PEDOT-PSS/Co-Fe_3O_4/PVA电磁功能复合纤维结构与性能

将化学共沉淀法合成的Co掺杂的Fe_3O_4(Co-Fe_3O_4)磁性粒子和化学氧化法合成的聚苯乙烯磺酸钠(PSS)掺杂的聚(3,4-乙撑二氧噻吩)(PEDOT-PSS)与聚乙烯醇(PVA)混合制备复合纺丝原液,然后经过湿法纺丝得到具有电、磁性能的PEDOT-PSS/Co-Fe_3O_4/PVA复合纤维.通过SEM、FTIR、XRD、TG、VSM以及电导率和机械性能的测试研究了不同牵伸倍率对复合纤维的结构和性能的影响.结果表明,随着牵伸倍率的增加,复合纤维的结晶性能、热稳定性能和机械性能都有所提升,其电导率则成倍增加,而其饱和磁化强度(M_s)则变化不大,约为1.7 A·m~2/kg.当牵伸倍数为4倍时,复合纤维的电导率可达到2.3 S/cm.     

组合荷载作用下腐蚀缺陷管道的极限承载力

腐蚀缺陷的存在会降低管道的承载力,影响管道的正常运行.考虑了管道轴向与环向材料强度的各向异性,提出了腐蚀缺陷压力管道在内压、轴力和弯矩组合荷载作用下极限承载力的一组广义解.推导了等深度腐蚀、椭圆腐蚀和抛物线三种形状腐蚀缺陷管道的解析解.通过算例验证了解析解与广义解结果具有很好的吻合性.腐蚀形状对极限承载力有显著影响,把...     

Probing the universality of acceleration scale in modified Newtonian dynamics with SPARC galaxies

We probe the universality of acceleration scale a₀ in Milgrom's modified Newtonian dynamics(MOND)using the recently released rotation curve data from SPARC galaxies.We divide the SPARC data into different subsamples according to the morphological types of galaxies,and fit the rotation curve data of each subsample with the theoretical prediction of MOND.MOND involves an arbitrary interpolation function which connects the Newtonian region and the MOND region.Here we consider five different interpolation functions that are widely discussed in the literature.It is shown that the best-fitting a₀ significantly depends on the interpolation functions.For a specific interpolation function, a₀ also depends on the morphological types of galaxies,implying that a₀ may be not a universal constant.Introducing a dipole correction to a₀ can significantly improve the fits.The dipole directions for four of the five interpolation functions point towards an approximately consistent direction,but a₀ still varies for different interpolation functions.     

装配收音机的参考材料

仪器的裝置我們这个無綫电裝置是供給十年級做学生实验用的,稍加复杂化即可供無綫电小組实習之用,例如进行真空管特性的实驗。全部仪器就裝在五塊底板上,而且裝置图和原理图完全一致。在每塊底板上裝置的一部份要完成一定的工作任务。     

台风过境下大型单桩式海上风机结构动力特性研究

风机大型化是我国海上风电技术发展的重要方向. 东南沿海是我国海上风电发展的重要基地, 这一区域频繁发生的台风对海上风机的影响不可忽略. 台风风场与常规大风风场有不同的湍流特性, 同时台风期间较高的风速会引起巨大的台风浪. 本文考虑台风经过期间独特的风场及波浪场, 开展风浪联合作用对大型单桩海上风机影响的研究. 基于DTU 10 MW大型单桩风机, 运用一体化分析软件SIMA建立风浪联合作用下大型单桩风机的耦合数值模型, 研究台风经过不同阶段大型风力机的动力响应特性. 计算结果显示, 叶片变桨能有效降低台风经过时风机叶片所受风载荷, 变桨状态下单桩风机所受风载荷主要来源于塔筒. 在台风经过的不同阶段, 大型单桩海上风机结构表现出不同的动力特性. 台风全过程塔筒运动均受波浪激发一阶频率控制, 塔基上方结构动力载荷以惯性载荷为主, FOVS至FEWS阶段及BOVS阶段至BEWS阶段塔筒运动一阶频率处响应能量增长较小, 响应能量向低频及波频转移. 塔基下方泥面线处剪力响应受波频控制, 弯矩响应受一阶频率控制.      

