位移损伤诱发CMOS图像传感器电荷转移损失退化的理论模拟研究

以4T PPD（4个晶体管的钳位光电二极管）型CMOS图像传感器为研究对象，开展注量为1×10¹¹,3×10¹¹,5×10¹¹,7×10¹¹,1×10¹² neutron/cm²的中子辐照下损伤模拟的研究，建立CMOS图像传感器的器件模型和不同注量中子辐照后位移损伤的缺陷模型；采用相关双采样技术测量由亮到暗连续两帧时序脉冲下浮置节点（FD）的输出值，建立测量电荷转移损失（CTI）的模拟方法；获得CTI随中子辐照注量的变化关系，分析CTI随中子累积注量的变化规律，结合中子辐照效应实验验证中子辐照诱发CTI退化的理论模拟计算结果的有效性。研究结果表明，CMOS图像传感器的位移损伤敏感区域为空间电荷区域，中子辐照后会在空间电荷区中引入位移损伤缺陷，这些缺陷通过不断俘获和发射载流子，使信号电荷不能快速转移到FD中，造成电荷转移损失；电荷转移损失随着中子辐照注量的增加而增大，二者在一定范围内呈线性关系。     

Chemical Conversion of a Coumarin Derivative Containing Arylhydrazono: Crystal Structures and Fluorescence Properties

An arylhydrazono-containing coumarin derivative(1) can undergo chemical conversions in two modes. When in the presence of Cu~(2+), a Cu~(2+)-promoted cyclization reaction was observed in aqueous acetonitrile and gives compound 2, while a ring-opening reaction occurs to give compound 3 in the absence of Cu~(2+). Both 2 and 3 were characterized by single-crystal X-ray diffraction. Compound 2 crystallizes in monoclinic C2/c space group with a = 26.606(5), b = 5.8142(12), c = 26.906(5) ?, β = 103.41(3)°, Z = 8, F(000) = 1696, μ = 0.186 mm~(-1), R = 0.0487 and wR = 0.1129. Compound 3 crystallizes in monoclinic P21/n space group with a = 9.917(2), b = 13.644(3), c = 15.912(3) ?, β = 95.38(3)°, Z = 4, F(000) = 896, μ = 0.182 mm~(-1), R = 0.0769 and w R = 0.1617. The spectroscopic studies show that compound 2 exhibits strong fluorescence emission.     

Competition between α-decay and β-decay for heavy and superheavy nuclei

In this work, the β-stable region for Z 90 is proposed based on a successful binding energy formula.The calculated β-stable nuclei in the β-stable region are in good agreement with the ones obtained by Mo¨ller et al. The half-lives of the nuclei close to the β-stable region are calculated and the competition between α-decay andβ-decay is systematically investigated. The calculated half-lives and the suggested decay modes are well in line with the experimental results. The decay modes are mostly β--decay above the β-stable region. Especially for Z 111,all the decay modes are β--decay. Regarding the nuclei above the β-stable region, α-decay and β--decay(α+β-)can occur simultaneously when Z 112. This is a very interesting phenomenon. The competition between α-decay and β-decay is very complex and drastic below the β-stable region. The predictions for half-lives and decay modes of the nuclei with Z =107–110 are presented in detail.     

Effects of chain entanglement on liquid-liquid phase separation behavior of LCST-type polymer blends: Cloud point and decomposition rate

By preparing homogenous blend samples with different degrees of chain entanglement, we report an anomalous contribution of chain entanglement to phase separation temperature and rate of poly(methyl methacrylate)/poly(styrene-comaleic anhydride)(PMMA/SMA) blends presenting a typical lower critical solution temperature(LCST) behavior. The meltmixed PMMA/SMA blends with a higher chain entanglement density present a lower cloud point(Tc) and shorter delay time, but lower phase separation rate at the given temperature than solution-cast ones, suggesting that for the polymer blends with different condensed state structure, thermodynamically more facilitation to phase separation(lower Tc) is not necessarily equivalent to faster kinetics(decomposition rate). The experimental results indicate that the lower Tc of melt-mixed sample is ascribed to smaller concentration fluctuation wavelength(Λm) induced by higher entanglement degree, while higher entanglement degree in melt-mixed sample leads to a confined segmental dynamics and consequently a slower kinetics(decomposition rate) dominated by macromolecular diffusion at a comparable quench depth. These results reveal that the chain packing in polymer blends can remarkably influence the liquid-liquid phase separation behavior, which is a significant difference from decomposition of small molecular mixtures.     

