Cartan型李超代数H的导子代数

In this paper,the derivation algebra of Lie superalgebra H of Cartan-type over F are determined by the calculating method in the situations of CharF = p≥ 3 or m ≥ 2 or n≥1.The main result is following:DerFH=adH(H" Fh)⊕<{adDi)pt|i=1,2,…,m,t=1,2,…,ti-1}>.     

Synthesis,Crystal Structure and Norbornene Polymerization of a Palladium(Ⅱ) Complex Based on Phenoxyimine Ligand

The title complex N,O-bis{2-[[(2,6-benzhydryl-4-methylphenyl)imino]-methyl]-phenol}-palladium(II)(C_(80)H_(64)N_2O_2 Pd) has been synthesized by the reaction of 2-[[(2,6-benzhydryl-4-methylphenyl)imino]-methyl]-phenol with Pd(CH_3COO)_2, and characterized by IR spectrum and elemental analysis. The spatial structure of the complex has been verified by single-crystal X-ray diffraction analysis. The compound belongs to the monoclinic system, space group P21/n with a = 13.492(3), b = 16.924(3), c = 14.135(3) ?, β = 97.84(3)°, V = 3197.4(11) ?~3, C_(80)H_(64)N_2O_2 Pd, Mr = 1191.73, Z = 2, Dc = 1.238 Mg/m~3, μ = 0.339 mm~(-1), F(000) = 1240, T = 293(2) K, the final R = 0.0593 and wR = 0.1192(I 2s(I)). The compound showed excellent catalytic activity up to 1.130 × 10~7 g of PNB(mol of Pd)~(-1)h~(-1) for the addition polymerization of norbornene by using methylaluminoxane(MAO) as a cocatalyst.     

分数阶不确定多混沌系统的自适应滑模同步

研究分数阶不确定多混沌系统的自适应滑模同步,通过构造滑模面,设计控制器和适应规则,能够满足滑模面的稳定性与到达性,进而得到分数阶不确定多混沌系统取得自适应滑模同步的充分性条件,研究表明:分数阶不确定多混沌系统满足在一定条件下能够取得自适应滑模同步.     

Improvement in the Stability of Gabapentin by the Complexation of Gabapentin with Different Metal Ions: a DFT Study

Gabapentin undergoes intramolecular cyclization by alkylamine nucleophilic attacking on carboxylate carbonyl. And the above self-dehydration condensation can produce gabapentin lactam which has some toxic effects. Therefore, in order to decrease the above subsidiary reaction, the effects of several metal ions on the reaction mechanism and the potential barriers of self-dehydration condensation of gabapentin are analyzed. Each molecular structure of gabapentin in the presence of several metal ions is optimized using the density functional theory(DFT) with B3LYP method at the 6-311+G(d,p) basis set level. And its geometric and thermodynamic parameters are also investigated. The calculated results showed that gabapentin can form stable complexes with divalent metal ions and exhibit the highest affinity for small and highly charged metal cations. The binding ability of these metal ions with gabapentin ranks in an order of Fe~(2+) Zn~(2+) Mg~(2+) Ca~(2+) Na~+ K~+. Besides, the potential barriers of subsidiary reaction of gabapentin increase obviously in the presence of several metal ions than that of free gabapentin. This means that the above metal ions can inhibit effectively the intramolecular cyclization of gabapentin.     

