EFFECT OF ATOMIC HYDROGEN ON THE ACETYLENE-ADSORBED Si(100)(2×1) SURFACE AT ROOM TEMPERATURE

High resolution electron energy loss spectroscopy, low energy electron diffraction and quadrupole maas spectrometer (QMS) have been employed to study the effect of atomic hydrogen on the acetylene-saturated pre-adsorbed Si(100)(2×1) surface and the surface phase transition at room temperature. It is evident that the atomic hydrogen has a strong effect on the adsorbed C₂H₂ and the underlying surface structure of Si. The experimental results show that CH and CH₂ radicals co-exist on the Si surface after the dosing of atomic hydrogen; meanwhile, the surface structure changes from Si(100)(2×1) to a dominant of (1×1). These results indicate that the atomic hydrogen can open C=C double bonds and change them into C-C single bonds, transfer the adsorbed C₂H₂ to C₂H_x(x = 3,4) and break the underlying Si-Si dimer, but it cannot break the C-C bond intensively. The QMS results show that some C₄ species axe formed during the dosing of atomic hydrogen. It may be the result of atomic hydrogen abstraction from C₂H_x which leads to carbon catenation between two adjacent C-C directs. The C₄ species formed are stable on Si(100) surfaces up to 1100 K, and can be regarded as the potential host of diamond nucleation.     

ELECTRONIC STRUCTURE STUDIES OF THE C60 FILM CONDENSED ON 2H-MoS2(0001) SURFACE

The electronic structure and vibrational spectrum of the C₆₀ film condensed on a 2H- MoS₂(0001) surface have been investigated by X-ray photoelectron spectroscopy (XPS), ul-traviolet photoelectron spectroscopy (UPS), Auger electron spectroscopy (AES) and infrared high-resolution electron-energy-loss spectroscopy (HREELS). AES analysis showed that at low energy side of the main transition, C₆₀ contains a total of three peaks just like that of graphite. However, the energy position of the KLL main Auger transition of C₆₀ looks like that of diamond, indicating that the hybridization of the carbon atoms in C₆₀ is not strictly in sp²- bonded state but that the curvature of the molecular surface introduces some sp²pz- bonded character into the molecular orbitals. XPS showed that the C 1s binding energy in C₆₀ was 285.0eV, and its main line was very symmetric and offered no indication of more than a single carbon species. In UPS measurement the valence band spectrum of C₆₀ within 10eV below the Fermi level (E_F) shows a very distinct five-band structure that character-izes the electronic structure of the C₆₀ molecule. HREEL results showed that the spectrum obtained from the C₆₀ film has very rich vibrational structure. At least, four distinct main loss peaks can be identified below 200 meV. The most intense loss was recorded at 66 meV, and relatively less intense losses were recorded at 95, 164 and 197meV at a primary energy of electron beam E_P = 2.0eV. The other energy-loss peaks at 46, 136, 157 and 186meV in HREEL spectrum are rather weak. These results have been compared to infrared spectrum data of the crystalline solid C₆₀ taken from recent literatures.     

ELECTRONIC STRUCTURE STUDIES OF THE C60 FILM CONDENSED ON 2H-MoS2(0001) SURFACE

The electronic structure and vibrational spectrum of the C₆₀ film condensed on a 2H- MoS₂(0001) surface have been investigated by X-ray photoelectron spectroscopy (XPS), ul-traviolet photoelectron spectroscopy (UPS), Auger electron spectroscopy (AES) and infrared high-resolution electron-energy-loss spectroscopy (HREELS). AES analysis showed that at low energy side of the main transition, C₆₀ contains a total of three peaks just like that of graphite. However, the energy position of the KLL main Auger transition of C₆₀ looks like that of diamond, indicating that the hybridization of the carbon atoms in C₆₀ is not strictly in sp²- bonded state but that the curvature of the molecular surface introduces some sp²pz- bonded character into the molecular orbitals. XPS showed that the C 1s binding energy in C₆₀ was 285.0eV, and its main line was very symmetric and offered no indication of more than a single carbon species. In UPS measurement the valence band spectrum of C₆₀ within 10eV below the Fermi level (E_F) shows a very distinct five-band structure that character-izes the electronic structure of the C₆₀ molecule. HREEL results showed that the spectrum obtained from the C₆₀ film has very rich vibrational structure. At least, four distinct main loss peaks can be identified below 200 meV. The most intense loss was recorded at 66 meV, and relatively less intense losses were recorded at 95, 164 and 197meV at a primary energy of electron beam E_P = 2.0eV. The other energy-loss peaks at 46, 136, 157 and 186meV in HREEL spectrum are rather weak. These results have been compared to infrared spectrum data of the crystalline solid C₆₀ taken from recent literatures.     

