含草酰胺桥的Cu(Ⅱ)-Fe(Ⅱ)和Cu(Ⅱ)-Zn(Ⅱ)双核配合物的合成、磁性及生物活性

抗菌活性;含草酰胺桥的Cu(Ⅱ)-Fe(Ⅱ)和Cu(Ⅱ)-Zn(Ⅱ)双核配合物的合成、磁性及生物活性     

基于3维实体重建的直线加速器加速管热稳定性的优化设计

 行波电子直线加速器运行时加速管腔体因铜损会产生不均匀的热变形和腔频率偏移。因无法获知腔频率的准确偏移值,设计加速管冷却系统的一种经验设计方法是控制管体温度离散度在3 ℃之内。提出并实现了一种以直接控制加速管腔体频率离散度为设计目标的方法。采用插值蒙皮曲面造型理论,依据温度场和热变形的有限元仿真结果,高精度重建出变形后的腔体3维实体模型。将其导入到电磁场分析软件微波工作室,解算出不均匀温度分布造成的热变形引起的各腔频率偏移,实现了热-结构-电磁场的耦合分析。以加速管腔体频率离散度最小为设计目标,获得冷却系统优化参数。相对于经验设计方法,可大大减小冷却水流量和水压差,节约运行成本。     

Behaviour of Rotating Bose-Einstein Condensates Under Shrinking

When the repulsive interaction strength between atoms decreases, the size of a rotating Bose-Einstein condensate will consequently shrink. We find that the rotational frequency will increase during the shrinking of condensate, which is a quantum mechanical analogy to ballet dancing. Compared to a non-rotating condensate, the size of a rotating BEC will eventually be saturated at a finite value when the interaction strength is gradually reduced. We also calculate the vortex dynamics induced by the atomic current, and discuss the difference of vortex dynamics in this case and that observed in a recent experiment carried out by the JILA group [Phys. Rev. Lett.90 (2003) 170405].     

Synthesis, characterization and magnetism of μ-chloranilato bi-nuclear chromium (III) complexes

Five new chloranilato-bridged binuclear chromium (III) complexes have been synthesized and identified as [Cr2(CA)L4]-(ClO4)4[L denotes 5-methyl-1,10-phenanthroline (Me-phen); 2,9-dimethyl-1, 10-phenanthroline ( Me2-phen); 5-chloro-1,10-phenanthroline(Cl-phen); diaminoethane (en) or 1,3-diaminopropane (pn)], where CA represents the dianion of chloranilic acid. Based on elemental analyses, molar conductivity and magnetic moment of room-temperature measurements, and IR and electronic spectral studies, it is proposed that these complexes have CA-bridged structures and consist of two chromium (III) ions, each in an octahedral environment. The complexes [Cr2(CA)(Me-phen)4](ClO4)4(1) and [Cr2(CA)(Me2-phen)4](ClO4)4(2) were further characterized by variable temperature (4.2-300 K) magnetic susceptibility measurements and the observed data were successfully simulated by the equation based on the spin Hamiltonian operator, , giving the exchange parameter J = -7.8 cm-1 for (1) and J= -6.5 cm*1 for (2). This result     

对↓Δ算符运算规则的讨论及介绍一些有用的张量微分公式

介绍一些有实用意义的↓Δ算符运算规则的基本方法和知识，并给出一些有用的张量微分公式．     

新峪焦精煤中硫在族组分间的赋存规律研究(英文)

为从煤的本体组成结构方面来阐述煤中硫的赋存与分布规律,以高含有机硫的新峪焦精煤为对象,采用萃取反萃取的煤全组分分离方法和XPS、GC/MS等分析技术,对原煤和各族组分中的不同形态无机硫和有机硫含量进行了研究,重点考察了有机硫在煤有机质本体中的赋存规律。结果表明,无机硫的分布主要依赖于其自身在煤主体中的粒径大小和密度高低,与煤族组分本身结构关联较小。无论是原煤还是族组分,其有机硫均以噻吩型硫占主导;共轭结构为主的分子外环境,使共轭结构类有机硫的电子结合能降低,而使脂肪结构类硫的电子结合能升高,反之亦然。有机硫在煤中分布总体均衡,不会因为族组分结构不同而产生较大差异;但有机硫的类型硫赋存比例则与族组分本身的结构特征有所关联,不过其差别相对较小。轻质族组分中只含有一种有机硫小分子化合物,且相对丰度较小。     

基于3维实体重建的直线加速器加速管热稳定性的优化设计

行波电子直线加速器运行时加速管腔体因铜损会产生不均匀的热变形和腔频率偏移。因无法获知腔频率的准确偏移值,设计加速管冷却系统的一种经验设计方法是控制管体温度离散度在3 ℃之内。提出并实现了一种以直接控制加速管腔体频率离散度为设计目标的方法。采用插值蒙皮曲面造型理论,依据温度场和热变形的有限元仿真结果,高精度重建出变形后的腔体3维实体模型。将其导入到电磁场分析软件微波工作室,解算出不均匀温度分布造成的热变形引起的各腔频率偏移,实现了热-结构-电磁场的耦合分析。以加速管腔体频率离散度最小为设计目标,获得冷却系统优化参数。相对于经验设计方法,可大大减小冷却水流量和水压差,节约运行成本。     

Centrality Dependence of Flow in High—Energy Nucleus—Nucleus Collisions

Directed flow and elliptic flow of final state particles in high-energy nucleus-nucleus collisions in the EMU01 experiment have been studied.The dependences of directed flow and elliptic flow on incident energy and impact centrality of outgoing particles are presented.The results exhibit strong dependence of flow on centrality and energy.We also suggest a more reliable way to determine the event plane resolution here.     

羧基官能化SBA-15型介孔分子筛的小角X射线散射研究

使用小角X射线散射(SAXS)技术对共缩聚法制备的羧基官能化SBA-15介孔分子筛进行了表征,利用相关函数理论和弦长分布理论获得了羧基化分子筛的孔结构、界面和周期性信息,辅以常规的氮气吸附-脱附测试,并将基于Barrett-Joyner-Halenda(BJH)模型计算的孔结构与弦长分布理论得到的结果进行比较.结果表明:除了羧基引入量高达50%(摩尔分数,相对无机硅源)的样品外,随着羧基引入量的增加所有羧基官能化SBA-15均能保持较高的有序结构且有序度变化不大.所有样品的Porod曲线均无明显偏离,羧基基团倾向于进入介孔的骨架结构而不仅仅是键合在表面的Si—OH上.利用弦长分布法,无需建立模型,可以得到独立的孔壁厚度分布和孔径分布,尤其是其它方法无法给出的孔壁厚度分布,对于进一步认识有序介观结构材料有很大帮助.