碘阴离子桥联的金属镍大环二聚体[(NiL)_2I](I_3)_3

利用 Ni II- I- Ni II联接单元合成并表征了四氮大环镍 (II)配合物二聚体 [(Ni L) 2 I](I3) 3,这里 L=5 ,7,7,1 2 ,1 4,1 4-六甲基 - 1 ,4,8,1 1 -四氮杂环十四 - 4 ,1 1 -二烯。 X射线晶体结构及光谱数据显示 [(Ni L) 2 I](I3) 3是三明治结构 ,对称中心为碘离子 ,两个大环配合物平面相互平行 ,整个组装体的对称性为 D4d。结构数据还表明使 Ni II- I- Ni II单元起稳定作用的主要是碘离子与金属离子间的静电作用 ,还有较弱的共价相互作用。在这种二聚体中 ,金属离子不仅作为大环配合物的中心原子 ,而且在 Ni II- I- Ni II单元中还作为碘阴离子的受体。 [(Ni L ) 2 I](I3) 3的变温紫外可见吸收光谱表明其分解温度约为 375 K。因为这种四氮大环金属配合物二聚体含碘离子一价及三价碘阴离子 ,故有可能在将太阳能转变为电能的光电化学电池中作为电解质而获得应用。     

发酵纤维素阴离子衍生物的转化与抗菌应用评价

在水相条件下用阴离子醚化剂（3-氯-2-羟基丙磺酸钠）通过一锅法对经微生物改造的纤维素阴离子化，其中的氢氧化钠溶液既作为反应物、溶剂，又作为催化剂，反应条件温和、取代度适中、转化率较高。采用元素分析、核磁共振、傅里叶红外光谱等表征方法研究了纤维素衍生物的取代度和结构，结果表明，获得的纤维素产物已阴离子化。对纤维素衍生物进行了抑制真菌评估，证明其具其有一定的抑菌特性。纤维素衍生物的生态亲和性决定其可应用于文物保护、农业和防疫等领域。     

精致概念抽象过程 提升数学抽象素养——以“函数的单调性”教学为例

数学概念课堂教学过程中,应通过精心设置的问题,努力揭示数学概念的本质,利用师生课堂有效对话,适当地拉长概念的抽象过程,使概念的抽象过程更加精细、更加精致,在概念精致的过程中让学生深刻体会概念的抽象过程,从而使得数学抽象素养得以提升,本文以“函数的单调性”教学为例进行说明.     

解析几何教学要注重对学生进行“算法”的引导

<正>最新的课程标准指出,要通过高中数学课程的学习,进一步发展学生的数学运算能力.数学运算不仅包括理解运算对象,掌握运算法则,还包括探究运算思路,选择运算方法.^[1]学生在解析几何的学习中,往往会形成一种理解上的误区,他们片面地认为解析几何就是繁琐运算的代名词,这导致学生在解决问题时思路单一,通过解析几何的学习,反而禁锢了他们的思维,浪费了解析几何所承载的特有育人功能.其实解析几何是一块连通知识内在关系、活跃学生思维、培养学生运算能力的沃土,通过解析几何的教学,我们不仅要培养学生的计算能力,更要培养他们选择“算法”的能力,通过对学生进行“算法”的引导,从更高的维度上来提升学生的数学运算素养.     

一道竞赛决赛题的多种解法

对第39届全国中学生物理竞赛决赛理论考试试题第1题的第1问,分别采用力平衡与力矩平衡法,抛物线准线特征求极值法以及三力汇交原理,给出了3种不同于原参考解答的解决方案.     

Studies of an LL-type 500 MHz 5-cell superconducting cavity at SINAP

A low loss- (LL) type 500 MHz 5-cell superconducting niobium prototype cavity with a large beam aperture has been developed successfully including the optimization, the deep drawing and electron beam welding, the surface treatment and the vertical testing. The performance of the fundamental mode was optimized and the higher order modes were damped by adopting an enlarged beam pipe for propagation. Surface preparation or treatment including mechanical polishing, buffered chemical polishing and high pressure rinsing with ultra-pure water and so on was carried out carefully to ensure a perfect inner surface condition. The vertical testing results show that the accelerating voltage higher than 7.5 MV was obtained while the quality factor was better than 1× 10⁹ at 4.2 K. No obvious multipacting or field emission was found during the test. However, a quench happened while increasing the field a little higher than 7.5 MV that at present limited the cavity performance.