微量pH电位滴定测定氨基酸、二肽和三肽与锌(Ⅱ)、镉(Ⅱ)配合物的稳定常数

His、Gly-His、Ala-His、Gly-Gly和Gly-Gly-Gly与锌、镉的配合物的稳定常数已有报道,由于不同作者的实验方法和数据处理方法不同,测定结果也不尽一致.有些数据是用手算方法进行数据处理的,求得的稳定常数可能不够精确.本工作采用文献推荐的微量pH电位滴定技术,对上述配体与Zn(Ⅱ)、Cd(Ⅱ)配合物稳定常数进行了测定.     

Synthesis of Dimethyl Carbonate from CO2 , Methanol, and Epoxides Using Re（CO） 5 Cl/K2 CO3 as Catalyst System

IntroductionOver the past few years, dimethyl carbonate(DMC) has been proven to be an efficientmethylating,methoxylating, and methoxycarbonylating agent inorganic syntheses, in which DMC is used to replace thetoxic methyl halides, dimethyl sulfate or carb     

A facile and convenient synthesis of novel imidazo[1,2-b] isoxazoles and their Mannich bases as potential biodynamic agents

A series of novel imidazo[1,2-b]isoxazoles 3 and their Mannich bases 4–6 were synthesized via convenient reactions. The reaction of 3-aminoisoxazole 1 with substituted phenacyl bromides 2 in dry ethanol afforded the corresponding 6-methyl-3-aryl imidazo[1,2-b]isoxazoles 3 in good yields.Compounds 3 on treatment with 37% formaline and secondary amines furnished the corresponding novel Mannich bases viz., 6-methyl-3-aryl-2-(morpholine/pyrrolidin-1-yl/piperidin-1-yl)-methyl-imidazo[1,2-b]isoxazoles 4–6.     

Single-Proton Pickup Reaction of the Halo Nucleus ^6He on a ^9Be Target at 25 MeV/nucleon

The inclusive differential cross sections of the ^7 Li nucleus in a reaction induced by ^6He on a ^9Be target are measured at an incident energy of 25 MeV/nucleon. Finite-range distorted-wave Born approximation calculations suggest that these ^7 Li particles are formed in a direct single-proton pickup reaction ^9Be（^6He,^7 Li）^8Li. The experimental data can be well reproduced by taking into account of the contributions of both the ground states and the first excited states of ^7Li and ^8Li.     

一题多解一例

题以直角三角形ABC的弦AB为边,在直角顶点另侧做正方形ABDE,设BC=a,AC=b,AB=c.试求直角顶点C到正方形中心的距离. 解法1(利用正弦定理)设Q是所作正方形的中心(图1),则∠AQB=90°,于是A、C、B、Q四点共圆,即Q在△ABC的外接圆周上.AB是这外接圆的直径.对△AQC,应用正弦定理有:     

State-space approach to two-temperature generalized thermoelasticity without energy dissipation of medium subjected to moving heat source

In this work,a model of two-temperature generalized thermoelasticity without energy dissipation for an elastic half-space with constant elastic parameters is constructed.The Laplace transform and state-space techniques are used to obtain the general solution for any set of boundary conditions.The general solutions are applied to a specific problem of a half-space subjected to a moving heat source with a constant velocity.The inverse Laplace transforms are computed numerically,and the comparisons are shown in figures to estimate the effects of the heat source velocity and the two-temperature parameter.     

Numerical study on scanning radiation acoustic field in formations generated from a borehole

The directivity of acoustic transducers used in conventional acoustic logging tools is uncontrollable[1,2], which inevitably affects investigation depth and resolution. At present, deep and wide range of investigation in petroleum exploration is urgently re- quired. It is important to improve the exploration capability to find more complex and fine reservoirs[3], for which the direction of the radiated acoustic energy is a direct factor. Acoustic field in the formations generated by the source…     

179Au的1/2[660](πi13/2)转动带

利用能量为164—180MeV的³⁵Cl束流,通过重离子核反应¹⁴⁹Sm(³⁵Cl,5n)研究了¹⁷⁹Au的高自旋态能级结构.实验进行了γ射线的激发函数、X-γ和γ-γ-t符合测量.基于对实验测量结果的分析,首次建立了¹⁷⁹Au的1/2[660](πi_13/2)转动带.结合已有的实验数据,着重讨论了奇AAu核中1/2[660](πi_13/2)转动带的带头激发能随中子数的变化     

δ掺杂的赝形高电子迁移率晶体管AIGaAs/InGaAs/GaAs结构中的费密边奇异性研究

报道了δ掺杂赝形高电子迁移率晶体管结构Al_(0.30)Ga_(0.70)As/In_(0.15)Ga_(0.85)As/GaAs的光致发光光谱研究的实验结果,除了观察到n=1电子子带到n=1重空穴子带,n=2电子子带到n=1重空穴子带间的强发光峰,还观察到了n=1电子子带到n=1轻空穴子带的弱发光峰,通过变化掺杂浓度来改变费密能级的位置,在这种δ掺杂的HEMTs系统中观察到了费密边奇异性,并把它归结为费密海与费密边附近未占据的第二电子子带之间的近共振散射作用所致。     

大气重力波产生中纬电离层不均匀体的理论

研究中纬电高层Ｆ区大尺度不均匀休的基本性质及其与大气重力波的关系。分析了等离子体Ｐｅｒｋｉｎｓ不稳定性的非线性发展，发现这种不稳定性饱和在很小的幅度上。讨论了Ｐｅｒｋｉｎｓ不稳定性与重力波的耦合，表明重力波能触发中纬电离层Ｆ区等离子体不稳定性。由重力波触发的等离子体不稳定性可能演变成大幅度的波形结构，空间和时间调制的不均匀体理论揭示了大尺度中纬电离层不均匀体的产生机制。 关键词：