排序方式: 共有84条查询结果,搜索用时 187 毫秒
21.
22.
聚乙烯吡咯烷酮存在时反相微乳液中水的状态
总被引:2,自引:0,他引:2
运用傅立叶变换红外光谱(FTIR)研究不同分子量的聚乙烯吡咯烷酮(PVP)存在时,十二烷基甜菜碱(C12BE)/正庚烷/正戊醇/水(Ⅰ)及二(2-乙基)己基磺化琥珀酸钠(AOT)/正庚烷/水(Ⅱ)反相微乳液中水的存在状态.采用计算机分峰技术将微乳液中水分子的O-H伸缩振动进行曲线拟合,(Ⅰ)得到三个子峰,分别位于(3560±20)cm 相似文献
23.
在十六烷基三甲基溴化铵(CTAB)/乙醇/水/盐酸形成的胶束溶液中, 以MnCl2·4H2O, 钛酸四异丙酯Ti(O-iPr)4为原料, 用溶胶-凝胶方法, 75℃首先合成了纳米TiO2-氧化锰(MnO2, Mn2O3, Mn3O4)干凝胶, 然后在不同温度下对其进行热处理. 用X射线衍射(XRD)、透射电子显微镜 (TEM)和X射线光电子能谱(XPS)对纳米材料的结构和相组成进行了表征; 用紫外-可见光谱(UV-Vis)和激光拉曼光谱(LRS)对纳米材料的光谱性能进行了研究. X射线衍射(XRD)分析表明该干凝胶在900℃ 煅烧后可制得红钛锰矿MnTiO3纳米材料. 透射电子显微镜(TEM)形貌观察, MnTiO3粒子为球形或椭球形, 平均粒径50 nm. 与TiO2(P-25)的光谱相比, 纳米MnTiO3的紫外-可见光谱(UV-Vis)在300~700 nm范围有明显的吸收谱带, 其激光拉曼光谱(LRS)中亦有新的特征吸收峰(684, 610, 462, 360, 336, 263, 235 和202 cm8722;1). 相似文献
24.
高分子表面活性剂已广泛应用于许多领域, 其构型复杂、分子量大等特点使其聚集行为不同于小分子表面活性剂. 从微观上认识其聚集行为可为应用提供指导, 因而此方面的研究倍受关注. 计算机模拟技术的发展使我们能成功地在微观或介观水平上获得高分子表面活性剂聚集行为的信息. 本文综述了耗散粒子动力学(DPD)和介观动力学(MesoDyn)在高分子表面活性剂聚集行为研究中的应用. 着重介绍了这两种介观模拟方法研究单一高分子表面活性剂溶液的相行为及其与低分子表面活性剂之间的相互作用, 揭示了实验中难以观测的微观相分离及聚集体结构形态的变化规律. 这些信息可以为实验研究提供指导和补充. 相似文献
25.
利用新型表面活性剂4-十二烷氧基苄胺(C12OBA)构成的C12OBA/正庚烷/正丁醇/HAuCl4/NaOH(aq.) W/O型微乳液作为微反应器, 通过微波辐射加热的正丁醇原位还原法制备了C12OBA包裹的憎水性金纳米粒子, 并通过紫外可见光谱(UV-vis)、透射电镜(TEM)、X射线衍射(XRD)、红外光谱(FT-IR)和接触角(CA)等分别进行了表征和分析. 结果显示, C12OBA既可参与形成稳定的W/O型微乳液, 又可作为金粒子的良好保护剂. 微乳液内核中碱度的增加能增强位于膜相的正丁醇分子的还原能力. 在固定氯金酸用量时, C12OBA/金的物质的量比增加有利于获得小尺寸、高单分散性的憎水性纳米金颗粒, 而体系的极性增加则导致金粒子的尺寸增大、单分散性下降. 通过本实验方法可方便快速地合成尺寸约为5 nm的具有高度单分散的憎水性金纳米粒子. 相似文献
26.
Influences of the carrier concentration and mobility of heavily doped n-type Si80 Ge20 alloys on the thermoelectrical power factor are investigated. The experimental results indicate that thermoeleetrieal power factors of 32- 36μWem-1K^-2 eouM be consistently achieved with carrier concentrations of 2.1-2.9 × 10^20cm^-3 and carrier mobilities of 36-40 cm^2 V^-1s^-1. However, many samples with suitable carrier concentrations do not always have high mobilities and high power factors. Some possible explanations for this behaviour are discussed. 相似文献
27.
The aggregates in sodium dedecylsulphate(SDS)/dimethylbenzene/water systems have been investigated using dissipative particles dynamic(DPD) simulation method.Through analyzing three-dimensional structures of aggregates,three simulated results are found.One is the phase separation,which is clearly observed by water density and the aggregates in the simulated cell;another is the water morphology in reverse micelle,which can be found through the isodensity slice of water including bound water,trapped water and bulky water;the third is about the water/oil interface,i.e.,ionic surfactant molecules,SDS,prefer to exist in the interface between water and oil phase at the low concentraion. 相似文献
28.
29.
The structure of twelve-carbon monolayers on the H-terminated Si(111) surface is investigated by molecular simulation method. The best substitution percent on Si(111) surface obtained via molecular mechanics calculation is equal to 50%, and the (8×8) simulated cell can be used to depict the structure of alkyl monolayer on Si surface. After two-dimensional cell containing alkyl chains and four-layer Si(111) crystal at the substitution 50% is constructed, the densely packed and well-ordered monolayer on Si(111) surface can be shown through energy minimization in the suitable-size simulation cell. These simulation results are in good agreement with the experiments. These conclusions show that molecular simulation can provide otherwise inaccessible mesoscopic information at the molecular level, and can be considered as an adjunct to experiments. 相似文献
30.