GeSbTe 与 AgInSbTe 体系相变光盘的研究进展

自Ovshinsky把相变材料用于光存储以来 ,一大批具有可逆光存储性能的材料不断出现 ,其中研究较多的是GeSbTe和AgInSbTe两种体系 .文章着重介绍了利用这两种材料制成的相变光盘记录介质的微观结构特点 ,阐述了其晶化机理 ;同时 ,较详细地概述了光盘的堆栈结构及掺杂其他元素对相变光盘性能的影响 ,并对比说明了GeSbTe和AgInSbTe两种体系在蓝光记录方面的各自特点     

Novel phthalocyanine thin film for compact disc recordable

In this paper, the spin-coated thin films of phthalocyanine dye are presented. Absorption spectrum of the thin film shows a comparatively broad absorption in the wavelength range 630 - 770 nm. Optical parameters of the thin film were measured by a spectroscopic ellipsometer system. 5-in CD-R discs made of this dye exhibit good performance with Yamaha 20-speed recorder. Jitters of land and pit are less than 30 ns, and the 3T-11T's signals show very good quality. This dye is a promising recording medium for CD-R with much higher recording speed.     

Influence of OH groups on 1.5-um emission of Yb_(3+)/Er_(3+) co-doped tungsten-tellurite glasses

The Yb3+/Er3+ co-doped TeO2-WO3-ZnO glasses bubbling with different times were prepared. The infrared (IR) transmission spectra, emission spectra and fluorescence lifetime of Er3+ at 1.5 um were measured. The quench effects of OH groups on emission intensity of Er3+ at 1.5 um as well as the relationships between fluorescence decay rate and OH group content were investigated. The constant kOH-Er which represents the strength of the interactions between Er3+ ions and OH groups, is approximately 17.0×10-20 cm4/s, and is comparable to that for Er3+ in Yb3+/Er3+ co-doped phosphate glasses.     

偏磷酸根(PO-3)对氟铝酸盐玻璃透光性能影响

在氟铝酸盐玻璃（AMCSBY）中引入Ba(PO3）2替代BaF2,替代公式为10MgF2-20CaF2-(10-x)BaF2-10SrF2-15YF3-35AlF3-xBa(PO3)2(x=,2,4,6,8)。对玻璃进行了差热分析，结果表明，在氟铝酸盐玻璃中引入偏磷酸盐使玻璃形成能力大大提高；测量了玻璃从紫外到红外的透过光谱和紫外吸收光谱，在玻璃中引入偏磷酸钡使玻璃中红外透过能力下降，红外吸收边带移向短波段，玻璃紫外透过能力得到提高。紫外吸收边带移向紫外波段，由于PO3^-的影响，O－H吸收峰由2830nm移到3145nm。     

被动光学限幅器的机制与研究进展

被动光学限幅器是利用介质的非线性光学性质实现对光的强度进行控制的器件,它在科研、军事和民用方面都具有广泛的应用.文章讨论了被动光学限幅器的反饱和吸收、双光子吸收、自由载流子吸收、非线性折射、光致散射和光折变机制,每种机制在光限幅器应用中的有效性及局限性;介绍了国内外研究状况及自己的工作;指出了今后被动光学限幅器研究的发展方向.     

磁控溅射法制备的高反Ag_5In_5Te_(47)Sb_(33)相变薄膜的光谱性质及短波长静态记录性能

研究了磁控溅射制备的Ａｇ５Ｉｎ５Ｔｅ４７Ｓｂ３３相变薄膜的光谱及短波长静态记录性能。研究结果表明，晶态薄膜反射率较高，并在６００～９００ｎｍ波长范围内，晶态与非晶态的反射率和折射率相差很大。在ＣＤ－Ｅ系统的工作波长７８０ｎｍ处，晶态反射率高达５０％，光学常数为５．３４－１．０ｉ；非晶态反射率为２３％，光学常数为２．５－１．０３ｉ。从这一角度讲，Ａｇ５Ｉｎ５Ｔｅ４７Ｓｂ３３相变薄膜适于做ＣＤ－Ｅ系统的记录介质。另外，采用波长为５１４．４ｎｍ的短波长光学静态记录测试仪对Ａｇ５Ｉｎ５Ｔｅ４７Ｓｂ３３薄膜的记录性能进行了测试，结果表明，这种薄膜短波长记录性能较好，它在较低功率和短脉宽的激光束作用下就可得到较高的反射率对比度。     

Crystallization of Ge2Sb2Te5 phase—change optical disk media

In this paper, the crystallization behaviour of amorphous Ge₂Sb₂Te₅ thin films is investigated using differential scanning calorimetry), x-ray diffraction and optical transmissivity measurements. It is indicated that only the amorphous phase to face-centred-cubic phase transformation occurs during laser annealing of the normal phase-change structure, which is a benefit for raising the phase-change optical disk's carrier-to-noise ratio (CNR). For amorphous Ge₂Sb₂Te₅ thin films, the crystallization temperature is about 200℃ and the melting temperature is 546.87℃. The activation energy for the crystallization, E_a, is 2.25eV. The crystallization dynamics for Ge₂Sb₂Te₅ thin films obeys the law of nucleation and growth reaction. The sputtered Ge₂Sb₂Te₅ films were initialized by an initializer unit. The initialization conditions have a great effect on the reflectivity contrast of the Ge₂Sb₂Te₅ phase-change optical disk.     

厚度对光聚物高密度全息存储记录参量的影响

本文用实验方法研究了光致聚合物的曝光时间常量、曝光能量常量、动态范围、曝光灵敏度和折射率调制度等高密度全息存储参量随样品厚度的变化规律,结果表明随着样品厚度的增加,曝光能量常量、曝光时间常量及材料的动态范围也增加,但材料的曝光灵敏度却减小,而折射率调制度却没有明显的变化规律.     

磷酸盐、锗酸盐和碲酸盐玻璃中Ce3+、Tb3+、Er3+、Tm3+离子的发光和敏化作用的研究——Ⅰ.吸收光谱、荧光光谱和激发光谱

研究了在不同基质玻璃中Ce3+、Tb3+、Er3+和Tm3+离子的吸收、荧光和激发光谱,对发光强度进行了定量的测定。研究了玻璃基质的紫外吸收对发光的影响,并且讨论了无机玻璃的配位场与上述稀土离子的相互作用。     

含Al(PO_3)_3氟磷酸盐玻璃的光学及其它物理性质

氟磷玻璃作为光学玻璃及激光工作物质,正在获得应用。在研究Al(PO_3)_3系统玻璃的生成及结构的基础上,本文研究了光学及其它物理性质。Al(PO_3)_3含量低的氟磷玻璃,网络结构受到极大的破坏,处于破坏区,性质变化及各种氟化物对性质的影响与处于破坏区的氧化物玻璃相似。LiF、MgF_2和AlF_3等氟化物的特殊作用在物理性质变化方面也得到反映。同时,与硅酸盐和硼酸盐等玻璃生成体含量高的玻璃比较,静电吸引力对Al(PO_3)_3含量低的氟磷玻璃的性质变化起着更大的作用。文中表示所研究玻璃在n_d～v_d图中的位置,给出低Al(PO_3)_3含量玻璃中的部分性质,与文献数据进行比较,并把部分性质的变化与Al(PO_3)_3含量相联系.