修饰LB膜法制备的PEDOT薄膜对HCl气体气敏性的影响

以二十烷酸(AA)LB膜为模板, 通过3,4-乙烯二氧噻吩(EDOT)单体在LB膜亲水基团间聚合, 采用垂直拉膜方式在叉指电极上制备了不同层数的AA/PEDOT膜, 并对HCl气体在AA/PEDOT复合LB膜中的作用进行研究, 结果表明, 膜厚、处理温度、拉膜膜压对AA/PEDOT复合LB膜的HCl气体敏感性能有不同程度的影响. 在较小气体体积分数范围(20～60 μL/L)内, AA/PEDOT多层有序膜对气体表现出非线性响应特性, 而在较高浓度范围内则表现出线性响应特性. AA/PEDOT复合LB膜对30 μL/L HCl气体的响应时间约为20 s, 远快于普通PEDOT旋涂膜(约为80 s), 同时在膜压达到45 mN/m时, AA/PEDOT膜的敏感性能反而下降. 敏感机理解释为电子在PEDOT共轭系统和氧化性气体间的转移.     

b→cτ■ decay in supersymmetry with R-parity violation

In past years,several hints of lepton flavor universality(LFU)violation have emerged from the b→ct■,and b→sl~+l-data.More recently,the Belle Collaboration has reported the first measurement of the D* longitudinal polarization fraction in the B→D*τV decay.Motivated by this intriguing result,along with the recent measurements of RJ/Ψand τ polarization,we present the study of b→ct■ decays in supersymmetry(SUSY)with R-parity violation(RPV).We consider B→D(*)t■,Bc→ηct■,Bc→J/ψt■ and ∧b→∧ct■ modes and focus on the branching ratios,LFU ratios,forward-backward asymmetries,polarizations of daughter hadrons,and the τ lepton.The RPV SUSY was capable of explaining the RD(*) anomalies at the 2σ level,after taking into account various flavor constraints.In the allowed parameter space,the differential branching fractions and LFU ratios are largely enhanced by the SUSY effects,especially in the large dilepton invariant mass region.Moreover,a lower bound B(B~+→K~+vv)7.37×10~(-6) is obtained.These observables could provide testable signatures at the high-luminosity LHC and SuperKEKB,and correlate with direct searches for SUSY.     

基于取代型多酸复合材料的多巴胺电化学检测

本文构建了基于取代型多酸与还原氧化石墨烯（RGO）复合材料的多巴胺电化学传感器. 首先,通过水热法合成了十一钨镍杂多钨硅酸盐K₂H₂SiW₁₁NiO₃₉·xH₂O（SiW₁₁Ni）,利用Hummers法与化学还原法合成了还原氧化石墨烯. 并使用SEM、XRD与FTIR等测试方法对材料进行了表征. 将SiW₁₁Ni与RGO按照一定的比例滴涂在玻碳电极表面,以便成功构建出传感界面（SiW₁₁Ni-RGO/GCE）. 然后,采用电化学阻抗法与循环伏安法等方法研究了传感界面的电化学性质. 优化实验条件后,利用该传感器通过循环伏安法对多巴胺进行定量检测,并且氧化过程展现出较为良好的性能. 其检出限为3.2 μmol·L ^-1（S/N = 3）,灵敏度为9.71 μA·(μmol·L ^-1·cm ^-2) ^-1,线性范围为10 ~ 80 μmol·L ^-1. 同时,所制备的传感器表现出良好的稳定性与抗干扰能力. 该传感器修饰过程简单、成本低、电化学性能良好,为多酸在化学传感领域的应用提供新思路.     

Distinctive distribution of defects in CdZnTe:In ingots and their effects on the photoelectric properties

Photoelectric properties of CdZnTe:In samples with distinctive defect distributions are investigated using various techniques. Samples cut from the head(T04) and tail(W02) regions of a crystal ingot show distinct differences in Te inclusion distribution. Obvious difference is not observed in Fourier transform infrared(FTIR) spectra, UV–Vis–NIR transmittance spectra, and Ⅰ–Ⅴ measurements. However, carrier mobility of the tip sample is higher than that of the tail according to the laser beam induced current(LBIC) measurements. Low temperature photoluminescence(PL) measurement presents sharp emission peaks of D~0 X and A~0 X, and relatively large peak of D~0 X(or A~0 X)/D_(complexfor) T04, indicating a better crystalline quality. Thermally stimulated current(TSC) spectrum shows higher density of shallow point defects, i.e.,Cd vacancies, In_(Cd)~+, etc., in W02 sample, which could be responsible for the deterioration of electron mobility.     

