椭圆纳米盘中磁涡旋结构的方位角自旋波模式

本文针对坡莫合金椭圆形盘中的磁涡旋结构, 采用微磁学模拟与傅里叶分析相结合的技术研究了磁涡旋自旋波的本征激发模式. 通过沿样品短轴方向施加一面内方向的脉冲磁场, 观察到一系列方位角自旋波模式. 观察到的自旋波模式具有两重对称性, 可以通过C₂群理论来进行类型的划分. 此外, 自旋波模式的频率随着方位角指标的变化而线性增加. 模拟结果显示样品的平均交换能量密度明显的高于平均静磁能量密度; 局域交换能量密度主要集中在涡核初始位置, 而局域静磁能量密度主要分布在长轴附近. 交换作用对受限于铁磁薄膜椭圆盘中的单个涡旋态的能量要起主导作用, 从而导致方位角自旋波模式频率随着方位角指标的增加而增加.     

Synthesis,Structure and Elastic Properties of a New Hybrid Perovskite Material: [C6H14N2]KBr3

A new hybrid organic-inorganic perovskite(HOIP)material,[C6H14N2]KBr3,has been synthesized via hydrothermal method and fully characterized.[C6H14N2]KBr3 has a three-dimensional perovskite structure and crystalizes in a trigonal P3121 space group.The elastic properties of[C6H14N2]KBr3 were fully calculated via the density functional theory calculations,which reveal the elastic moduli(11.54~14.07 GPa),shear moduli(4.56~5.68 GPa),Poisson’s ratios(0.18~0.32),bulk modulus(8.51 GPa)and acoustic velocity(2.57~2.74 kms^-1).Additional nanoindentation experiments in the form of single-crystals confirmed the validity of our theoretical approach.[C6H14N2]KBr3 exhibits higher stiffness and thermal stability than the well-known photovoltaic CH3NH3PbI3,which makes it worthwhile for exploring optoelectronic properties.     

重离子辐射提高腺病毒介导小鼠黑色素瘤细胞转染率的研究

探讨12C6+ 离子束辐射对用带有绿色荧光蛋白基因的缺陷性腺病毒（AdCMV GFP）转染小鼠黑色素瘤细胞(B16细胞系)的影响。 采用不同剂量的12C6+ 重离子束辐射经AdCMV GFP 转染的B16细胞， 利用流式细胞仪检测腺病毒的转染率。 结果表明， 12C6＋重离子束辐射能提高腺病毒对B16细胞的转染率， 且具有量效关系。 此外， 先转染后辐射法比起先辐射后转染法能更显著地提高转染率。The effect of 12C6+ beam irradiation on AdCMV GFP (a replication deficient recombinant adenoviral vector containing CMV promoter and green fluorescent protein) gene transfection efficiency for murine melanoma cell B16 has been investigated. B16 cells infected with AdCMV GFP were irradiated by different doses of 12C6+ beam. The transfection efficiency was assessed by flow cytometry (FCM). Results show that 12C6+ beam irradiation can improve tansfection efficiency of AdCMV GFP on murine melanoma cell B16 in a dose dependent manner. In addition， the tansfection efficiency in pre tranfection plus irradiation group is higher than that in pre irradiation plus tranfection group at the same dose irradiation dose.     

双诱导映射(L)集合范畴的幂对象及子对象分类子探讨

引入双诱导映射(L)集合范畴的幂对象及子对象分类子的概念,并分别讨论它们的判别定理,同时给出它们的具体结构.     

X-Ray Emission from Zr, Mo, In and Pb Targets Bombarded by Slow Highly Charged Ar^q＋（q = 13, 14, 15, 16） Ions

We study the L x-ray emission from Zr, Mo and In targets and M x-ray emission from Pb target under bombardment of low energy Ar^q (q = 13, 14, 15, 16) ions. The relative x-ray yields were measured in the projectile kinetic energy range 210-360 keV. It is found that the relative x-ray yields from Zr, Mo and Pb targets increase with the increasing projectile kinetic energy for Ar^14 and Ar^16 projectiles and depend on the potential energy of the projectile remarkably.     

Quantum plasmons in the hybrid nanostructures of double vacancy defected graphene and metallic nanoarrays

We study the plasmonic properties of hybrid nanostructures consisting of double vacancy defected graphene(DVDGr)and metallic nanoarrays using the time-dependent density functional theory. It is found that DVDGr with pure and mixed noble/transition-metal nanoarrays can produce a stronger light absorption due to the coherent resonance of plasmons than graphene nanostructures. Comparing with the mixed Au/Pd nanoarrays, pure Au nanoarrays have stronger plasmonic enhancement. Furthermore, harmonics from the hybrid nanostructures exposed to the combination of lasers ranged from ultraviolet to infrared and a controlling pulse are investigated theoretically. The harmonic plateau can be broadened significantly and the energy of harmonic spectra is dramatically extended by the controlling pulse. Thus, it is possible to tune the width and intensity of harmonic spectrum to achieve broadband absorption of radiation. The methodology described here not only improves the understanding of the surface plasmon effect used in a DVDGr-metal optoelectronic device but also may be applicable to different optical technologies.     

