丙氨酸二肽分子二级结构与振动光谱特性

利用从头算方法探索蛋白质模型分子——丙氨酸二肽的二级结构布居特性以及体系势能变化. 引入对分子结构敏感的振动探针(酰胺振动吸收带), 借助其光谱表象, 寻求振动光谱参数与分子结构之间的联系. 研究结果表明: 丙氨酸二肽分子处于C_7eq构型(Φ/Ψ=-80°/80°)时具有最低能量值, 且分子易形成β折叠、PP_II、C₅及C₇等能量较低的稳定构型. 通过简正模式分析, 得到分子3N-6 个振动模式的吸收光谱, 并通过势能分布分析方法对分子骨架上酰胺振动吸收带的特征振动模式进行了指认. 重点考察分子骨架上酰胺-I带振动光谱参数与分子构型变化之间的相关性, 建立振动光谱参数与蛋白质二级结构之间的联系, 为在化学键水平上研究蛋白质的结构及其发挥作用的机制提供科学依据.     

乘积FC-空间中的不动点定理及其对广义约束多目标对策的应用文开庭

建立了乘积FC-空间中的Browder型不动点定理,作为应用,获得了FC-空间中广义约束多目标对策的弱Pareto平衡存在定理.我们的结论统一改进和推广了一些近期文献的已知结果.     

L-凸空间中新的不动点定理及其应用(英文)

In this paper, we present a new fixed point theorem in L-convex spaces and apply it to obtain a maximal element theorem, a variational inequality and a saddle point theorem in L-convex spaces.     

ICP-AES分析河套灌区盐碱地向日葵矿质元素吸收与积累

以HNO3+HClO4消解向日葵根、茎、叶、花盘等器官,采用ICP-AES测定河套灌区盐碱胁迫下向日葵植株对十种矿质元素的吸收和积累。结果表明:(1)Fe,Mn,Zn,Ca,Na在向日葵根部含量最高,K含量在茎中最高,B和Mg在叶中含量最高,花盘中P含量高于其他部位,Cu含量在向日葵各器官间无明显差异;(2)向日葵器官间矿质元素累积量差异表现为花盘中Ca,Mg,P,Cu,B,Zn累积量最高,根Na,Fe,Mn累积量最高,茎K累积量最高;(3)向日葵全株常量矿质元素累积量比值为K∶Ca∶Mg∶P∶Na=16.71∶5.23∶3.86∶1.23∶1.00,微量矿质元素积累量比值为Zn∶Fe∶B∶Mn∶Cu=56.28∶27.75∶1.93∶1.17∶1.00;(4)盐分胁迫对向日葵矿质元素吸收的影响因部位及元素种类各异,根部矿质元素含量对土壤盐分变化最为敏感,茎、叶次之,花盘元素含量变化动态较为复杂。     

Y模型四能级原子辅助光力学系统的多稳现象

本文对Y模型四能级原子辅助光力学系统的稳态特性进行了研究.结果发现,构成复合光力学系统的振动腔镜和被束缚在腔内的原子系综将随着弹簧劲度系数的减小,由单稳态过渡到多稳态.在劲度系数很大时,振动腔镜对整个光力学系统几乎无作用,光力学系统和处在腔中的原子系综都将出现一个稳态解.而当劲度系数足够小时,振动腔镜的稳态位移出现了多稳现象,随之对处于光力学腔中的原子系综的稳态行为也产生了影响,不但使得原子系综的极化率呈现出多个稳态解,同时使得腔中的原子系综对探测光的吸收和色散也发生了相应的变化.同时发现,通过调节劲度系数的取值可以控制整个系统稳态解的个数.这些研究结果在精密测量或量子信息处理等方面具有潜在应用价值.     