Mode couplings of a semiconductor nanowire scanning across a photonic crystal nanocavity

The position-dependent mode couplings between a semiconductor nanowire(NW) and a planar photonic crystal(PPC) nanocavity are studied. By scanning an NW across a PPC nanocavity along the hexagonal lattice's Γ– M and M – K directions, the variations of resonant wavelengths, quality factors, and mode volumes in both fundamental and second-order resonant modes are calculated, implying optimal configurations for strong mode-NW couplings and light-NW interactions. For the fundamental(second-order) resonant mode, scanning an NW along the M – K(Γ– M) direction is preferred, which supports stronger light-NW interactions with larger NW-position tolerances and higher quality factors simultaneously. The simulation results are confirmed experimentally with good agreements.     

Evidence for Magnetic Fractional Excitations in a Kitaev Quantum-Spin-Liquid Candidate α-RuCl3

It is known that α-Ru Cl₃ has been studied extensively because of its proximity to the Kitaev quantum-spin-liquid（QSL） phase and the possibility of approaching it by tuning the competing interactions. Here we present the first polarized inelastic neutron scattering study on α-Ru Cl₃ single crystals to explore the scattering continuum around the Γ point at the Brillouin zone center, which was hypothesized to be resulting from the Kitaev QSL state but without concrete evidenc...     

基于迈克尔逊干涉仪的光纤微流速传感器

设计了一种基于迈克尔逊干涉仪的光纤微流速传感器。传感器由单模光纤、双芯光纤、小球、高反膜构成。通过数值计算分析了双芯光纤长度、纤芯间距、小球半径和流体密度对传感器敏感度的影响。仿真结果表明,光纤长度和小球半径的减小均能提高传感器的敏感度,而双芯光纤的纤芯间距对敏感度的影响较小;流体密度越大,传感器的敏感度越小。计算结果显示,传感器可以在较小尺寸的情况下实现超高灵敏度的流速测量。同时,对不同设计参数下传感器输出的自由光谱范围进行理论推导与数值计算,发现传感器各个参数与自由光谱范围成1/x或1/x~(1.5)的关系。     

三维拓扑磁振子在真实材料体系中的实现

正将"拓扑"这一数学概念引入物理学后,一方面推动了基础物理学研究的发展,另外一方面也促使了大量新颖拓扑量子材料的出现,例如石墨烯[1]、拓扑绝缘体[2]、三维狄拉克半金属以及外尔半金属[3]等,极大地丰富了材料科学,为低耗散、更稳定的下一代电子器件的发展奠定了材料基础。在这类拓扑材料中,系统的对称性在拓扑电子能带的形成中发挥着极为重要的作用。例如在石墨烯或者三维的狄拉克半金属材料中,系统受到空间     

CO_2在Fe_3O_4(111)表面的吸附结构及能量研究（英文）

利用密度泛函理论研究了CO_2在Fe_3O_4(111)表面Fe_(tet1)和Fe_(oct2)两种终结的吸附行为。在Fe_(tet1)终结表面,当覆盖度为1/5 ML时,CO_2倾向于线性吸附;而在高覆盖度下,弯曲的CO_2与表面O作用形成CO_3~(2-)结构。在Fe_(oct2)终结表面,CO_2倾向于弯曲吸附,在1/6 ML和1/3 ML覆盖度时都可以形成CO_3~(2-)和-COO结构。覆盖度对Fe_(tet1)终结的表面影响很弱,但是对Fe_(oct2)终结的表面影响很大。从热力学上来说,CO_2在Fe_(oct2)终结表面的吸附要比Fe_(tet1)终结表面更有利。     

修饰Langmuir-Blodget膜法制备聚(3,4-亚乙基二氧噻吩)薄膜结构和导电性能的研究

采用修饰Langmuir-Blodget(LB)膜法以二十烷酸(AA)LB膜为模板,通过3,4-亚乙基二氧噻吩(EDOT)单体在LB膜亲水基团间聚合,制备了二十烷酸/聚(3,4-亚乙基二氧噻吩)(AA/PEDOT)复合LB膜.UV-Vis、FTIR和XPS分析表明EDOT在多层膜中有效聚合,生成了PEDOT导电聚合物;X射线衍射(XRD)和二次离子质谱(SIMS)分析表明薄膜具有较好的层状有序结构,进一步研究发现EDOT在AA多层膜中的聚合破坏了原有LB膜的有序性,这可能与聚合过程对层状结构产生的破坏作用有关;采用四探针仪及半导体测试仪研究了薄膜导电性能,发现AA/PEDOT多层膜的电导率随处理时间的变化产生突变,这与多层膜中导电通道的"逾渗"有关,在有效导电网络连通后电导率发生了突变.测试结果还表明AA层和PEDOT层之间具有较为明显的界面,PEDOT显示出较好的定域性,薄膜具有很好的层状有序结构.