水相中荧光CdSe纳米晶的优化合成与表征

Ⅱ-Ⅵ族半导体纳米粒子（也称半导体量子点（semiconductor quantum dots）简称NCs）由于其独特的光学、光化学、电化学以及非线性光学性质已逐渐引起人们的广泛关注。而Ⅱ-Ⅵ族NCs最诱人的 潜在应用是作为荧光探针应用于生物体系,在生命科学研究中起到定性和定量标记分子和细胞的作用。     

同系物保留指数与沸点的关联式中斜率因子的重要作用

]本文根据保留指数定义及热力学方程,导出同系物保留指数与沸点的关联式为I=atb+b玝斜率a是独立于固定相以外的常数,与温度无关。由文献数据回归分析得到苯和萘同系物的a值分别为3.762和4.814。并对煤焦油萘油进行了实例分析。由GC/FTIR证实,保留指数结合斜率因子a定性的正确率至少是88.9%。     

Application of shooting methods for two-point boundary value problems of ordinary differential equations with parameters in hydrodynamics

In this paper. first we introduce the shooting method (including the method of adjoints and the method of quasilinearization) for two-point boundary value problems of ordinary differential equations with parameters, and give out an example of solving hydrodynamic lubrication equation by using the shooting method. The calculated results are satisfactory.     

糟醉带鱼湿腌中鱼肉氯化钠、失重率与盐卤成分的变化

对糟醉带鱼不同腌制条件下鱼肉与盐卤成分的变化及其动力学变化特性进行了研究.结果表明:腌制条件对鱼肉中氯化钠含量、鱼肉失重率及盐卤中可溶性蛋白和氨基态氮含量变化有明显影响;腌制时间与鱼肉中氯化钠含量及盐卤中可溶蛋白和氨基态氮含量均呈极显著正相关,腌制温度与盐卤中氨基态氮和可溶蛋白含量呈极显著正相关,随着盐水质量分数的提高,鱼肉中氯化钠含量和鱼肉失重率显著上升,盐卤中可溶蛋白和氨基态氮含量明显降低;降低腌制温度、缩短腌制时间、提高盐水质量分数可降低鱼肉中氯化钠含量,控制肌肉中营养成分的析出;试验建立的动力学方程可较好地描述糟醉带鱼腌制过程中鱼肉的氯化钠含量、失重率及盐卤中可溶蛋白、氨基态氮含量的变化.     

Molecular dynamics study of primary radiation damage in TiVTa concentrated solid-solution alloy

The primary radiation damage in pure V and TiVTa concentrated solid-solution alloy(CSA) was studied using a molecular dynamics method. We have performed displacement cascade simulations to explore the generation and evolution behavior of irradiation defects. The results demonstrate that the defect accumulation and agglomeration in TiVTa CSA are significantly suppressed compared to pure V. The peak value of Frenkel pairs during cascade collisions in TiVTa CSA is much higher than that in pure V du...     

Ka波段同轴多注相对论速调管的电子束引入

首先通过理论分析确定影响多注电子束引入效率的主要因素,确定初步的结构参数;其次利用三维粒子模拟软件建立Ka波段相对论多注二极管模型进行仿真优化,使电子束引入效率达到89%;并开展了电子束的产生与传输实验研究,验证了粒子模拟仿真结果。在电子束电压502 kV、束流4.34 kA、轴向磁感应强度0.76 T的条件下,电子束引入效率达到了72%,由电子束轰击尼龙靶材获得的电子束束斑图表明,电子束在产生与传输过程中形状未发生畸变,产生的电子束直径约为2 mm。模拟和实验研究验证了设计的强流多注二极管可以产生高品质的电子束和实现高效率的电子束引入。     

S波段长脉冲相对论速调管重复频率运行稳定性研究

为了进一步提高S波段高功率强流长脉冲相对论速调管放大器(RKA)的重复频率稳频稳相运行的性能,采用实验结合理论和模拟的方法,分析了其主要制约因素,特别分析了造成器件脉冲缩短和重复频率运行不稳定等问题的根源。研究结果表明,RKA中的中间腔和输出腔的电子反射、电子散焦轰击腔体鼻锥是造成脉冲缩短、重复频率运行不稳定的主要根源。通过采用大漂移管半径的器件结构、在漂移管中加载吸波材料以及引导磁场位形、采用电子发射较均匀的碳/碳复合阴极材料等措施,使杂频振荡、脉冲缩短和重复频率工作不稳定性等问题得到了明显减轻,输出微波相位稳定性得到显著提高。采用电压830 kV、束流7.7 kA、脉宽190 ns的环行电子束驱动S波段3腔RKA,重复频率25 Hz运行得到了峰值功率1.55 GW、脉宽163 ns、相位抖动18°(rms)的输出微波。     

纳升电喷雾-离子迁移谱及其与高效液相色谱的联用

搭建了一套纳升级电喷雾-离子源离子迁移谱仪。首先,分别对尾吹气流速、溶剂流速等影响仪器去溶剂化效果的参数进行了研究和优化。在此基础上,用一系列胺类化合物对该仪器的去溶剂化效果、分辨能力以及灵敏度进行了表征。实验结果表明,该仪器能够对电喷雾离子液滴实现完全去溶剂化;三辛胺的检出限可以达到10 μg/L。最后,将该仪器用作高效液相色谱的检测器,在无需衍生化的条件下对胺类混合物样品进行检测。由三乙胺、二乙胺以及丁胺组成的混合样品被成功分离并测定。该系统对三乙胺、二乙胺以及丁胺的线性响应范围均达到近两个数量级。     

Extraction of periodic signals in chaotic secure communication using Duffing oscillators

This paper presents a novel approach to extract the periodic signals masked by a chaotic carrier. It verifies that the driven Duffing oscillator is immune to the chaotic carrier and sensitive to certain periodic signals. A preliminary detection scenario illustrates that the frequency and amplitude of the hidden sine wave signal can be extracted from the chaotic carrier by numerical simulation. The obtained results indicate that the hidden messages in chaotic secure communication can be eavesdropped utilizing Duffing oscillators.     

Improving performance of optical fibre chaotic communication by dispersion compensation techniques

This paper numerically investigates the effects of dispersion on optical fibre chaotic communication, and proposes a dispersion compensation scheme to improve the performance of optical fibre chaotic communication system. The obtained results show that the transmitter-receiver synchronization progressively degrades and the signal-to-noise ratio of the recovered message deteriorates as the fibre length increases due to the dispersion accumulation. Two segments of 2.5-km dispersion-compensating fibres are symmetrically placed at both ends of a segment of 245-km nonzero dispersionshifted fibre with low dispersion in one compensation period. The numerical results show that the signal-to-noise ratio of the extracted 1 GHz sinusoidal message is improved from -2.92 dB to 15.38 dB by this dispersion compensation for the transmission distance of 500 km.