscillations from a continuously pumped singly resonant frequency doubler based on a periodically poled potassium titanyl phosphate crystal (PPKTP). The sustained square-wave and staircase curve of self-oscillations are obtained when the incident pump powers are below and above the threshold of subharmonic-pumped parametric oscillation (SPO), respectively. The self-oscillations can be explained by the competition between the phase shifts induced by cascading nonlinearity and thermal effect, and the influence of fundamental nonlinear phase shift by the generation of SPO. The simulation results are in good agreement with the experiment data. 相似文献
84.
85.
Amorphous silicon oxide containing nanocrystalline silicon grain(nc-SiO_x:H) films are prepared by a plasmaenhanced chemical vapor deposition technique at different negative substrate bias voltages.The influence of the bias voltage applied to the substrate on the microstructure is investigated.The analysis of x-ray diffraction spectra evidences the in situ growth of nanocrystalline Si.The grain size can be well controlled by varying the substrate bias voltage,and the largest size is obtained at 60 V.Fourier transform infrared spectra studies on the microstructure evolutions of the nc-SiO_x:H films suggest that the absorption peak intensities,which are related to the defect densities,can be well controlled.It can be attributed to the fact that the negative bias voltage provides a useful way to change the energies of the particles in the deposition process,which can provide sufficient driving force for the diffusion and movement for the species on the growing surface and effectively passivate the dangling bonds.Also the larger grain size and lower band gap,which will result in better photosensitivity,can also be obtained with a moderate substrate bias voltage of 60 V. 相似文献
86.
本文用十六烷基三甲基溴化铵(CTAB)作为试剂,通过软模板法合成介孔二氧化硅,利用在合成过程中,由伪莫尔转动所引起的微粒内部的大量缺陷,通过溶剂抽提,形成了具有空腔结构的介孔二氧化硅纳米微球.采用透射电子显微镜(TEM)、X射线粉末衍射仪(XRD)、N2吸附-脱附等手段对产物的形貌和结构进行了详细的表征.并以溴甲酚绿作为目标物,通过改变压强和温度,调节溴甲酚绿进入空心SiO2微球中的不同部位,对所制备的空腔介孔二氧化硅微球进行染料的装载和释放试验.结果显示该微球腔壁具有可渗透性和缓释性,而且在负压蒸发溶剂的情况下可以得到较高的药物负载量和极大地提高缓释性能. 相似文献
87.
The mechanism of photosensitized decomposition of benzoyl peroxide by several anthracene derivatives has been studied. It comfirms that the photosensitized process is carried out by electron transfer.It is discovered that benzoyl peroxide can be decomposed by sensitizer of different anthracene derivatives which are used either electron donor or acceptor and the active radical which produces in this reaction can initiate the polymerization of MMA. It is considered that the BPO with positive charge in the charge transfer complex is easier to decompose into radical than that with negative charge,so the rate (Rp) of polymerzation of MMA in-itiated by the system of DCA/BPO has higher value than others. 相似文献
88.
采用预处理-瞬态反应产物分析方法定量研究了Co-ZSM-5催化剂上乙烯选择性催化还原氮氧化物反应过程中表面中间物种的组成. 催化剂在275 ℃经0.1%NO-0.05%C2H4-10%O2/Ar混合气处理后生成了表面中间物种NCaObHc, 该物种与NO/O2/Ar混合气反应比与单独的NO或O2反应生成更多的N2. 通过质谱、红外吸收四组分
(CO2, CO, CH4和N2O)分析仪及气相色谱-质谱联用等技术分析了表面中间物种与NO/O2/Ar混合气反应的产物,确定了表面中间物种中三种元素N, C和H的平均原子数之比为1.0∶1.8∶5.0 (氧物种由于实验原因很难确定). 相似文献
89.
90.
插层聚合制备聚丙烯/蒙脱土纳米复合材料及其结构性能表征 总被引:32,自引:0,他引:32
将插层聚合的概念引入烯烃聚合,制备了聚丙烯/蒙脱土(PP/MMT)纳米复合材料。X射线衍射和TEM分析结果表明,蒙脱土在聚丙烯基体中达到了纳米级的分散,动态力学性能研究结果表明,在高于Tg的温度区域内PP/MMT纳米复合材料的储能模量(E′)成倍增加,加入8%的蒙脱土(MMT),PP/MMT的E′提高近3倍。PP/MMT的玻璃化转变温度Tg有一定程度的提高,随蒙脱土含量的增加,PP/MMT的热分解温度和热变形温度(HDT)都有大幅度提高。 相似文献