利用聚合脂质体的沉淀可逆性固定STI及其PL-STI对胰蛋白酶的亲和作用

通过双功能试剂戊二醛、二甘醇二酸酐和1,4-丁二醇双缩水甘油醚等将大豆胰蛋白酶抑制剂STI固定到由二十五-10,12-二块-1-醇磷脂乙醇胺形成的聚合脂质体上.同时探讨了其作为亲和沉淀吸附剂对对胰蛋白酶的亲和作用.在PL沉淀过程中,胰蛋白酶有20%～60%从PL-STI上解离下来.PL-STI可作为酶的亲和沉淀吸附剂.     

熔融法转炉钢渣微晶玻璃的结构与性能研究

利用转炉钢渣制备出高性能的微晶玻璃,可有效提高其附加值,同时具有环保效益.本文以转炉钢渣为主要原料,通过组分设计,改变其掺人量,制备出了相应的基础玻璃与微晶玻璃.并通过XRD、DSC、FTIR、SEM以及抗折强度、密度、表面硬度等进行表征,获得了如下结果:转炉钢渣的掺量在45wt; ～ 55wt;之间变化时,均可以制备出微晶玻璃.随着CaO/SiO2的增加,有利于促进玻璃析晶,与此同时,会促进在架状结构的霞石晶相中析出聚粒状的二次晶相普通辉石.普通辉石晶相的析出不利于抗折强度的增长,但对密度和硬度均有所提高.当钢渣掺量为50wt;时,微晶玻璃的最高抗折强度为198.89 MPa,显微硬度为772 MPa,密度为2.86 g/cm3.     

Analysis of Aberrations in Laser-Focused Nanofabrication

Based on the semi-classical model, we analyse the motion equation of chromium atoms in the laser standing wave field under the condition of low intensity light field using fourth-order Adams-Moulton algorithm. The trajectory of the atoms is obtained in the standing wave field by analytical simulation. The image distortion coming from aberrations is analysed and the effects on focal beam features are also discussed. Besides these influences, we also discuss the effects on contrast as well as the feature width of the atomic beam due to laser power and laser beam waist. The simulation results have shown that source imperfection, especially the transverse velocity spread, plays a critical role in broadening the feature width. Based on these analyse, we present some suggestions to minimize these influences.     

Topological Dirac surface states in ternary compounds GeBi2Te4, SnBi2Te4 and Sn0.571Bi2.286Se4

Using high-resolution angle-resolved and time-resolved photoemission spectroscopy, we have studied the low-energy band structures in occupied and unoccupied states of three ternary compounds GeBi₂Te₄, SnBi₂Te₄ and Sn_0.571Bi_2.286Se₄ near the Fermi level. In previously confirmed topological insulator GeBi₂Te₄ compounds, we confirmed the existence of the Dirac surface state and found that the bulk energy gap is much larger than that in the first-principles calculations. In SnBi₂Te₄ compounds, the Dirac surface state was observed, consistent with the first-principles calculations, indicating that it is a topological insulator. The experimental detected bulk gap is a little bit larger than that in calculations. In Sn_0.571Bi_2.286Se₄ compounds, our measurements suggest that this nonstoichiometric compound is a topological insulator although the stoichiometric SnBi₂Se₄ compound was proposed to be topological trivial.     

中性钠原子在激光驻波场中的运动特性研究

基于半经典理论,分析了中性钠原子在激光驻波场中的受力特征,以此为基础分别对不同纵向运动速度和横向运动速度条件下中性钠原子的运动轨迹进行了仿真运算,得到了不同速度条件下中性钠原子的运动轨迹特征,基于累计算法进一步对不同速度条件下中性钠原子的沉积特性进行了仿真,当钠原子的纵向运动速度符合最可及速度(740 m/s)时,纳米沉积条纹的半高宽为2.78 nm,条纹对比度为38.5 ∶1,当纵向运动速度偏离最可及速度(350 m/s)时,纳米沉积条纹的半高宽为29.1 nm,其对比度下降为15 ∶1.而当中性钠原子 关键词： 原子光刻 激光驻波场 条纹半高宽 条纹对比度     

土壤源热泵在合肥地区规模化应用绩效研究

介绍了土壤源热泵的工作原理,探讨了土壤源热泵空调应用于中央空调系统的设计方法,以及其主要部件地热换热器的埋管方式、结构、管材、运行等特点。选取几种常用的冷热源系统与土壤源热泵系统进行比较,参考合肥地区的能源价格,计算各方案的运行成本,用动态费用年值法评价了各方案的经济性。最后,对土壤源热泵系统的节能减排量进行了分析。     

