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Cooperative Quantum Cutting of Nano-Crystalline BaF2:Tb^3+, Yb^3+ in Oxyfluoride Glass Ceramics
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We report on cooperative quantum cutting in Tb^3+- Yb^3+ codoped glass ceramics. Precipitation of BaF2 nanocrystals is confirmed by XRD and HRTEM analysis. Near-infrared emission due to transition of Yb^3+ ions under 485 nm excitation indicates cooperative energy transfer from Tb^3+ to Yb^3+. The quantum efficiency of this process reaches 145%. The realization of quantum cutting in glass ceramics may have promising applications in solar cells. 相似文献
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PbS-doped glasses are prepared. Absorption and luminescence spectra show that both the absorption and infrared emission can be tuned widely by thermal treatment conditions. Optical amplification at 1300 nm is observed, and amplified spontaneous emission (ASE) spectrum is also measured to confirm the optical gain from PbS quantum dots. 相似文献
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本工作以SiO2-TiO2凝胶体系为基质,选择合适的溶剂,采用特定的溶胶-凝胶工艺,成功地将纯的C60和C60/C70混合物分别均匀掺入上述基质中,研究了吸收与荧光光谱特性,室温下观测到峰位置位于660nm附近的较强荧光带,对上光谱性质作了初步的解释。 相似文献
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Bismuth(Bi)-doped near-infared(NIR) glass that can cover the entire optical communication window(850, 1310, and1550 nm) has become the subject of extensive research for developing photonic devices, particularly, tunable fiber lasers and ultrabroadband optical amplifiers. However, the realization of highly efficient NIR luminescence from Bi-doped glass is still full of challenges. Notably, due to the co-existence of multiple Bi NIR centers in the glass, the origin of newly generated Bi NIR emissi... 相似文献
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三层材料纳米颗粒形状对消光特性的影响 总被引:1,自引:1,他引:0
通过高分辨率电子束光刻方法制备了不同形状的三层复合材料纳米颗粒,研究了这种纳米颗粒的形状变化对消光特性的影响。测试结果表明,当入射波偏振方向平行于短轴时,随着长宽比的增大,共振峰位置发生蓝移;当光源偏振方向平行于长轴时,随着长宽比的增大,共振峰位置发生红移。还用时域有限差分算法以及表面等离波子的Lorentz模型对纳米颗粒的消光特性进行数值计算,所得的消光频谱曲线、共振峰位置变化趋势与实验基本一致。此外,还研究了主体材料层厚度对消光特性的影响,发现其厚度在20~90nm变化时,共振峰发生3~115nm的蓝移。 相似文献
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飞秒激光相干场诱导材料功能微结构 总被引:2,自引:0,他引:2
飞秒激光在整个脉冲宽度内具有极好的相干性,因而当从同一光束分出的两束或两束以上的光束时间与空间上实现相互叠加时将会形成强度周期性调制的电磁场.这种周期调制的电磁场与材料产生相互作用,能诱导出相应的周期微结构.最近通过两束或两束以上飞秒激光干涉诱导功能微结构得到了广泛研究.文章综合了国内外飞秒激光研究小组在干涉诱导微结构方面的一些最新成果以及作者在这方面开展的工作,对飞秒激光干涉技术的原理及其在诱导微结构方面的应用进行了介绍. 相似文献