钨钼钒硅杂多酸盐的合成

Keggin结构的杂多酸及其盐已广泛地应用于催化、比色分析、生化等领域,因此新型杂多酸,特别是高电荷、易还原的含钒混合齿顶杂多酸,及其盐的合成和性质的研究就成了引人注目的课题。含两种齿顶原子的杂多酸已见报道,含杂原子为硅的三种齿顶原子的杂多酸及其盐尚未见报道。本文报道了两个新的三种齿顶原子的杂多酸TBA盐(四丁基铵盐),其     

选择题试编

选择题作为一种新颖的试题形式,目前在国内外已普遍采用,这类试题能较好地考查学生的思维能力。现行中学数学教材,这类习题极其欠缺,为了使学生能适应这种试题,我在教学过程中,根据教学内容,给学生平时练习中出现的错误,编拟了一些选择题给学生练习,现抄录一部分供同行们参考。     

Painlev property of the modified C-KdV equation and its exact solutions

In this paper,the Painlev’e properties of the modified C-KdV equation are verified by using the W-K algorithm.Then some exact soliton solutions are obtained by applying the standard truncated expansion method and the nonstandard truncated expansion method with the help of Maple software,respectively.     

多线性Marcinkiewicz积分在Campanato空间上的存在性与有界性

设n≥2, m≥1,y=(y1,..., ym).μ(f)是如下定义的多线性Marcinkiewicz积分:μ(f)(x)=(∫∞01/tm∫(B(0,t))~m?(y)|y|m(n-1)m∏i=1f_i(x-y_i)|2dt/t)~(1/2),其中dy=dy1···dym.本文考虑了μ(f)在Campanato空间上的存在性与有界性,证明了若m-线性Marcinkiewicz积分μ(f)在一点处有限,则它几乎处处有限,而且,如下范数不等式成立:||μ(f)||Eα,p≤C m∏j=1||fj||Eαj,pj,其中E~(α,p)是经典的Campanato空间,1/p=1/_p1+···+1/p_m,α=α_1+···+α_m.     

Cross-section measurement for Ni（n,x）^58（m＋g）Co, Ni（n, x）^60mCo, Ni（n,x）^61Co and Ni（n,x）^62mCo reactions induced by neutrons around 14 MeV

The cross sections of Ni(n,x)~(58(m g))Co,Ni(n,x)~(60m)Co,Ni(n,x)~(61)Co and Ni(n,x)~(62m)Co reactions induced by neutrons around 14 MeV were measured in this work and calculated by a previously developed formula in this work.The neutron flux was determined using the monitor reaction ~(27)Al(n,α)~(24)Na and the neutron energies were measured with the method of cross-section ratios for ~(90)Zr(n,2n)~(89)Zr to ~(93)Nb(n,2n)~(92m)Nb reactions.     

5,10,15-三(五氟苯基)Corrole及其相似卟啉化合物的光物理特性

采用稳态和时间分辨的瞬态光谱技术对比研究了一种Corrole化合物5,10,15-三(五氟苯基)Corrole(FtsTPC)和一种卟啉化合物5,10,15,20-四(五氟苯基)卟啉(F20TPP)的光物理特性.结果表明:F15TPC的B带吸收峰较宽而F20TPP的强而窄,F15TPC的Q带有两个吸收峰而F20TPP有四个.F15TPC的荧光量子产率为0.15,荧光寿命为4.8 ns,F20TPP的荧光量子产率为0.05,荧光寿命为11.1 ns;与F20TPP相比F15TPC具有发光效率高、荧光寿命短的特点.F15TPC具有较大的发光速率常数和无辐射跃迁速率常数,这可能是由于F15TPC少了一个氟代苯基,致使其发色团本身的电子结构发生变化所致.另外空间结构的不对称性和非共面性也对其光物理性质有影响.     

有机材料(EDT-DSDTFVO)FeCl_4和(EDT-DSDTFVO)GaCl_4的输送现象

通过对有机材料(EDT-DSDTFVO)2FeCl4和(EDT-DSDTFVO)2GaCl4的输送测定,对其电阻率的温度依赖性以及压力效果进行了系统的比较,虽然两类盐的电阻率随着温度的变化行为十分相似,但是其压力效果尤其在高压时表现出明显的差异性。认为这种差异性和π-d相互作用密切相关。在这里,用EDT-DSDTFVO表示ethylenedithiodiselenadithiafulvalenothioquinone-1,3-dithiole methide。     

Construction and application of an electrochemical sensor based on graphene-MXene nanocomposites for baicalin detectionEI北大核心CSCD

Redox graphene-MXene(rGO-MXene) nanocomposites were prepared by ion polymerization and used to construct a highly sensitive electrochemical sensor for baicalin(BA) detection. The synergistic effect of rGO and MXene increased the specific surface area and electron transport capacity of the electrode, and significantly enhanced the electrochemical response of BA. The cyclic voltammetry and differential pulse voltammetry were used to investigate the electrochemical behavior of BA on the sensor. Under the optimal conditions, the peak current exhibited a good linear relationship with BA concentration in the range of 0. 05-10 μmol / L, and the limit of detection was as low as 28 nmol / L. The method was applied to analyze traditional Chinese medicine preparations containing baicalin, such as Qingkailing Capsule and Sanhuang Tablets with good accuracy and spiked recovery. The results were highly consistent with those of high performance liquid chromatography, providing a technical means for the rapid and sensitive detection of traditional Chinese medicine preparations. © 2022, Youke Publishing Co.,Ltd. All rights reserved.     

带新熵函数的Entropy-Ultra-bee格式计算线性传输方程

本文研究了线性传输方程的数值解法.利用物理的熵函数得到了一种新的Entropy-Ultrabee格式.数值实验表明该格式长时间计算效果非常好,在间断附近有比较高的分辨率.     

Blumlein传输线的解析分析

 在传输线应用中,负载终端匹配设计是一个重要问题。用拉普拉斯变换方法严格求解Blumlein传输线的电报方程,研究在纯电阻负载和带分布参数负载情况下,波在传输线中的瞬态传输过程,得到了清晰的物理图像,结果与通常的行波传播分析法完全一致。