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51.
 采用同位素示踪技术,系统地研究了K2CO3/CH3I促进的CO2插入甲醇直接合成碳酸二甲酯(DMC)的反应机理. 结果表明,固体碱碳酸钾催化剂直接参与了DMC的合成过程, DMC分子中的羰基由CO2插入甲醇后形成,两个甲基分别来源于甲醇和碘甲烷. 本文将以往文献中提出的DMC生成机理和二甲醚生成机理结合起来,并对其进行适当补充后,可以很好地解释实验结果.  相似文献   
52.
基于线型腔掺铒光纤激光器的光纤光栅传感实验研究   总被引:1,自引:0,他引:1  
提出了一种基于线型腔掺铒光纤激光器的光纤布拉格光栅传感解调系统,并进行了理论分析和实验验证。此传感系统具有稳定性好、信噪比高、结构简单等特点。实验结果表明:在常温下光纤光栅传感解调系统能很好的实现光纤光栅传感信号的传感和检测;15m掺铒光纤用作增益介质可以产生较大信噪比的稳定激光输出,系统在4nm范围内的解调精度为0.04nm。  相似文献   
53.
罗伟  张民  周平  殷红成 《中国物理 B》2010,19(8):84102-084102
<正>An iterative method in the Kirchhoff approximation is proposed for high frequency multiple electromagnetic scattering from two-dimensional dielectric sea surface.The multiple interaction of the scattering field is characterized with the corrected electromagnetic currents of the wind-driven sea surface.The actual surface currents are approximated with the iterative solution of the corrected currents.A newly developed sea spectrum,Elfouhaily spectrum,is utilized to build the sea surface model.The shadowing correction is improved by the Depth-Buffer algorithm.The validity of the iterative Kirchhoff approximation is verified by the agreement of backscattering coefficients with the measured data.  相似文献   
54.
讨论了刚体转动惯量实验中数据处理过程的缺陷,通过Origin软件改进了数据处理过程,经过计算比较证明了方法改进后数据的精确度确实得到提高。  相似文献   
55.
Numerical modeling on the composite electromagnetic (EM) scattering from a two-dimensional (2-D) object located on a rough surface is presented by using the efficient method of fundamental solution (MFS). The proposed special choice of the MFS is an interesting alternative to the onerous mesh generation in the traditional numerical methods, particularly for the method of moment (MoM). There is no mesh scheme and singularity analysis, the field to be solved can be obtained directly in terms of the fundamental solutions of the appropriate wave equations. The numerical results are obtained and compared with the traditional MoM results, to demonstrate the accuracy and effectiveness of this technique.  相似文献   
56.
经含有羟基的二胺单体HAB与二酐单体 4 ,4′ (六氟异丙基 ) 双邻苯二甲酸酐 ( 6FDA)的缩聚反应 ,制备了含有羟基的先驱聚合物PI OH ,通过PI OH上羟基与肉桂酰氯的酯化反应 ,制备了侧链带有肉桂酸酯基团的光敏聚酰亚胺PI CI.用氢核磁共振 ( 1H NMR)分析、傅立叶红外光谱 (FTIR)分析等表征了上述聚合物的结构与感光性能 .用紫外 可见光谱 (UV Vis)等方法研究了PI CI的光交联反应 .聚合物PI CI旋镀膜经线性偏振光聚合技术 (LPP)处理并装配得到的液晶盒可使液晶分子很好地定向沿面排列 .上述实验表明 ,本文所合成的聚酰亚胺定向层材料是一种新的液晶光定向层材料  相似文献   
57.
Based on the double superimposition model, a sea slope model is obtained on the basis of the generated oceanic surface instead of being assumed as a Gaussian distribution model. Then, a summation formula of the backscattering coefficient is derived from the Bass Fuks two-scale model and its application is extended to the non-Gaussian oceanic surface with the help of simulated sea slopes, which can adequately reflect the non-Gaussian configuration of the sea surface. Finally, this scattering model is employed to describe the baekscattering configuration of sea surfaces in different sea states and wind directions, and is confirmed by several numerical examples.  相似文献   
58.
A time-domain surface integral equation (TDCFIE) approach is utilized to calculate the transient scattering from arbitrarily shaped, three-dimensional dielectric bodies. In conjunction with the marching-on-in-time (MOT) method, the TDCFIE-MOT method is used to derive explicit expressions for the present-time current as a function of the incident field. Sample results showing various geometries are presented and are compared with other numerical techniques. Finally, by an incident Gaussian plane tapered wave, transient scattering from the sea surface governed by Jonswap's sea spectra is computed.  相似文献   
59.
聂丁  张民 《中国物理 B》2010,19(7):74101-074101
Based on the local configuration angle division to select the corresponding method for electromagnetic scattering calculation from rough sea surface,this paper presents an angular cutoff composite model:when the local scattered angle is in the specular region that is given by an approximately 20 degrees cone around the specular direction,the Kirchhoff approximation is applied to evaluate the specular reflection,which dominates the total scattering in this region;the small perturbation method is employed to handle the diffuse reflection which is predominant as the local scattered angle is situated out of the specular region.Numerical results are compared with those of experimental and theoretical models in several configurations as a function of incident angle,wind speed,wind direction.The comparison of numerical results of other experimental and theoretical models in several configurations shows that the new composite model is robust to give accurate numerical evaluations for the sea surface scattering.  相似文献   
60.
本文介绍“Fuzzy信息处理与机器智能”国家自然科学基金重大项目第一子课题中的学术思想。这个子课题的任务是研制Fuzzy推理机,本文将对其中所依据的一种数学理论——真值流推理进行介绍。  相似文献   
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