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用核磁共振对非晶态中B3+离子的微观结构进行了测定,结合Raman光谱的研究,对Li2O-B2O3-P2O5系统非晶态的性能(电导率、密度等)在P2O5/B2O3比约等于1时产生极值的原因从理论上作了阐明。 相似文献
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本工作以SiO_2和SiO_2-TiO_2凝胶体系为基质,选择合适的溶剂,采用特定的溶胶一凝胶工艺,成功地将纯的C_(60)和C_(60)/C_(70)混合物分别均匀掺入上述基质中.研究了吸收与荧光光谱特性.室温下观测到峰置位于660nm附近的较强荧光带.对上述光谱性质作了初步的解释. 相似文献
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含铒碲酸盐玻璃的上转换荧光性质研究 总被引:1,自引:0,他引:1
在室温下,用804nm波长的半导体激光器作激发源,在TeO_2-PbO基掺铒碲酸盐玻璃中实现了中心波长分别为525nm,550nm和660nm的上转换发射.荧光强度与激发功率呈非线性关系.估测了PbO含量对上转换荧光相对强度的影响. 相似文献
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报导和总结了运用两种先驱体配方和溶胶-凝胶的工艺过程,成功地把富勒烯物质掺入,到各种种凝胶介质中,比较了采用不同方法的优缺性,富勒烯处于凝胶介质的微孔及凝胶介质结构相关联的2种结构状态,分别测定了处于2种结构状态下紫外-可见光谱及与介质相关联的红外光谱,并进行了比较和讨论,用调Q,YAG,532nm波长脉宽为10ns的激光作为光源,实现了处于2种结构状态下的光限制效应,讨论了介质对富勒烯物质的结构 相似文献
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Space-Selective Precipitation of Ba2TiSi2O8 Crystals in Sm3^+-Doped BaO-TiO2-SiO2 Glass by Femtosecond Laser Irradiation 下载免费PDF全文
The ferroelectric crystal Ba2TiSi2O8 with high second-order optical nonlinearity is precipitated in Sm^3+-doped BaO-TiO2-SiO2 glass by a focused 800hm, 250 kHz and 150fs femtosecond laser irradiation. No apparent blue and red emissions are observed at the beginning, while strong blue emission due to second harmonic generation and red emission due to the f-f transitions of Sm^3+ are observed near the focal point of the laser beam after irradiation for 25s. Micro-Raman spectra confirm that Ba2 TiSi2O8 crystalline dots and lines are formed after laser irradiation. The mechanism of the phenomenon is discussed. 相似文献
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Study of the microstructural transformations of borate glass and barium metaborate crystals induced by femtosecond laser 下载免费PDF全文
This paper describes the microstructural transformations of borate glass and barium metaborate crystals induced by femtosecond laser. Such structural transformations were verified by Raman spectroscopy. The borate glass is transformed into low temperature (LT) phase of barium metaborate (BaB_2O_4) crystals after being irradiated for 10 min by a femtosecond laser. In addition, after 20 min of irradiation, high temperature (HT) phase of BaB_2O_4 crystals is also produced. Further studies demonstrate that LT phase BaB_2O_4 crystals are formed in the HT phase BaB_2O_4 crystals after femtosecond laser irradiation for 10 s. 相似文献
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We report on structural change in an Au^3+-doped BK7 glass irradiated by an infrared femtosecond laser at 800 nm. A grating structure is inscribed in the glass sample. The glass sample is then annealed at various temperatures. Structural change of the grating is observed by an optical microscope. Absorption spectra indicate that colour centres are induced after the laser irradiation, and they decrease with increasing annealing temperature. Au nanoparticles are precipitated at high temperatures (≥ 600℃). The mechanisms of the phenomena are discussed. 相似文献
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Blue-to-Orange Tunable Luminescence from Europium Doped Yttrium--Silicon--Oxide--Nitride Phosphors 下载免费PDF全文
Europium-doped yttrium-silicon-oxide-nitride phosphors are synthesized by carbothermal reduction and nitridation method. The crystal structure of the phosphors changed gradually from oxide Y2Si2O7 to nitride YSi3N5 state with increasing dosage of Si3N4 and carbon powder. The Y2Si2O7:Eu phosphor shows a blue emission at 465 nm with 300 nm excitation and a characteristic red emission of Eu^3+ at 612 nm with 230 nm excitation. The YSi3N5:EU phosphor shows a broad emission band centred at 595nm with some sharp peaks of Eu^3+ with 325nm excitation. The absorption of the studied phosphors increases from 450 to 700hm with an increment in nitrogen content. Blue-to-orange tunable luminescence is observed with 390 nm excitation. 相似文献