MW级峰值功率掺钛蓝宝石激光振荡器

在常规重复频率77 MHz掺钛蓝宝石飞秒激光器的基础上,通过腔内引入Herriott型多通望远镜系统增加总腔长及对腔内色散的深入分析和实验控制,实现了低重复频率、高脉冲能量飞秒激光振荡的稳定运行.在连续功率8.2 W的532 nm激光抽运下,得到了重复频率11 MHz、单脉冲能量达72.73 nJ、对应峰值功率MW量级的结果.相对80 MHz重复频率下6.25 nJ的单脉冲能量及150 kW的峰值功率,其输出能力提高了约一个量级. 关键词： 飞秒激光 掺钛蓝宝石激光器 低重复频率 MW     

α稳定噪声驱动的非对称双稳随机共振现象

以微弱周期信号激励的非对称双稳系统为模型, 以信噪比增益为指标, 首先针对加性和乘性α 稳定噪声共同作用的随机共振现象展开了研究, 然后针对单独加性α 稳定噪声激励的随机共振现象进行了研究, 探究了α 稳定噪声特征指数α 和对称参数β 分别取不同值时, 系统结构参数a, b, 刻画双稳系统非对称性的偏度r以及α 稳定噪声强度放大系数Q或D对非对称双稳系统共振输出的作用规律. 研究结果表明, 无论在加性和乘性α 稳定噪声共同作用下还是在单独加性α 稳定噪声作用下, 通过调节a和b或者r均可诱导随机共振, 实现微弱信号的检测, 且有多个参数区间与之对应, 这些区间不随α 或β 的变化而变化; 在研究噪声诱导的随机共振现象时发现, 调节噪声强度放大系数也可使系统产生随机共振现象, 且达到共振状态时D的区间也不随α 或β 的变化而变化. 这些结论为α 稳定噪声环境下参数诱导随机共振中系统参数以及噪声诱导随机共振中噪声强度的合理选取提供了依据.     

高等数学教学中的素质教育

本文介绍了数学素质的界定,阐述了高等数学教学中素质教育的必要性和重要性,指出了素质教育是高等数学教学改革的核心与根本目的,并且提出了加强数学素质教育的具体措施。     

α稳定噪声驱动的非对称双稳随机共振现象

以微弱周期信号激励的非对称双稳系统为模型,以信噪比增益为指标,首先针对加性和乘性α稳定噪声共同作用的随机共振现象展开了研究,然后针对单独加性α稳定噪声激励的随机共振现象进行了研究,探究了α稳定噪声特征指数α和对称参数β分别取不同值时,系统结构参数a,b,刻画双稳系统非对称性的偏度r以及α稳定噪声强度放大系数Q或D对非对称双稳系统共振输出的作用规律.研究结果表明,无论在加性和乘性α稳定噪声共同作用下还是在单独加性α稳定噪声作用下,通过调节a和b或者r均可诱导随机共振,实现微弱信号的检测,且有多个参数区间与之对应,这些区间不随α或β的变化而变化;在研究噪声诱导的随机共振现象时发现,调节噪声强度放大系数也可使系统产生随机共振现象,且达到共振状态时D的区间也不随α或β的变化而变化.这些结论为α稳定噪声环境下参数诱导随机共振中系统参数以及噪声诱导随机共振中噪声强度的合理选取提供了依据.     

钒氧酞菁薄膜瞬态光电压性能的研究

本文分别用1064nm, 532nm和 355nm激发波长的YAG脉冲激光对所制备的phase Ⅱ结构钒氧酞菁膜Al\phase ⅡVOPc\ITO夹心电池进行瞬态光电压响应研究.随着3种波长激发光脉冲强度的增加, 瞬态光电压信号均增强. 激发光波长1064nm、532nm处于酞菁膜Q-带吸收区肩部, 光电压的极性与激发光入射方向无关, 均为负信号; 而激发光波长 355nm处于酞菁膜B-带, 光电压的极性与激发光入射方向有关, 从ITO极方向激发产生正电压信号, 从A1极激发产生负电压信号. 激发光波长对夹心电池的光电压产生有明显的作用, 光电压产生过程中应存在不同的机理. 这与前文^[1]对同一夹心电池稳态光电压响应研究所推断的结论一致.     

面向21世纪《工程数学》课程教学改革的构想与实践

本阐述了《工程数学》教学改革的现状、意义、目的以及我们的认识、作法与问题．     

中药配伍的统一分析方法研究 Ⅱ.拟合定量

 配伍过程中物质组分的浓度变化需要进行定量 ,但复方中大量的重叠色谱峰影响定量的准确性。而在色谱理论基础上发展起来的拟合定量技术 ,可以对重叠色谱峰进行拟合定量。在统一分离和复方中单味药的特征物质组分得到识别的基础上 ,以黄芪、当归用量变化时 ,复方“当归补血汤”中黄芪、当归的特征物质组分的拟合定量为实例 ,介绍了中药配伍过程中定量的手段和研究方法