共沉淀法制备铝酸镧超微粉末的研究

用尿素-氨水在热水溶液中调pH共沉淀制备铝酸镧超微粉末。研究了氨水浓度、尿素浓度和尿素-氨水滴加速度对超微粉末颗粒的影响和焙烧温度对超微粉末颗粒微观变化的作用。在选定的条件下,制备成粒径为0.1～0.7μm、比表面93～112m~2/g的铝酸镧超微粉末。     

NaLn（WO4）2晶体的研究（Ln=La,Pr,Nd）

用助熔剂缓冷法从Na_2WO_4—LiCl熔体中生长出NaLn(WO_4)_2(Ln=La,Pr,Nd)晶体。化学组成分析证明了所得晶体是NaLa(WO_4)_2、NaPr(WO_4)_2和NaNd(WO_4)_2。测定表明该类晶体属白钨矿型结构,四方晶系,空间群I4_1/a。计算了它们的晶胞参数,发现随着稀土元素(La、Pr、Nd)原子序数的增加,Ln~(3+)离子半径减小,Ln—O键长呈规律地递减,NaLn(WO_4)_2晶体的晶胞体积减小。测定了晶体的红外光谱和NaPr(WO_4)_2的激发光谱和荧光光谱。     

密闭溶样两次金汞齐冷原子吸收光谱法测定煤中微量汞

建立了密闭溶样两次金汞齐冷原子吸收光谱法测定煤样中微量汞的方法，该法具有试剂空白低的特点，适合于测定煤样中的微量汞。研究表明，该法最低检出限为２５×１０－９，精密度为７３％，回收率平均为９９８１％。     

Synthesis of Novel Amphiphilic Poly （ester-amine） Dendrimers and Their Recognition of Hg2＋ at the Air／Water Interface

Two novel amphiphilic poly(ester-amine)dendrimers were synthesized and characterized by 1H NMR,13C NMR and IR spectra.Their properties of Langmuir film were investigated at the air/water interface.The relationship between the surface pressure and area isotherms of the dendrimers was found to be dependent on the nature of subphases,Interaction between HgCl2 and the dendrimers was observed,indicating that the amphiphilic dendrimers could act as a sensor for Hg^2 .     

高精度的非相对论与完全相对论密度泛函理论计算方法和程序

介绍非相对论与完全相对论密度泛函理论计算方法和相应的计算程序（ＮＲ／Ｒ－ＤＦＴ）的结构和功能。本程序是目前用密度泛函理论方法计算完全相对论总能量能达到最高精度的程序。利用本程序可以高精度地计算含重元素体系的总能量、分子轨道能级、原子化能、键合能、偶极矩，分析化学键性质等。     

一题多解

今天做一道题目,虽然不太难,但仔细钻研下去,竟获得很多种解法,这令我很兴奋.于是写下一时的感受,一一介绍这些解法.     

水平刻槽管壁面液体升膜非线性特性研究

水平刻槽管壁面升膜流动是一种低雷诺数流,低雷诺数流动的特点是惯性力与粘性力相比可以忽略不计,因此在求解Navier-Stokes方程时,常忽略对流项进行计算.本文通过采用一种级数解法,对含有对流项的Navier-Stokes方程进行逐级求解,分析不同雷诺数下含对流项的Navier-Stokes方程对速度解的影响.     

平稳环境中马氏链的不可约性

给出若单链X^→具π-不可约性，则环境空间中的平稳分布π-是遍历的．同时也指出在单链叉的状态空间有限的前提下，该单链是强常返的，从而推广了经典马氏链相应的结论．     

Behavior of an Extended Dislocation near an Elliptical Blunt Crack

The behavior of an extended dislocation near an elliptical blunt crack is investigated. The equilibrium separation between Shockley partials and the critical value of stacking fault energy for the formation of extended dislocations by dissociation reaction as well as the extended dislocation emission criterion are developed. The results show that the equilibrium separation increases as the extended dislocation tends to the blunt crack. If the stacking fault energy is comparable to the critical energy for dissociation in a perfect medium, complete dislocations can dissociate to form extended dislocations near the blunt crack. The critical stress intensity factor （SIF） for extended dislocation emission increases with the stacking fault energy and the curvature radius of the blunt crack tip. Moreover, the critical SIF for extended dislocation emission is far lower than the critical SIF for edge dislocation emission.