Effects of Contact Atomic Structure on Electronic Transport in Molecular Junction

Based on nonequilibrium Green＇s function and first-principles calculations, we investigate the change in molecular conductance caused by different adsorption sites with the presence of additional Au atom around the metal- molecule contact in the system that benzene sandwiched between two Au（111） leads. The motivation is the variable situations that may arise in break junction experiments. Numerical results show that the enhancement of conductance induced by the presence of additional Au is dependent on the adsorption sites of anchoring atom. When molecule is located on top site with the presence of additional Au atoms, it can increase molecular conductance remarkably and present negative differential resistance under applied bias which cannot be found in bridge and hollow sites. Furthermore, the effects of different distance between additional Au and sulfur atoms in these three adsorption sites are also discussed.     

再加热双脉冲激光诱导等离子体的时空演变特性研究

为了研究再加热双脉冲激光诱导击穿光谱(LIBS)对信号的增强机制,分别采用单脉冲LIBS和再加热双脉冲LIBS两种方式烧蚀合金钢样品产生等离子体,利用高分辨率的中阶梯光栅光谱仪采集等离子体发射光谱信号,同时用快速成像ICCD相机观测等离子体形态的变化,研究了两种烧蚀方式下等离子体的时空演变特性。通过比较两种烧蚀方式下等离子体产生初期光谱信号和图像的时间演变规律,发现再加热双脉冲LIBS提高了等离子体温度,且当信号采集延时等于再加热双脉冲的脉冲间隔时,等离子体温度的衰减速率发生变化;再加热双脉冲LIBS使等离子体图像强度增加,等离子体的中心区域高度和宽度分别增大了23.5%和15.1%。空间分布的研究结果表明,与单脉冲LIBS相比,当到样品表面的距离大于0.6 mm时,等离子体中的Fe Ⅱ和N Ⅰ谱线强度有较明显的增强,而Fe Ⅰ谱线在空间不同位置处的增强程度都较小,局部区域有减小的现象;再加热双脉冲LIBS使等离子体温度增加了约2 000 K,等离子体中产生了一个较大的高温区域。综合时空演变的实验结果说明再加热双脉冲对光谱信号增强的机制主要是由于第二束激光对第一束激光烧蚀样品产生的等离子体再次激发,使等离子体温度增加,进而引起等离子体辐射强度增加。     

20 GW/100 Hz脉冲功率源研制

20 GW/100 Hz脉冲功率源是一台基于Tesla变压器技术的重复频率脉冲功率装置,设计功率20 GW,脉宽40 ns,重频1～100 Hz,输出功率及重频指标在一定范围内可调。介绍了20 GW/100 Hz脉冲功率源的系统构成,电气及结构参数的确定方法,关键部件的工程工艺技术,并分析了关键绝缘部件的电场分布。实验调试结果表明,20 GW/100 Hz脉冲功率源运行稳定可靠,重频工作时输出电压分散性小于1％,可应用于高功率微波及强流束产生等物理实验研究。     

Discontinuous Structural Phase Transition Behaviour in Multiple Component Alloy Melts

Discontinuous structural phase transition behaviour in seven kinds of liquid multiple component alloys are found by using a torsional oscillation viscometer. There are different phases existing in the system and the number of phases is discussed using the equilibrium thermodynamics phase rule. The phase parameters （ηo,ε） and order parameter dI in different phase regions are calculated based on the researched results. It is found that the parameters （ηo,ε, df） change at the structural transition point. The diameter of the fluid clusters, di, is stable in each phase region, which indicates that the structure is uniform.     

Enhancement in Magnetorheological Effect of Magnetorheological Elastomers by Surface Modification of Iron Particles

为了研制具有高磁流变效应的磁流变弹性体,从新的化学修饰的角度制备了各向异性的橡胶基磁流变弹性体. 阴离子表面活性剂、非离子表面活性剂和复合表面活性剂等三种不同类型的表面活性剂分别用于修饰铁颗粒. 使用力磁耦合动态测试仪测量磁流变弹性体的动态剪切模量,并计算材料的磁流变效应. 测试结果表明,当Span 80的含量为15%时,材料的相对磁流变效应可达到188%,除了表面活性外,Span 80的增塑效应也有利于相对磁流变效应的增加. 当使用具有强表面活性的复合表面活性剂修饰铁颗粒时,用量只需0.4%,便可使相对     

涡旋光的干涉特性及其在变形测量中的应用

将涡旋光应用于电子散斑干涉,测量变形物体的离面位移.把传统的电子散斑干涉测量技术与液晶空间光调制器相结合,将所获得的涡旋光作为参考光或者物光进行变形测量.推导出物光为平面光、参考光为涡旋光,和参考光、物光均为涡旋光时物体变形后的干涉强度公式,模拟计算了变形后的干涉图样,分析了变形图样的特征.运用四步相移方法得到了物体的变形相位公式,通过解包裹得到了物体的变形相位.模拟计算得到的三维相位分布图与物体离面位移的变形相位理论值的三维分布图相吻合.模拟实验结果表明,涡旋光可以应用于物体的变形测量,为变形测量提供新的途径.     

基于AVR单片机的高精度光学测厚系统设计

对薄膜测厚系统进行了详尽剖析,从整体上论述了膜厚测量系统,研究了测厚系统中薄膜测厚仪的关键硬件电路,对薄膜测厚仪的软件流程进行了离散设计。以AVR单片机为核心处理器进行了数据采集和处理,设计并生产出了在线式光学薄膜厚度测量与监控系统。通过与实际膜厚进行对比实验,验证了薄膜测厚系统具有高精度、高稳定性和高可靠性,可应用于实际工业生产。     

Effect of surface plasmon coupling with radiating dipole on the polarization characteristics of AlGaN-based light-emitting diodes

The optical polarization characteristics of surface plasmon (SP) coupled AlGaN-based light emitting diodes (LEDs) are investigated theoretically by analyzing the radiation recombination process and scattering process respectively. For the Al_0.5Ga_0.5N/Al/Al₂O₃ slab structure, the relative intensity of TE-polarized and TM-polarized spontaneous emission (SE) rate into the SP mode obviously depends on the thickness of the Al layer. The calculation results show that TM dominated emission will be transformed into TE dominated emission with the decrease of the Al thickness, while the emission intensities of both TE/TM polarizations will decrease significantly. In addition, compared with TM polarized emission, TE polarized emission is easier to be extracted by SP coupling. For the Al_0.5Ga_0.5N/Al nano-particle structure, the ratio of transmittance for TE/TM polarized emission can reach ～3.06, while for the Al free structure, it is only 1.2. Thus, the degree of polarization of SP coupled LED can be improved by the reasonable structural design.     

Eu3+/Sm3+共掺聚合物PMMA中敏化效应的研究

研究了Eu3+/Sm3+共掺聚合物PMMA中Sm3+对Eu3+发光的敏化效应,实验采用改进的本体聚合法制备得到了Eu3+/Sm3+共掺聚合物PMMA,并对其荧光光谱和荧光寿命进行了分析.荧光光谱分析发现,Sm(TTFA)3的加入大大增强了Eu3+的特征发光,表明Sm3+对Eu3+的荧光有很强的敏化效应,文中对其敏化过程进行了探讨与分析,提出了两种可能的敏化机理.荧光寿命分析表明,在共掺情况下,掺杂浓度对荧光寿命没有明显的影响,寿命范围在300~400 μs之间.