The effect of an anti-hydrogen bond on Fermi resonance： A Raman spectroscopic study of the Fermi doublet v1-v12 of liquid pyridine

The effects of an anti-hydrogen bond on the v1 v12 Fermi resonance （FR） of pyridine are experimentally investigated by using Raman scattering spectroscopy. Three systems, pyridine/water, pyridine/formamide, and pyridine/carbon tetrachloride, provide varying degrees of strength for the diluent-pyridine anti-hydrogen bond complex. Water forms a stronger anti-hydrogen bond with pyridine than with formamide, and in the case of adding non-polar solvent carbon tetrachloride, which is neither a hydrogen bond donor nor an acceptor and incapable of forming a hydrogen bond with pyridine, the intermolecular distance of pyridine will increase and the interaction of pyridine molecules will reduce. The dilution studies are performed on the three systems. Comparing with the values of the Fermi coupling coefficient W of the ring breathing mode v1 and triangle mode v12 of pyridine at different volume concentrations, which are calculated according to the Bertran equations, in three systems, we find that the solution with the strongest anti-hydrogen bond, water, shows the fastest change in the v1-v12 Fermi coupling coefficient W with the volume concentration varying, followed by the formamide and carbon tetrachloride solutions. These results suggest that the stronger anti-hydrogen bond-forming effect will cause a greater reduction in the strength of the v1-v12 FR of pyridine. According to the mechanism of the formation of an anti-hydrogen bond in the complexes and the FR theory, a qualitative explanation for the anti-hydrogen bond effect in reducing the strength of the v1 - v12 FR of pyridine is given.     

用清除羟自由基法评价竹叶提取物抗氧化能力

进行了Fe2+与邻二氮菲生成红色配合物的吸收光谱,抗氧化剂TBHQ及竹叶提取物样品对清除羟自由基能力的研究。分光光度法测定抗氧化剂清除羟自由基能力的测定波长为509.1 nm。以IC₅₀值(清除率为50%时,抗氧化剂的浓度值)作为评价抗氧化剂清除羟自由基能力的指标,测得合成抗氧化剂和效果最好竹叶提取物样品IC₅₀值分别为0.040(TBHQ),0.378(M20),0.323(M40),0.334(M60),M20, M40, M60等竹叶提取物可以作为天然抗氧化剂进行开发。     

基于ALE方法的飞机水面降落过程

为了研究飞机水面降落过程中的动态响应规律,采用arbitrary Lagrangian-Eulerian(ALE)方法开展了飞机水面降落的动力学分析。研究了飞机水面降落过程的速度变化规律,结果表明,降落速度和飞行速度在飞机入水的初始阶段变化较快,随后变化幅度趋于平缓。分析了不同降落速度、飞行速度和降落仰角下的机身结构响应,得到了飞机水面降落时结构响应随时间的变化规律。机身结构应力在入水的初始阶段达到最大值,随后迅速下降,最后保持稳定。飞机结构的最大变形也出现在入水的初始阶段,随后迅速回复到初始状态。对比了降落速度、飞行速度和降落仰角对飞机结构响应的影响程度,结果表明降落速度对结构响应的影响程度最大,降落仰角次之,飞行速度的影响最小。 更多还原     

水电站地下厂房大型岩体洞室的抗爆性能

通过大量的数值模拟试验,以洞室岩体和混凝土衬砌结构的损伤为指标,研究了水电站地下厂房这类大型岩体洞室在强地表爆破荷载作用下,洞室埋深、围岩岩体强度和地应力对洞室抗爆性能的影响。数值计算中,洞室岩体和混凝土衬砌均采用弹塑性损伤本构模型,同时考虑了几何非线性效应。研究结果表明:对于水电站地下厂房这类高边墙洞室,浅埋深洞室的抗爆性能较差,深埋深洞室的抗爆性能较强;岩体强度越高,洞室的抗爆性能越强;当地应力侧压因数λ1时,随地应力侧压因数的增大,洞室的抗爆性能显著下降。 更多还原     

THE EXACT SOLUTIONS OF THE BURGERS EQUATION AND HIGHER-ORDER BURGERS EQUATION IN (2+1) DIMENSIONS

Some exact solutions of the Burgers equation and higher-order Burgers equation in (2+1) dimensions are obtained by using the extended homogeneous balance method. In these solutions there are solitary wave solutions, close formal solutions for the initial value problems of the Burgers equation and higher-order Burgers equation, and also infinitely many rational function solutions. All of the solutions contain some arbitrary functions that may be related to the symmetry properties of the Burgers equation and the higher-order Burgers equation in (2+1) dimensions.     

芽胞杆菌模式菌株细胞脂肪酸组分的气相色谱分析

通过气相色谱对１０个芽胞杆菌模式菌株的细胞脂肪酸组分及其含量进行分析,经ＵＰＧＭＡ,ＮＴＳＹＳ－Ｐｃ系统聚类分析绘制的树状图谱可以清楚地将４个属的菌株分成４个不同的类群,而且同一类群中不同的种也表现出一定的差异。由此可见,控制芽胞杆菌的培养条件及生长状态,同样有效地使脂肪酸组分成为芽胞杆菌化学分类的重要指证。     

激光光栅显微图像检测技术及其应用

介绍一种可以用来测量曲面试件表面应分量（εｚ,εθ,εｚθ）的激光光栅显微图像检测技术（ＩＧＭ）,它能实现从小应变到大应变全过程的高精度定量测量。我们将这一技术成功地应用在铁基形状记忆合金（ＦＳＭＡ）管接头的结构设计中,在这项研究中,首先在管接头结构表面制作了变形的载体－位相型干涉光栅,由结构表面产生的衍射光通宵我学系统后形成新的干涉光栅,我们利用数字图像系统接收了逆相变前后各自的干涉图像,采用带     

低浓度样品拉曼光谱的实验研究

在液芯光纤内产生共振拉曼效应,可以提高拉曼光谱强度１０＾９倍。测定了１０＾－１０－１０＾－５ｍｏｌ／Ｌ浓度样品的拉曼光谱。实验结果表明,β－胡罗卜素在ＣＳ２中１５２０ｃｍ＾－１拉曼线的强度（散射系数）、频移、线宽随浓度降低而发生变化。     

多模式广义失效概率计算的数值模拟法及其工程应用

提出了安全与失效状态含有模糊信息时,广义失效概率计算的数值模拟,及相应的方差估算,并提出了对应的数值积分方法．当状态变量服从正态分布,且其对模糊安全域的隶属函数为正态型时,单个模式的广义失效概率具有精确解．首先利用这种特殊情况检验了所提数值模拟的精度,结果表明对于数值模拟法,随抽样次数的增加,估计值逐渐收敛于真实值．然后利用扩展原理和概率定理,提出两个及两个以上失效模式数广义失效概率的数值模拟计算方法以及相应的数值积分方法．对于工程结构问题,一般在删除次要失效模式之后,主要失效模式的数目不会太多,因此用该数值模拟与数值积分法可以得到精度较高的解．工程算例结果证明了此结论．另外还对所提的两种方法的适用范围做了讨论．     

Approximate direct reduction method: infinite series reductions to the perturbed mKdV equation

The approximate direct reduction method is applied to the perturbed mKdV equation with weak fourth order dispersion and weak dissipation. The similarity reduction solutions of different orders conform to formal coherence, accounting for infinite series reduction solutions to the original equation and general formulas of similarity reduction equations. Painlevé II type equations, hyperbolic secant and Jacobi elliptic function solutions are obtained for zero-order similarity reduction equations. Higher order similarity reduction equations are linear variable coefficient ordinary differential equations.