查尔酮衍生物E-2-(甲氨基)-7-(3-(吡啶基)丙烯酰基)卓酮的合成(英文)

以2-乙酰基-7-(甲氨基)卓酮(1)为原料,经由与各种吡啶醛的Claisen-Schmidt缩合反应得到查尔酮衍生物E-2-(甲氨基)-7-(3-(吡啶基)丙烯酰基)卓酮(2～5).全部合成产物均为新化合物,未见文献报道;其结构均由红外光谱分析、1H核磁共振、质谱及元素分析得以证实.     

An ab initio Study on the Structural and Bonding Properties of Li_2Si_3O_7

A theoretical study on the structural and electronic properties of Li2Si3O7 is performed by using density functional theory(DFT) method.The molecular structure of the crystal and two kinds of [SiO4]-tetrahedra with different number of non-bridging oxygen(Qn) are analyzed.The structure of crystal Li2Si3O7 can be considered as a framework of corner-sharing tetrahedra.From the band structure(BS),total density of state(TDOS) and projected density of state(PDOS) of the crystal,the structures of Q3,Q4,and LiO4 tetrahedra as well as their bonding characters are presented.For lithium trisilicate,we find the bond cation-NBO(nonbridging oxygen and oxygen atoms bonding to one silicon atom only) is stronger than the bond cation-BO(bridging oxygen and oxygen atoms bonding to two silicon atoms).By analyzing the ionicity of two different types of bonds of silicon-oxygen according to the Mulliken population analysis,we also find that the Si-NBO bonds have higher ionicity than Si-BO for crystalline lithium trisilicate,which agrees with other lithium silicates.     

模拟微重力条件下C离子辐射对小鼠生殖器官的影响

探究模拟微重力条件下不同剂量C离子辐射对雄性动物生殖器官的急性影响, 以期了解空间环境辐射所致机体生殖系统的损伤。采用小鼠尾部悬吊模型地面模拟微重力状态1周后, 利用重离子加速器提供的C离子辐照处理, 检测了生殖器官脏器系数及精子密度、组织形态变化、DNA损伤以及细胞凋亡各项指标。结果表明, 微重力和C离子辐射均能引起睾丸损伤, 且1 Gy单纯辐照组中损伤最为严重。此外发现, 模拟微重力能够在一定程度上降低辐射诱导的损伤, 其内在机制有待于进一步的研究。In this paper it was investigated that the effect of modeled microgravity on the acute injury induced by low doses of carbon ions in the male reproductive organs of mice, assessing the risk associated with the space environments. In our study, outbred Kunming mice were stimulated in microgravity by tail suspension, and then were irradiated with the low doses of carbon ions diliuered by HIRFL, and measured the testis and epididymis coefficient, sperm number of epididymis, histological alterations, DNA strand breaks and cell apoptosis. The results demonstrated that carbon ions and stimulated microgravity could induce the damage in the present study. Moreover, most serious injury all occurred in the irradiation group. In addition, it was also found that the damage of the carbon ion irradiation combined microgravity group were lower than those of the irradiation group, while the related mechanism needs the further investigation.     

Spectroscopic investigations on NO+(x1∑+,a3∑+,A1Ⅱ) ion using multi-reference configuration interaction method and correlation-consistent sextuple b

Three low-lying electronic states (x¹∑⁺,a³∑⁺,and A¹Ⅱ) of NO⁺ ion are studied using the complete active space self-consistent-field (CASSCF) method followed by highly accurate valence internally contracted multi-reference configuration interaction (MRCI) approach in combination of the correlation-consistent sextuple basis set augmented with diffuse functions, aug-cc-pV6Z. The potential energy curves (PECs) of the NO⁺(x¹∑⁺,a³∑⁺,A¹Ⅱ) are calculated. Based on the PECs, the spectroscopic parameters R_e, D_e, ω_e, ω_eχ_e, α _e, B_e, and D₀ are reproduced, which are in excellent agreement with the available measurements. By numerically solving the radial Schrödinger equation of nuclear motion using the Numerov method, the first 20 vibrational levels, inertial rotation and centrifugal distortion constants of NO⁺(x¹∑⁺,a³∑⁺,A¹Ⅱ) ion are derived when the rotational quantum number J is equal to zero (J = 0) for the first time, which accord well with the available measurements. Finally, the analytical potential energy functions of these states are fitted, which are used to accurately derive the first 20 classical turning points when J = 0. These results are compared in detail with those of previous investigations reported in the literature.