基于Ugi多组分反应的海藻酸酰胺衍生物改性二氧化硅纳米粒子的制备

采用海藻酸酰胺衍生物通过Ugi多组分反应制备了新颖的聚合物-二氧化硅(Oct-Alg-Si O_2)纳米粒子.通过氢核磁共振波谱(~1H NMR)和X射线光电子能谱(XPS)对Oct-Alg-Si O_2的结构和表面元素组分进行了表征.采用透射电子显微镜(TEM)、Zeta电位和激光粒度分析仪对Oct-Alg-Si O_2的形貌、粒径和胶体性能进行了探索.结果表明,海藻酸酰胺衍生物共价接枝到氨基二氧化硅(Si O_2-NH_2)纳米粒子的表面,提高了其平均直径,调控了其Zeta电位,在水介质中能够表现出良好的分散稳定性.以10%的液体石蜡为油相,采用Oct-Alg-Si O_2制备了Pickering乳液.在油水界面能够形成液滴粒径为5.7μm的稳定Pickering乳液.随着水相p H值的增大,乳液体积分数增大,稳定性增强.细胞相容性实验结果表明,Oct-Alg-Si O_2纳米粒子具有极好的生物相容性.     

“ 延迟选择”没有延迟

延迟实验是惠勒提出的一个实验, 它所展示的物理结论与人们之前的得到的物理规则格格不入: 观测 行为决定了观测之前发生的事情, 时间上从古至今是一个整体. 该实验充分彰显了量子力学中哥本哈根学派的思 想, 不仅引发一个科学问题还引发了一个哲学问题. “ 延迟选择”实验中, 人们可以在事后以延迟的方式选择光子两 条传播路径中的某一条, 这和因果律相违背. 但是如果能继续以量子力学的基本假设去分析每个实验结果而不是用 “ 定域实在论”去人为确定粒子的路径, 就不会出现难以理解的“ 延迟选择”和“ 因果颠倒”     

氢化物发生-原子荧光光谱法测定大米与圆白菜中痕量铅

建立了氢化物发生-原子荧光光谱法(HG-AFS)测定经HNO3-HClO4-H2O2湿法消解的大米与圆白菜等样品中痕量铅的方法,系统地优化了灯电流等仪器参数条件,探讨了载流、还原剂、样品酸度、氧化剂的最佳浓度,考察了掩蔽剂去干扰的情况。实验表明:在选定载流浓度HCl 2%(V/V)、还原剂KBH4浓度2%(m/V)[KOH恒为0.5%(m/V)]、样品酸度HCl 1%(V/V)、氧化剂K3Fe(CN)60.4%(m/V)、掩蔽剂H2C2O40.2%(m/V)及优化设置灯电流等参数的最佳实验条件下,测定铅的检出限为0.07μg/L,在0.00—50.00μg/L范围呈良好的线性关系,样品测定变异系数小于等于6.22%。该方法简便、干扰少、灵敏度高,应用于大米、圆白菜等样品中Pb的测定,结果与参考值相符,是一种切实可行的方法。     

一类4pq(p>q≠3)阶群的构造

在有限群理论中,确定n阶群的构造是一个分类问题.利用了超可解群的性质,通过群的扩张理论解决了在p 1(modq)时4pq(p>q≠3)群的构造,即证明了下面的定理:当p/≡1(modq)时4pq(p>q>3)阶群的构造:①10种,p/≡1(mod 4),q/≡1(mod 4)时;②16种,p≡1(mod 4),q≡1(mod 4)时.③12种,p≡1(mod 4),q/≡1(mod 4)时;④12种,p/≡1(mod 4),q≡1(mod 4)时.     

The dynamic characteristics of harvesting energy from mechanical vibration via piezoelectric conversion

As an alternative power solution for low-power devices, harvesting energy from the ambient mechanical vibration has received increasing research interest in recent years. In this paper we study the transient dynamic characteristics of a piezoelectric energy harvesting system including a piezoelectric energy harvester, a bridge rectifier, and a storage capacitor. To accomplish this, this energy harvesting system is modeled, and the charging process of the storage capacitor is investigated by employing the in-phase assumption The results indicate that the charging voltage across the storage capacitor and the gathered power increase gradually as the charging process proceeds, whereas the charging rate slows down over time as the charging voltage approaches to the peak value of the piezoelectric voltage across the piezoelectric materials. In addition, due to the added electrical damping and the change of the system natural frequency when the charging process is initiated, a sudden drop in the vibration amplitude is observed, which in turn affects the charging rate. However, the vibration amplitude begins to increase as the charging process continues, which is caused by the decrease in the electrical damping （i.e., the decrease in the energy removed from the mechanical vibration）. This electromechanical coupling characteristic is also revealed by the variation of the vibration amplitude with the charging voltage.     

A prototype of trigger electronics for LAWCA experiment

The Large Area Water Cherenkov Array （LAWCA） experiment focuses on high energy gamma astronomy between 100 GeV and 30 TeV. Invoked by the idea of hardware triggerless structure, a prototype of LAWCA trigger electronics is implemented in one single VME-9U module which obtains all the data from the 100 Front End Electronic （FEE） endpoints. Since the trigger electronics accumulate all the information, the flexibility of trigger processing can be improved. Meanwhile, the dedicated hardware trigger signals which are fed back to front end are eliminated; this leads to a system with better simplicity and stability. To accommodate the 5.4 Gbps system average data rate, the fiber based high speed serial data transmission is adopted. Based on the logic design in one single FPGA device, real-time trigger processing is achieved; the reprogrammable feature of the FPGA device renders a reconfigurable structure of trigger electronics. Simulation and initial testing results indicate that the trigger electronics prototype functions well.     

Kerr效应对二项式腔场谱量子干涉的影响

研究了含Kerr介质高Q腔内单个二能级原子与双模二项式光场发生双光子共振相互作用系统的腔场谱,给出了Kerr效应与量子干涉项ΔS(ω)关系的数值计算结果,讨论了Kerr效应对二项式腔场谱量子干涉的影响.结果表明:若初始时刻原子处于激发态而双模光场处于二项式态,随Kerr效应的增强,致使量子干涉项引起谱线强度的改变量呈现出"不规则的周期性衰减振荡"特性,震荡幅度与两模光场的频差密切相关.在Kerr系数χg(g为光场与原子的耦合常数)时,Kerr效应对干涉项的影响比较强烈;在χg时,趋于平稳.随着Kerr效应的增强,系统腔场谱由对称结构逐渐演化为不对称的多谱线结构.     

Al_xGa_(1-x)As:Si中DX中心的双极化子机制及统计分析

基于极化子和双极化子的物理图像,采用无拟合参数的巨正则统计方法计算了Si掺杂的AlxGa1-xAs的导带载流子浓度,计算得到的理论结果从高温到低温都与实验结果定量一致.计算证实了AlxGa1-xAs:Si中的DX中心的基态DX-是电子-晶格相互作用产生的负电双极化子.处于热平衡状态时,施主Si在AlxGa1-xAs中除了电离状态,处于不同晶格构型的单、双极化子态共存,低温时双极化子态被冻结;光照下发生持续光电导时,双极化子态变成单极化子态同时向导带释放一个电子,此过程伴随着进一步的晶格弛豫.理论与实验的对照说明单电子局域的DX0态在热平衡时并不能稳定存在,这和提出的双极化子机制是完全一致的.     

搜索引擎行业竞争策略

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