稀土钨青铜K0.71Nd0.028WO3的制备及其电性能

Tetragonal tungsten bronze K_0.71Nd_0.028WO₃ was synthesized by rare earth co-permeation method using Keggin type POMs of α-K₁₀[SiCu₃(OH₂)W₉O₃₇]·6H₂O (abbreviated as SiW₉Cu₃) as precursor. XRD, XPS, XRF, TG-DTA were used to characterize the resulting material. The XPS results indicate that Nd has permeated and diffused into the body of the sample and exists in tungsten bronze in the form of K_0.71Nd_0.028WO₃. The results of TG-DTA show that K_0.71Nd_0.028WO₃ begins to decompose at 320 ℃. The consequence of DC four-probe shows that the conductivity of the sample permeated by rare earth is 10³ times higher than that of the sample only permeated by methanol at room temperature. The conductivity of the sample only permeated by methanol is only 10^-3 S·cm^-1 but the conductivity of the sample permeated by rare earth is 1.65 S·cm^-1.     

型钢-钢板混凝土组合墙抗震性能试验研究

提出一种型钢–钢板混凝土组合墙,为了研究其抗震性能,设计制作该形式的型钢–钢板混凝土组合墙进行拟静力试验。通过改变试件的轴压比、剪跨比,研究其在低周往复载荷作用下的受力机理、滞回性能、刚度退化及耗能能力等。试验结果表明:试件的破坏形态为压弯破坏,组合墙两端方钢管正面及侧面发生撕裂,两侧底部钢板屈曲严重,混凝土压溃;随着轴压比减小,试件具有更好的塑性变形能力和耗能能力,剪跨比对组合墙的抗震性能影响较小。     

无溶剂体系中固定化脂肪酶Candida sp. 99-125催化合成油酸低碳醇酯

采用固定化脂肪酶Candida sp.99-125在无溶剂体系中催化合成油酸低碳醇酯,考察了加酶量、温度、酸醇摩尔比和醇结构对油酸酯化率的影响。结果表明,加酶量为底物质量的3%,最适温度为20℃,酸与醇摩尔比为1∶1,甲醇对该酶有一定的毒性,由于空间位阻效应,该酶对伯醇具有高选择性,对仲醇、叔醇的选择性低,且对长链脂肪酸催化活性高,对带支链的多元酸、多元醇活性低。该酶重复使用5次,酶活性基本没有降低。与传统的化学法相比,用该酶催化合成酯类化合物的色泽更浅。     

用稀土多元渗法制备钾稀土钨青铜KxLayWO3的XPS研究

Potassium tungsten bronze K_xLa_yWO₃ (x>0.5 and y<0.01) was synthesized by rare earth co-permeation method using α-K₇[SiMg₃(OH₂)₃W₉O₃₇] as the precursor. Binding energies of La, W, O and C were determined by XPS. From the XPS data, a peak at 34.21 eV indicates that some W⁶⁺ turned into W⁵⁺ by rare earth co-permeation. The binding energies La3d were the same in the surface and inner of the composite, showing that rare earth element La could diffuse into the body of the composite and the compound of K_xLa_yWO₃ was formed at the same time. The binding energies of O1s in K_xLa_yWO₃ surface were 531.4 eV and 532.0 eV, respectively, while peak at 531.4 eV disappeared through etching process. The result implies that the binding energy of 531.4 eV was due to the adsorbent O. In addition, the binding energies of C1s in the surface were 283.5 eV, 285.0 eV and 286.7 eV respectively, while the inner had only one peak at 285.0 eV due to standard C1s. This proves that there was no C in the core.     

便携式低压钠灯电子镇流器设计

针对现有低压钠灯光源功耗高、输出稳定性差的问题,提出一种便携式低压钠灯电子镇流器设计方法。通过分析低压钠灯伏安特性曲线,对比现有典型低压钠灯镇流器的特点,根据低压钠灯工作原理设计相应的镇流电路。在电磁滤波的基础上,加入功率因数校正及恒功率控制电路以保证电路输出功率的稳定,加入LC谐振电路以保证电路输出频率的稳定,通过反馈控制实现电路的可靠工作。采用GP20NA-1型低压钠灯作为输出对象对低压钠灯电子镇流器输出电压、电流及低压钠灯辐射光谱进行验证,结果表明,低压钠灯电子镇流器输出功率稳定,常态下输出功率不大于20 W,钠灯辐射光谱稳定于589.3 nm,在光学计量、实验室照明等方面具有较高的应用价值。