聚γ-缩水甘油醚氧丙基三甲氧基硅烷的合成与表征

采用双金属氰化络合物催化剂(DMC)催化γ-缩水甘油醚氧丙基三甲氧基硅烷(KH560)开环聚合,合成出结构规整的均聚产物PKH560.通过FTIR2、9Si-NMR1、H-NMR对聚合物的结构进行表征.结果表明,以DMC为催化剂,可以实现KH560的开环聚合,合成出分子量较大的目标产物PKH560.凝胶渗透色谱与多角度激光联用仪(GPC/MALLS)测得该聚合物PKH560的数均分子量大于1×104,分子量分布介于1.10与1.35之间;分析不同聚合时间PKH560的数均分子量与单体转化率之间的关系可知,聚合物的数均分子量Mn与单体转化率呈线性增长关系,聚合物的分子量分布较窄(Mw/Mn=1.10~1.35),表明该聚合反应具有活性聚合的特征.     

核磁共振研究蛋白二级结构的方法

核共振共振法常规应用于解析化学物质结构和反应性能,现已发展成为生物化学和分子生物学的重要实验技术,尤其是在确定溶液中蛋白和多肽结构方面起着其它物理分析方法不可比拟的作用。文章综述了化学位移,偶合常数。核Ｏｖｅｒｈａｕｓｅｒ效应（ＮＯＥ）以及同位素交换等确定蛋白或多肽二级结构的方法。     

光纤陀螺用超辐射发光二极管启动模型研究

为了实现光纤陀螺的快启动, 从超辐射发光二极管(SLD)发光机理出发, 通过分析光源的驱动电流和管芯温度在上电后的变化规律, 建立了SLD的启动模型, 找出了影响SLD启动时间的因素。用高速数据采集卡测得SLD的常温启动时间约为3~4s, 由温控系统系统引起的功率波动误差为4.5%, 波长的漂移量为0.92nm。实验测试结果与建立的理论模型相符, 从理论上提出了缩短SLD启动时间和实现陀螺快启动的方法。     

Study of multipacting effect in sub-harmonic buncher of SSRF linac

During the design process, multipacting effect has been taken into consideration using a 2D simulation code MultiPac and all of the corners are rounded to suppress the multipacting effect in the pill-box cavity. However, unexpected multipacting effect prevents the increase of the input power when the magnetic field of focusing coils is added after adequate conditioning and a novel method is adopted to suppress it by introducing extra coils to counteract the field. This paper focuses on the simulation of multipacting effect in different magnetic field configurations. The experimental observations and simulation results of multipacting effect are presented and details of the multipacting process are also analyzed.     

基因算法在光阴极注入器优化设计中的应用

基于正在建设的大连自由电子激光装置,研究了基因算法在注入器优化设计中的系统应用。与传统的注入器优化方法相比较,基因算法在多变量、多目标注入器优化问题中具有优化效率高、优化结果精确的优势;通过采用权重因子的方法将多目标问题转化为单目标优化问题,大大简化了基因算法优化流程;光阴极注入器对束流稳定性要求严格,通过基因算法优化使束流的到达时间抖动控制到150fs,满足束流稳定性的要求。     

基于光学遥感图像的南海北部内孤立波振幅反演模型与应用

收集2015年1月至2018年12月共计4年的MODIS光学遥感图像,利用神经网络算法建立适用于南海北部深海与浅海的内孤立波振幅反演模型。模型的计算结果与现有的南海实测数据对比,无论对于浅海(文昌海域)还是深海(东沙岛附近海域和深海盆地),反演精度都高于15%。利用模型得到了南海北部内孤立波的振幅分布,发现振幅分布与水深呈正相关,相关系数为0.81。计算了南海北部文昌海域、东沙岛附近海域以及深海盆地的内孤立波振幅分布,发现同一条内孤立波,振幅不同。南海北部文昌海域、东沙岛附近海域以及深海盆地的单条内孤立波振幅与水深呈正相关,相关系数分别为0.79,0.91,0.81。本文为南海北部海域深海与浅海的内孤立波振幅反演提供借鉴。     

CaGdAlO4:Eu3+荧光粉的制备及其X射线存储特性研究

采用自蔓延燃烧法制备了不同Eu~(3+)掺杂浓度的CaGd_1-xAlO_4:xEu~(3+)(CGA:xEu~(3+))X射线荧光粉材料.当Eu~(3+)掺杂浓度在0～0.150范围时,Eu~(3+)取代了基质中处于无中心反演对称的格位,使CGA:xEu~(3+)样品呈现为单一相,并可观察到红光发射.当x=0.100时,红光发射强度达到最大.随着Eu~(3+)离子浓度增加,Eu~(3+)离子之间的距离减小,增大了Eu~(3+)→Eu~(3+)→猝灭中心的能量传递几率,出现了发光猝灭现象.实验发现,当Eu~(3+)掺杂浓度为0.003时,光激励发光强度最大.对CGA:0.003Eu~(3+)样品进行氮气气氛热处理后,CGA中的OH~-离子基团减少,红光发射的发光强度增强.热释曲线表明CGA:0.003Eu~(3+)样品中存在两种类型的陷阱,其陷阱深度分别为0.79eV和0.93eV.经氮气热处理后的CGA:0.003Eu~(3+)样品,较深陷阱数量显著增多,光激励发光强度增强,光存储性能显著提高.随着X射线辐照时间的增加,X射线吸收剂量在0～11.8Gy范围内大致呈线性增加的趋势.当X射线吸收剂量为1.2Gy时,以在氮气气氛下热处理CGA:0.003Eu~(3+)圆片为成像板,得到了较高质量X射线红色成像.实验结果表明,Eu~(3+)掺杂的CGA X射线荧光粉材料在以CCD为光探测器的计算机X射线医学成像技术中有潜在的应用前景.     

New linear accelerator （Linac） design based on C-band accelerating structures for SXFEL facility

A C-band accelerator structure is one promising technique for a compact XFEL facility. It is also attractive in beam dynamics in maintaining a high quality electron beam, which is an important factor in the performance of a free electron laser. In this paper, a comparison between traditional S-band and C-band accelerating structures is made based on the linac configuration of a Shanghai Soft X-ray Free Electron Laser (SXFEL) facility. Throughout the comprehensive simulation, we conclude that the C-band structure is much more competitive.     

Multipacting saturation in parallel plate and micro-pulse electron gun

A novel parallel plate model is proposed that divides the electron cloud into three parts at saturation,and it is studied in detail using both an analytical approach and particle-in-cell(PIC) code simulations. As one part of the electron cloud, ribbons modes are suggested by tracking the trajectory of individual particles, and the aim of this mode form is to simplify the progress of the multipacting effect in the parallel plate so as to be eliminated by optimizing RF parameters. The micro-pulse electron gun(MPG) has demonstrated the potential to address the need for high peak and average current electron beams, hence studying the multipacting in MPG is essential. On the basis of studying multipacting in the parallel plate, it is clear that increasing the cavity voltage is of interest in yielding high quality beams in the gun.     

逐孔起爆震动参数预报的BP神经网络模型

根据神经网络理论,结合逐孔起爆技术的特点,建立了爆破震动参数预报的BP网络模型。以某矿 山深孔台阶爆破为例,利用逐孔起爆过程中收集的原始资料和爆破震动监测数据,对建立的BP网络模型进 行了训练和应用。与实测值比较后发现,BP网络模型的预报结果更接近实测值。