具有大范围高分辨率线性响应特性的超短无芯光纤溶液折射率传感器

通过理论与实验对比, 证明模式传输分析(MPA)方法求解单模-多模-单模(SMS)结构的可行性. 以MPA理论为基础, 提出了SMS结构折射率传感装置线性响应点的寻找方法. 利用该方法为实验制作的无芯光纤SMS折射率传感器设计了大范围高分辨率线性响应位置, 并在实验中获得证实. 实验采用短至4.4 mm的直径104 μ无芯光纤, 在折射率1.326–1.417范围上获得了19.10 dB的功率线性变化, 以商用光功率计0.01 dB分辨率计, 折合折射率分辨率4.76×10^-5, 实现了理论指导下的大范围高分辨率线性响应. 关键词： 全光纤折射率传感器 多模干涉仪 SMS 无芯光纤     

基于啁啾光纤光栅的色散补偿器在超长距离密集波分复用系统中的应用

对啁啾光纤光栅在超长距离多波长传输系统中应用时所存在的问题进行了研究，主要分析了多波长级联的啁啾光纤光栅之间的串扰，并提出了利用相干长度法来抑制不同信道间啁啾光纤光栅串扰的方法.在此基础之上实现了基于光纤光栅色散补偿的8×10Gbit/s,1500km G.652光纤上的传输系统. 关键词： 光纤通信 色散补偿 啁啾光纤光栅     

人血清中半胱氨酸测定用自组装电化学传感器的研制

将四羧基钌(Ⅱ)酞菁(RuPc)共价键合到自组装在Au电极表面的巯基丁二胺单分子层上,获得了自组装修饰电极(RuPc-CME).研究了它的电化学性质,并采用扫描电子显微镜(SEM)、傅立叶变换红外光谱(FT-IR)、X射线光电子能仪(XPS)以及循环伏安法(CV)对该电极表面进行了表征.在pH 5.5时,循环伏安图显示RuPc修饰层存在一对氧化还原峰,其峰电位分别为V1pa=1.12 V,V1pc=1.09 V(vs. SCE).它的表面电子的电荷转移系数α为0.52,速率常数Ks=1.43 s-1,表面覆盖度Γ=7.82×10-10mol/cm2,属于单分子层吸附.在pH 3.0～5.5的PBS底液中,该电极对L-半胱氨酸(Hcy)的氧化有催化作用,采用计时安培电流法(CA)测定催化电流与Hcy的浓度在5.0×10-7～5.4×10-5mol/L范围内呈良好的线性关系,检出限为1.8×10-7 mol/L.用于检测人血清样品中的Hcy,结果满意.     

A Simple One-pot Synthesis of 3,5-Dicyano-1,2-dihydropyrid-2-ones in Aqueous Media

A simple and clean synthesis of 3,5-dicyano-1,2-dihydropyrid-2-ones by a one-pot three-component reaction of malononitrile, aromatic aldehydes and 2-cyanoacetamide or 2-cyanothioacetamide has been achieved in an aqueous solution with potassium carbonate as a base under microwave irradiation without a phase transfer reagent. This protocol has the advantages of short reaction time （5-8 min） and convenient work-up.     

The system of L-band 2×10 Gb/s WDM transmission over conventional single mode fibre with 600 km by chirped fibre Bragg gratings dispersion compensation

A chirped fibre Bragg grating according to ITU-T suggested L-band (2nd channel $\lambda _{1}=1570.83$~nm; 80th channel $\lambda _{2}=1603.57$ nm) with more than 1800 ps/nm single channel dispersion compensation is presented in this paper, of which the cladding mode loss, the delay curve ripple and the power fluctuation of the reflected spectrum are less than 0.5 dB, 50 ps and 0.25 dB, respectively. With this new FBG as dispersion compensation device, a $2\times 10$ Gb/s wavelength division multiplexing (WDM) L-band transmission of 600 km based on conventional single mode fibre (G.652 fibre) is performed without forward error correction. The bit error rate (BER) is less than 10$^{ - 12}$ and the power penalties of the 2{nd} and 80{th} channel of L-band are 1.8~dB and 2.0~dB, respectively.     