基于本征正交分解的串列叶栅多目标气动优化研究

为提高压气机串列叶栅复杂气动构型优化设计的效率,本文基于本征正交分解(POD)理论,建立了集几何外形参数化、样本空间降维、气动性能求解、降维模型构建和遗传算法寻优于一体的串列叶栅高效优化设计系统,针对叶型型面和叶片相对位置关系参数,开展了多目标优化设计工作。在7°攻角工况下,优化后的串列叶栅的静压升提高了0.53%,总压损失系数下降了9.25%,其他攻角条件下叶栅性能同样也得到了改善。与传统CFD方法相比,极大提高了优化效率,与基于Kriging代理模型相比,本文发展的优化系统由于缩小了设计变量空间,提高了优化的迭代效率,收敛耗时仅为Kriging代理模型的0.0796%。此外,基于POD方法的优化设计系统具有更高的建模精度,使串列叶栅获得了更高的静压升和更低的总压损失系数。优化后的串列叶栅节距系数增大、弯角比减小,减小了掺混损失,抑制了流动分离,改善了全攻角范围内的气动性能。     

CAEPXFEL波荡器束线初步物理设计

中国工程物理研究院计划开展XFEL光源的研制,主要通过电子束在波荡器中的辐射特性产生硬X射线。根据理论分析和数值模拟,在电子束最高能量可达12GeV的实际条件下,初步设计了一条间隙可调的真空外波荡器束线,波荡器分为25段,每段长3.86m,间隙7~10mm,周期长度25.4mm,磁场0.636~1.03T,束线总长120m左右,辐射光子能量为3~25keV。     

自由电子激光摇摆器磁测系统

根据理论分析及实际加工水平,设计了一套摇摆器磁场测量系统,同时对影响磁测系统整体性能的主要参数进行了详尽分析。摇摆器磁测装置主要由气浮运动平台、测磁设备及控制系统组成,其主要功能是对霍尔探头的位置与磁场数据进行高精度测量及同步采集。主要参数如下:z向定位精度小于5μm,重复定位精度小于2μm;霍尔探头的测量精度为0.05%,重复测量精度为0.01%,响应频率为1kHz;数据采集卡的采样率不小于1000。     

基于调频Z变换的均匀线列阵恒定束宽波束形成器设计

提出了基于调频Z变换(CZT)的宽带恒定束宽波束形成(CBB)方法:假设在每个子带内,各方位波束的权系数相同,推导得到:每个频率子带的权系数序列与参考频率的权系数序列的频谱相同,而在频率轴上满足比例伸缩关系,比例尺度为参考频率与相应频率子带的中心频率之比。依据此设计思想,给出有效孔径不变的CZT法(CZTIA)和有效孔径变化的CZT法(CZTVA)两种CBB实现方法。它们均是由参考频率的权系数序列,通过设定不同的参数值,采用CZT快速计算各个子带的权系数序列的频谱,然后通过傅里叶反变换便可得到相应频率子带的权系数序列。计算机仿真结果验证了理论分析的正确性。     

基于网上拍卖的共同价值托投标分析

基于信息不对称条件下的共同价值模型,刻画了网上拍卖过程中可能存在的托投标行为,并运用博弈理论结合竞价关系求解了竞标者的赢标概率和最优竞价策略．研究发现,在共同价值模型下,参与竞标的人数与嬴者诅咒的发生存在联系;在最高出价者赢标的概率模型基础上,分别建立了是否存在托投标行为时的竞标者收益模型,并求解了竞标者的均衡竞价策略．     

聚乙二醇双水相萃取光度法测定铬(Ⅵ)

通过研究二苯碳酰二肼(DPC)-铬(Ⅵ)配合物在聚乙二醇(PEG)2000-Na2SO4双水相中的显色和萃取分离条件,建立了集萃取分离和测定Cr6+于一身的双水相萃取光度分析方法。对双水相体系中PEG溶液、Na2SO4和二苯碳酰二肼的用量以及溶液酸度进行了优化,探讨了共存离子对Cr6+萃取测定的影响。实验表明,在0.16mol/L的H3PO4溶液中,二苯碳酰二肼与Cr6+形成的配合物被萃取到PEG相,最大吸收波长为545nm,表观摩尔吸光系数为4.3×104L.mol-1.cm-1。Cr6+的质量浓度在0.05～13.0μg/mL的范围内符合比尔定律,最低检出限为0.029μg/mL,5μg/mL标准溶液的相对标准偏差为1.3%。本方法用于测定含铬工业废水中的Cr6+,结果与原子吸收光谱法测定值相符,不同水平的回收率为96.7%～99.8%。