厚壁空心微球的球形度和壁厚均匀性的表征研究

为建立高效简洁的厚壁空心微球球形度和壁厚均匀性的表征和测量方法,以内径850μm、壁厚25μm的厚壁聚苯乙烯(PS)微球为测量对象,分析球形度和壁厚均匀性的表征方法,探讨测量过程中采样方式对表征微球球形度和壁厚均匀性的影响。研究表明:对于批量微球球形度和壁厚均匀性的表征,当抽样数目不小于30时,测量结果之间的差异很小;而对于单一微球的球形度和壁厚均匀性的表征,至少3个不同投影面的测量结果的平均值才趋于稳定。不同投影面导致球形度或壁厚均匀性较差的批次样品的测量结果有一定差异,多次投影测量可提高测量结果的可靠性。     

间隙大小对高负荷压气机叶栅流动特性的影响

在低速平面叶栅风洞中,对不同间隙大小条件下的高负荷压气机叶栅流动特性进行了实验研究。实验采用五孔气动探针测量了叶栅出口截面参数,得到了该截面的二次流速度矢量分布,并对叶栅下端壁和叶片表面进行了墨迹流动显示.结果表明,叶顶间隙的增加加剧了间隙泄漏流动与通道涡的相互作用和掺混,导致叶栅流道内的二次流结构和形态发生改变;增加叶顶间隙可完全抑制吸力面角区分离,但被间隙泄漏流动带走的低能流体被带到尾缘及其下游位置,加剧了相应位置的流动分离;间隙泄漏流动将引起叶栅总损失的显著下降,损失的大小并不一定与间隙大小成正比.     

A preliminary quadrupole asymmetry study of a β=0.12 superconducting single spoke cavity

An Accelerator Driven System(ADS) has been launched in China for nuclear waste transmutation. For the application of high intensity proton beam acceleration, the quadrupole asymmetry effect needs to be carefully evaluated for cavities. Single spoke cavities are the main accelerating structures in the low energy front-end. The single spoke cavity has small transverse electromagnetic field asymmetry, which may lead to transverse RF defocusing asymmetry and beam envelope asymmetry. A superconducting single spoke resonator(PKU-2 Spoke) of β=0.12 and f =325 MHz with a racetrack-shaped inner conductor has been designed at Peking university. The study of its RF field quadrupole asymmetry and its effect on transverse momentum change has been performed. The quadrupole asymmetry study has also been performed on a β=0.12 and f =325 MHz ring-shaped single spoke cavity. Our results show that the quadrupole asymmetry is very small for both the racetrack-shaped and the ring-shaped single spoke cavity.     

超高速高性能门控型三分幅相机

针对~108帧/秒或更高速度上的超高速分幅摄影,采用一种成像质量较好的基于会聚光中分光的全口径分光原理,利用具有高速快门控制功能的像增强器、冷却型科学CCD相机、基于大规模可编程集成电路的高速控制器等部件,研制成功了一种高性能的超高速三分幅相机.该分幅相机具有三幅图像的超快拍摄能力,快门速度最高可达3ns,摄影速度则达到3.3×108帧/秒,并且在较大范围内具有单独调节的能力;图像幅间间隔同时具有任意调节的能力,从0ns到秒级;有效像面面积达到Φ25mm,图像阵列为1 024×1 024;空间分辨率达到30lp/mm,同时具有较好的线性度和空间响应的均匀性,满足了超高速、大幅面的分幅摄影要求.     

Transmission through array of subwavelength metallic slits curved with a single step or mutli-step

The transmission of normally incident plane wave through an array of subwavelength metallic slits curved with a sin- gle step or mutli-step has been explored theoretically. The transmission spectrum is simulated by using the finite-difference time-domain method. The influences of surface plasmon polaritons make the end of finite long sub-wavelength metallic slit behaves as magnetic-reflecting barrier. The electromagnetic fields in the subwavelength metallic slits are the superpo- sition of standing wave and traveling wave. The standing electromagnetic oscillation behaves like LC oscillating circuit to decide the resonance wavelength. Therefore, the parameters of adding step may change the LC circuit and influence the transmission wavelength. A new explanation model is proposed in which the resonant wavelength is decided by four factors： the changed length for electric field, the changed length for magnetic field, the effective coefficient of capacitance, and the effective coefficient of inductance. The effect of adding step is presented to analyze the interaction of two steps in slit with mutli-step. This explanation model has been proved by the transmission through arrayed subwavelength metallic slits curved with two steps and fractal steps. All calculated results are well explained by our proposed model.