BiVO4膜电极的制备及其光电化学性能

以自制的BiVO4纳米粉制备膜电极, 采用电化学方法较系统地研究了退火温度和膜厚对BiVO4膜电极的光电化学行为和电子输运与复合的影响. 结果表明: 退火温度和膜厚对BiVO4膜电极的光电特性有显著的影响. 膜厚为6.75 μm时, BiVO4膜电极具有最佳的光电化学特性. 退火温度低于500 °C时, 膜电极的光电活性随着温度的升高而增强, 至500 °C时达到最大值; 此后膜电极内的体相缺陷明显增加, 导致其光电活性逐渐降低. BiVO4膜电极有良好的可见光光电转换效率, 并利用其单色光转换效率曲线计算得到BiVO4的带隙为2.36eV, 采用莫特-肖特基电化学法测得其平带电位为-0.7 V (vs Ag/AgCl). 上述结果为BiVO4光催化体系的优化提供了重要的参考.     

蓝宝石单晶纳米压痕蠕变性能研究

蓝宝石单晶的蠕变性能对结构失效行为有很大的影响.本文采用纳米压痕测试方法对蓝宝石单晶窗口材料的蠕变性能进行了测试与分析.分析表明,纳米压痕测试方法能够较为精确地测得蓝宝石单晶蠕变应力指数;不同的最大载荷对蓝宝石单晶的蠕变位移及蠕变应力指数没有明显的影响;蓝宝石单晶的蠕变位移及蠕变应力指数随着加载速率的减小分别减小和增大.     

多功能超声造影剂

与其他成像方法相比,超声成像具有成像效果好、实时成像、操作简便、无放射性污染、价格相对低廉、适用面广以及适用于床旁等诸多无法比拟的优点,因此是目前临床上应用最为广泛的成像诊断手段之一。临床上使用超声造影剂可以提高疾病诊断的准确性,但是,超声成像自身的缺点如灵敏度相对较低等使其在对癌症等重大疾病进行诊断时存在一定的局限性。将超声成像与其他成像模式联合使用则可实现优势互补,为临床诊断提供更快捷、更精确和更清晰的图像,为疾病的诊治提供更多的信息。同时,由于超声成像实时便捷的特性,使得超声成像特别适合与多种治疗方式结合在一起,开发超声成像实时监控治疗的复合试剂,即基于超声成像的诊断治疗一体化试剂。本文介绍了以超声成像为核心的多功能造影剂,包括靶向超声造影剂、多模态造影剂以及基于超声成像的诊断治疗一体化试剂,综述了近年来有关这一研究热点的报道,并提出了存在的问题以及今后可能的研究方向。     

吹扫捕集-GC-MS-SIM法测定水中微量甲基叔丁基醚

采用吹扫捕集-气相色谱-质谱联用选择离子检测法(GC-MS-SIM)测定水中微量的甲基叔丁基醚,最低检出质量浓度0．05μg/L,相对标准偏差2．4％,样品的加标回收率在94％∽120％之间。     

Electronic structures and edge effects of Ga_2S_2 nanoribbons

Ab initio density functional theory calculations are carried out to predict the electronic properties and relative stability of gallium sulfide nanoribbons(Ga_2S_2-NRs) with either zigzag- or armchair-terminated edges. It is found that the electronic properties of the nanoribbons are very sensitive to the edge structure. The zigzag nanoribbons(Ga_2S_2-ZNRs)are ferromagnetic(FM) metallic with spin-polarized edge states regardless of the H-passivation, whereas the bare armchair ones(Ga_2S_2-ANRs) are semiconducting with an indirect band gap. This band gap exhibits an oscillation behavior as the width increases and finally converges to a constant value. Similar behavior is also found in H-saturated Ga_2S_2-ANRs,although the band gap converges to a larger value. The relative stabilities of the bare ANRs and ZNRs are investigated by calculating their binding energies. It is found that for a similar width the ANRs are more stable than the ZNRs, and both are more stable than some Ga_2S_2 nanoclusters with stable configurations.     

磁性靶向药物递送中铁磁流体的动力学建模

Among the proposed techniques for delivering drugs to specific locations within human body, magnetic drug targeting prevails due to its non-invasive character and its high targeting efficiency. Magnetic targeting drug delivery is a method of carrying drug-loaded magnetic nanoparticles to a target tissue target under the applied magnetic field. This method increases the drug concentration in the target while reducing the adverse side-effects. Although there have been some theoretical analyses for magnetic drug targeting, very few researchers have addressed the hydrodynamic models of magnetic fluids in the blood vessel. A mathematical model is presented to describe the hydrodynamics of ferrofiuids as drug carriers flowing in a blood vessel under the applied magnetic field. In this model, magnetic force and asymmetrical force are added, and an angular momentum equation of magnetic nanoparticles in the applied magnetic field is modeled. Engineering approximations are achieved by retaining the physically most significant items in the model due to the mathematical complexity of the motion equations. Numerical simulations are performed to obtain better insight into the theoretical model with computational fluid dynamics. Simulation results demonstrate the important parameters leading to adequate drug delivery to the target site depending on the magnetic field intensity, which coincident with those of animal experiments. Results of the analysis provide important information and suggest strategies for improving delivery in clinical application.     

川芎化学成分研究

芎藭因主产於四川灌縣一帶,所以一般稱作川芎。本草列为上品,主治中風、痙攣、驚風、頭痛等症。近年來又用以治療高血壓病。因此,我們列為治療高血壓藥物研究之一。按川芎的原植物係屬繖形科(Umbelliferae),過去都循作Cnidium univittatum Turcz.或Conioselinum univittatum Turcz.。但最近我們將灌縣所產的川芎全植物送植物所中山植物園鑑定,經定其正確學名應為Ligusticum wallichii Fr.。     

生物可降解磷酸酯-碳酸酯共聚物的合成及性能研究

通过光气，二氯磷酸酯和双酚Ａ反应，合成六种磷酸酯 碳酸酯共聚物，用ＩＲ、１Ｈ ＮＭＲ及元素分析表征了共聚物，测量了Ｍｎ和热学性质．初步研究了在ｐＨ７４磷酸盐缓冲溶液中，核糖核酸酶或碱性磷酸酶存在下的体外降解性能及其对抗肿瘤药物５ Ｆｕ的释放性能．     

引导学生自我获取知识的几点作法

引导学生自我获取知识,是开发智力,培养能力,提高教学质量的关键一着。在教学过程中,注意了这种能力的培养,就等于为学生开创了一条自我探索和运用知识的途径,交给了学生进一步打开知识大门的钥匙。本文想就自己几年来的教学探索,谈几点粗浅的作法。一、理提纲,指导学生阅读教材书本是学生获取知识的主要来源,-也是他们在自学过程中的最好老师。教育学生重视课本,     

在曲面上图嵌入的唯一性(英)

在本文中，证明了图嵌入在一个已知曲面上的唯一性充分条件．这个条件比［4］中要弱些．