过渡金属催化的炔烃芳构化反应

综述了过渡金属催化的炔烃环三聚芳构化反应的历史沿革及最新研究进展，并 重点对含有不同电性取代基的炔烃环三聚反应、几种典型的催化体系和作用机理、 该领域的一些前沿热点作了评述．     

N－取代硫代磷酰胺二乙酯合成新方法的研究

以ＰＥＧ作相转移催化剂，在无机碱（Ｋ＿２ＣＯ＿３或Ｎａ＿２ＣＯ＿３）存在下，用乙基氯化物（Ｏ，Ｏ－二乙基硫代磷酰氯）与不同的胺反应，合成了六种Ｎ－取代硫代磷酰胺二乙酯，其结构经ＩＲ、ＮＭＲ和元素分析证实。     

代铬刷镀层的耐腐蚀机理的考察

对新型的代铬刷镀层Ni-Fe-W-P-S进行了耐腐蚀性能机理的分析研究。用扫描电镜(SEM)、透射电镜(TEM)、扫描隧道显微镜(STM)、X射线衍射及电子能谱(XPS)等的分析表明，基体组织为非品结构是代铬刷镀层优异耐腐蚀性的主要原因.     

化学发光法测定硫代膦酸酯农药的研究

采用传统的银离子催化法可将硫赶膦酸酯类化合物转化成氟膦酸酯类化合物。由于银离子的干扰,不能用高灵敏的化学发光法检测产物。作者考虑到上述原因,经反复试验,提出对含基团三类化合物实施高汞离子催化转化,然后用DTPA螯合剂掩蔽汞离子,消除汞离子对测定的严重正干扰,可定量测定上述三类化合物,标准曲线的相关系数在0.9970-0.9996之间,测定步骤也很简单。     

DFT Study on the Structure of Ionic Liquid 1-Ethyl-3-methylimidazolium Hexafluorophosphate

1 INTRODUCTION Ionic compounds generally have high melting points and always exist in solid state since they are main- tained by electrovalent bonds. Ionic Liquids (ILs), which are liquids at or near ambient temperature, have been a class of ionic compounds extensively studied experimentally and theoretically in recent years[1, 2]. ILs consist exclusively of anions and ca- tions and do not contain any neutral molecule. They have many attractive properties, such as low vapor pressure, no…     

5,7′-(亚甲胺基)-二-8-羟基喹啉的合成及其理论研究

以4-甲基苯磺酸作催化剂、用三乙胺调节pH值约为9的条件下, 由5-甲酰基-8-羟基喹啉和5-氨基-8-羟基喹啉合成了新的5,7′-(亚甲胺基)-二-8-羟基喹啉, 利用IR, UV, ¹H NMR, MS确认了分子结构, 比较研究了其光致发光特性, 运用Gaussian 98量子化学程序包, 采用B3LYP密度泛函(DFT)的方法, 在6-31G(d,p)水平上对分子的几何构型进行结构优化; 并对目标化合物的稳定结构通过计算预测其振动光谱, 计算结果与实验值基本相符.     

KINETICS OF NON-ISOTHERMAL CRYSTALLIZATION OF POLY (ETHYLENE TEREPHTHALATE) MODIFIED BY POLY (ETHYLENE GLYCOL)

The non-isothermal crystallization kinetics of poly(ethylene terephthalate) (PET) modified by poly (ethlene glycol) (PEG) were determined by DSC. The dual linear regression method was used to evaluate the relationship between the reciprocal of t 1/2 ( the half life of crystallization) and the appropriate temperature variable. The parameters such as the activation energy (Ed) for transport, the equilibrium melting temperature (T_m~0),the nucleation parameter (ψ),themaximum crystallization temperature (T_(e, max)), and the kinetic crystallizability (G) for the copolyesters were obtained. The influence of the PEG content in PET chains on the parameters characterizing crystallization kinetics and crystallization thermodynamics was discussed.     

Imidazole Coordinated Sandwich-type Antimony Polyoxotungstates Na9[ {Na（H=O2}3{M（C3H4N2）}3（ Sb W9O33）2]·xH=O（M=Ni^Ⅱ, Co^Ⅱ, Zn^Ⅱ, Mn^Ⅱ）

The imidazole covalently coordinated sandwich-type heteropolymngstates Na9[ {Na（H=O2}3{M（C3H4N2）}3（ Sb W9O33）2]·xH=O（M=Ni^Ⅱ, Co^Ⅱ, Zn^Ⅱ, Mn^Ⅱ） were obtained by the reaction of Na2WO4·2H2O, SbCl3·6H2O, NiCl2·6H2O [MnSO4·H2O, Co（NO3）2·6H2O, ZnSO4·7H2O] and imidazole at pH≈7.5. The structure of Na9[{Na（H2O）2}3{Ni（C3H4N2）}3（SbW9O33）2]·32H2O was determined by single crystal X-ray diffraction. Polyanion [{Na（H2O）2}3{Ni（C3H4N2）}3（SbW9O33）2}3]^9- has approximate C3v symmetry, imidazole coordinated six-nuclear duster [{Na（H2O）2}3{Ni（C3H4N2）}3]^9＋ is encapsulated between two （α-SbW9O33）^9-, the three rings of imidazole in the polyanion are perpendicular to the horizontal plane formed by six metals （Na-Ni-Na-Ni-Na-Ni） in the central belt, and x-stacking interactions exist between imidazoles of neighboring polyanions with dihedral angel of 60%. The compounds were also characterized by IR, UV-Vis spectra, TG and DSC, and the thermal decomposition mechanism of the four compounds was suggested by TG curves.     

硼掺杂还原态氧化石墨烯催化剂的制备及其蒽催化加氢性能的研究

制备了一系列硼掺杂的还原氧化态石墨烯催化剂并应用于蒽加氢反应。结果表明，随着催化剂处理温度的升高，催化剂中有序碳结构会发生变化，硼会取代材料骨架中的碳，进而影响蒽和氢气的吸附活化。经硼改性后，催化剂对蒽加氢反应表现出了很高的加氢活性，蒽的最高转化率可达97%，深度加氢产物八氢蒽的最高选择性可达19%。     

应用中药材开发微量元素保健品

介绍了用中药村开发几种微量元素保健品，有补锌，有助小儿生长，补硒抗癌，补铁钴养血，补铬治糖尿病和补锌铅的肝病滋补保健品。