吗啡和海洛因等生物碱的高效液相色谱化学发光测定

研究了吗啡、可待因、Ｏ＾３单乙酰吗啡和海洛因等生物碱在多聚磷酸介质中与高锰酸钾的发光行为和光谱现象。建立了反相 高效液相色谱化学发光检测吸毒者尿液和雅片中吗啡、可待因等物质的方法。     

In0.49Ga0.51P中缺陷的俘获行为

利用深能级瞬态谱（ＤＬＴＳ）和瞬态光电阻率谱（ＴＰＲＳ）研究了利用金属有机物化学汽相沉淀（ＭＯＣＶＤ）生长的未有意掺杂的Ｉｎ０．４９Ｇａ０．５１Ｐ中缺陷对载流子的俘获过程和发射过程．利用ＤＬＴＳ测量观测到了一个激活能为０．３７ｅＶ的缺陷,该缺陷的俘获势垒值介于１８０ｍｅＶ到２４０ｍｅＶ之间．该缺陷的俘获势垒值的大的分布被解释为缺陷周围原子重组的微观波动．在研究中发现研究这些缺陷的俘获过程比发射过程更有效,俘获势垒为０．０６ｅＶ和０．４０ｅＶ的两个缺陷在俘获过程中被观测到,而在发射过程中并没有观测到     

基于二维材料异质结的光探测器研究进展

二维材料异质结因其特有的层状结构和优异的光响应性质,被认为具有应用于新一代光探测器件的潜力.二维材料家族具有丰富的种类,因其能带带隙范围分布广,光电响应可覆盖从紫外到红外的波谱范围.另外二维材料层间通过范德瓦尔斯力相结合,因此理论上可以利用不同二维材料层间的范德瓦尔斯力相互作用制备出多种性能优异的二维材料异质结.近年来有多种二维材料异质结通过机械堆叠法及CVD生长法被制备出来,且二维材料异质结光探测器在可见光至远红外波段表现出优异的性质.在这样的研究背景之下,本文从二维材料异质结的制备、器件制备与器件性能等几个方面综述了近年来二维材料异质结光探测器的研究进展.     

1.55 μm低温生长GaAs谐振腔增强型探测器

利用低温（200℃）生长的GaAs材料作为吸收层制备了GaAs基1.55 μm谐振腔增强型（RCE） 光电探测器,对其光电特性进行了分析、研究.无光照0偏压下探测器暗电流为8.0×10－12A;光电流谱峰值波长1563 nm;响应谱线半宽4 nm, 具有良好的波长选择性.     

Difference scheme for two-phase flow

A numerical method for two-phase flow with hydrodynamics behavior was considered. The nonconservative hyperbolic governing equations proposed by Saurel and Gallout were adopted. Dissipative effects were neglected but they could be included in the model without major difficulties. Based on the opinion proposed by Abgrall that “a two phase system, uniform in velocity and pressure at t = 0 will be uniform on the same variable during its temporal evolution“, a simple accurate and fully Eulerian numerical method was presented for the simulation of multiphase compressible flows in hydrodynamic regime. The numerical method relies on Godunov-typescheme, with HLLC and Lax-Friedrichs type approximate Riemann solvers for the resolution of conservation equations, and nonconservative equation. Speed relaxation and pressure relaxation processes were introduced to account for the interaction between the phases. Test problem was presented in one space dimension which illustrated that our scheme is accurate, stable and oscillation free.     

Effect of Chemicals on Chemical Mechanical Polishing of Glass Substrates

We investigate the effect of chemicals on chemical mechanical polishing （CMP） of glass substrates. Ceria slurry in an ultra-low concentration of 0.25 wt. % is used and characterized by scanning electron microscopy. Three typical molecules, i.e. acetic acid, citric acid and sodium acrylic polymer, are adopted to investigate the effect on CMP performance in terms of material removal rate （MRR） and surface quality. The addition of sodium acrylic polymer shows the highest MRR as well as the best surface by atomic force microscopy after CMP, while the addition of citric acid shows the worst performance. These results reveal a mechanism that a long-chain molecule without any branches rather than small molecules and common molecules with ramose abundant-electron groups is better for the dispersion of the slurry and thus better for the CMP process.     

图形衬底量子线生长制备与荧光特性研究

报道了在V型槽图形衬底上利用分子束外延技术外延生长的GaAs/AlGaAs量子线.外延截面在扫描电子显微镜下可以看到在V型槽底部形成了弯月型量子线结构,量子线尺寸约为底边60 nm高14 nm的近三角形.低温87 K下光致发光谱测试在793.7和799.5 nm处出现峰值,验证了量子线的存在.理论近似计算结果显示,相比等宽度量子阱有8 meV的蓝移正是由于横向量子限制引起的. 关键词： V型槽图形衬底 量子线 GaAs     

GaSb-based type-I quantum well cascade diode lasers emitting at nearly 2-μm wavelength with digitally grown AlGaAsSb gradient layers

We report a GaSb-based type-I quantum well cascade diode laser emitting at nearly 2-μm wavelength. The recycling of carriers is realized by the gradient AlGaAsSb barrier and chirped GaSb/AlSb/InAs electron injector. The growth of quaternary digital alloy with a gradually changed composition by short-period superlattices is introduced in detail in this paper. And the quantum well cascade laser with 100-μm-wide, 2-mm-long ridge generates an about continuous-wave output of 0.8 W at room temperature. The characteristic temperature T₀ is estimated at above 60 K.     

An effective reflectance method for designing broadband antireflection films coupled with solar cells

The solar spectrum covers a broad wavelength range, which requires that antireflection coating (ARC) is effective over a relatively wide wavelength range for more incident light coming into the cell. In this paper, we present two methods to measure the composite reflection of SiO₂/ZnS double-layer ARC in the wavelength ranges of 300-870 nm (dual-junction) and 300-1850 nm (triple-junction), under the solar spectrum AM0. In order to give sufficient consideration to the ARC coupled with the window layer and the dispersion effect of the refractive index of each layer, we use multi-dimensional matrix data for reliable simulation. A comparison between the results obtained from the weighted-average reflectance (WAR) method commonly used and that from the effective-average reflectance (EAR) method introduced here shows that the optimized ARC through minimizing the effective-average reflectance is convenient and available.