激光功率对铬原子束一维沉积的影响

以粒子光学方法为基础,利用适当步长的四阶Runge-Kutta算法模拟研究了准直铬原子束经过波长为425.55 nm,功率分别为3.93mW和40 mW的一维高斯激光驻波场汇聚作用后所沉积的一维条纹情况.在以上两种激光功率下,沉积条纹沿ox方向的结构质量的周期性相同,而沿着oy方向的结构质量却存在很大的差异:在3.93 mW时,每一根沉积条纹在oy方向上都非常清晰,并且半高宽在[-0.5,0.5](以激光束腰半径为单位)的区域内具有较好的一致性,对比度在[-0.2,0.2]区域内有较好一致性;在40mW时,每一根沉积条纹呈现出较为复杂的结构,在激光束的中轴区域附近[-1.08, 1.08]内,原本在3.93 mW时的一根条纹分裂成三根.另外,3.93 mW时y=0的平面内条纹情况和40 mW时y=±1.08平面内情况对应性很好,即平均间距为212.78nm,半高宽为21.65 nm,对比度为24.78.分析结果表明,较好地沉积条纹与适当激光功率有关.     

一种新颖的实现纳米条纹沉积方法研究

利用近共振激光驻波场操纵中性原子实现纳米量级条纹沉积技术是一种新型的研制纳米结构长度传递标准的方法,采用了一种新颖的方法,通过预准直孔的设定,将原子束在空间分成三部分,利用中间部分的原子束和近共振激光驻波场相互作用,在激光驻波场辐射压力作用下使原子按照特定周期沉积在基板上,从而实现纳米条纹的制作.利用两侧部分的原子束与探测激光束相互作用,通过其感生荧光来监测中间部分原子束沉积过程中的准直效果,从而为原子的沉积过程提供实时的原子束特性监测.最后对纳米沉积条纹在经由三狭缝预准直结构作用前后的效果进行了三维仿真,结果表明,未采用该三狭缝预准直结构时,纳米沉积条纹的半高宽为32nm,对比度为8∶1,而采用该三狭缝预准直结构之后,纳米沉积条纹的半高宽为6.2nm,对比度为28∶1,大大提高了纳米沉积条纹的质量.     

Temperature Evolution of Energy Gap and Band Structure in the Superconducting and Pseudogap States of Bi_2Sr_2CaCu_2O_(8+δ) Superconductor Revealed by Laser-Based Angle-Resolved Photoemission Spectroscopy

We carry out detailed momentum-dependent and temperature-dependent measurements on Bi_2Sr_2CaCu_2O_(8+δ)(Bi2212) superconductor in the superconducting and pseudogap states by super-high resolution laser-based angleresolved photoemission spectroscopy. The precise determination of the superconducting gap for the nearly optimally doped Bi2212(T_c= 91 K) at low temperature indicates that the momentum-dependence of the superconducting gap deviates from the standard d-wave form(cos(2Φ)). It can be alternatively fitted by including a high-order term(cos(6Φ)) in which the next nearest-neighbor interaction is considered. We find that the band structure near the antinodal region smoothly evolves across the pseudogap temperature without a signature of band reorganization which is distinct from that found in Bi_2Sr_2CuO_(6+δ) superconductors. This indicates that the band reorganization across the pseudogap temperature is not a universal behavior in cuprate superconductors.These results provide new insights in understanding the nature of the superconducting gap and pseudogap in high-temperature cuprate superconductors.     

烧结法制备高炉渣CMAS系统微晶玻璃的研究

利用高炉渣及其它辅助原料制备基础玻璃,采用一步烧结法制备主晶相为辉石的CaO-MgO-Al2O3-SiO2(CMAS)微晶玻璃.综合运用DSC,XRD以及场发射扫描电子显微镜等测试手段,分析热处理制度对高炉渣CMAS微晶玻璃的析晶行为及性能的影响.结果表明:随着热处理温度上升,微晶玻璃的主晶相均为辉石,次晶相均为长石,晶相析出量增加,微晶玻璃的体积密度及抗折强度均呈现先增后减趋势.随着热处理时间增加,微晶玻璃的体积密度及抗折强度均呈现下降趋势.当热处理温度为1020 ℃,晶化时间30 min时,样品的机械性能最好,体积密度为2.690 g·cm-3,抗折强度为67.00 MPa.