基于长周期光纤光栅载边比连续可调的单边带调制光载无线通信系统

提出了一种基于长周期光纤光栅(LPFG)载边比(CSR)连续可调的单边带调制光载无线通信(RoF)系统。其核心单元是由偏振控制器(PC)、偏振分束器(PBS)、两个平行的长周期光纤光栅和偏振合束器(PBC)构成的载边比调节单元。通过调节偏振控制器输出的偏振角度,就可以实现载边比的连续可调。进一步分析了调制指数、长周期光纤光栅透射率峰值和马赫-曾德尔调制器消光比对载边比的影响。仿真结果与理论分析结果具有很好的一致性。经40km标准单模光纤(SMF)传输后的仿真实验表明,当载边比由13.22dB调节到5.4dB后,系统灵敏度提高了5.7dB。     

Ultra-Long Haul L-Band WDM Transmission over a Standard Single-Mode Fibre Loop Using DCF＋CFBG Hybrid Dispersion Compensation

We demonstrate a 10. 7Gb/s-line-rate L-band wavelength-division-multiplexer （WDM） loop transmission over a 1890-kin standard single-mode fibre （SSMF） with a 100-km amplifier spacing as well as non-return-to-zero （NRZ） format. The dispersion compensating fibre （DCF） plus chirped tibre Bragg grating （CFBG） is employed for hybrid inline dispersion compensation. The power penalty of each channel is less than 3 dB after three-loop transmission. The experimental results show that high-performance CFBGs can be successfully used in ultra-long haul （〉 1000km） WDM systems. We also point out that the all-CFBG compensation scheme is not suitable for re-circulating loop transmissions.     

酸性媒染紫-示波计时电位法测定天然水和饮用水中铝

报道酸性媒染紫（ＳＶＲＳ）－示波计时电位法测定天然水及饮用水中铝。在０．８５ｍｏｌ／Ｌ　ＮＨ３·Ｈ２Ｏ－ＮＨ４Ｃｌ－５×１０－５ｍｏｌ／Ｌ ＳＶＢＳ（ｐＨ８．８）底液中,Ａｌ－ＳＶＲＳ络合物在－１．０５Ｖ电位处产生灵敏切口,切口深度与铝浓度成正比,可用于定量分析。线性范围为１×１０－７～６×１０－６ｍｏｌ／Ｌ． ＲＳＤ为５．５％ （ｎ＝１０,２×１０－７ｍｏｌ／Ｌ）,检测限为５×１０－８ｍｏｌ／Ｌ。本法特点为：在碱性条件下,无需加热,无需通氮除氧,无需预富集,大大减少了分析时间。仪器简单,方法灵敏准确,特别适用于天然水和饮料中Ａｌ的分析。对实际水样进行了分析,与ＩＣＰ／ＡＥＳ法所测结果基本一致。     

Synthesis and Thermal Decomposition Kinetics of the Complex of Samarium p-Methylbenzoate with 1 ,10-Phenanthroline

The complex [Sm（p-MBA）3phen]2 （p-MBA, p-methylbenzoate; phen, 1,10-phenanthroline） was prepared and characterized by elemental analysis, IR and UV spectra. The thermal decomposition process of [Sm（pMBA）3phen]2 was studied under a static air atmosphere by TG-DTG and IR techniques. Thermal decomposition kinetics was investigated employing a newly proposed method, together with the integral isoconversional non-finear method. Meanwhile, the thermodynamic parameters （AH#, △G# and AS#） were also calculated. The lifetime equation at mass-loss of 10% was deduced as In r=-24.7825＋ 18070.43/T by isothermal thermogravimetric analysis.     

基于联合有限元-离散元的混凝土重力坝破坏三维仿真模拟

水利工程中混凝土重力坝在地震等作用下的三维破坏形式以及破坏过程对大坝安全影响重大。本文建立了固体材料的联合有限元-离散元(Combined Finite-Discrete Element)三维数学模型,并引入Single/Smeared断裂损伤模型,模拟混凝土材料的破坏。数学模型经验证后,用于地震作用下混凝土重力坝破坏的三维数值模拟,结果表明,联合有限元-离散元方法能够有效模拟坝体的破坏模式和破坏阈值条件,且具有将坝体连续变形与不连续断裂有机结合的优点。通过一系列数值模拟工况的对比,分析了模型网格分辨率对破坏条件、破坏模式以及程序计算效率的影响,研究结果能够为大坝的抗震设计提供有价值的参考。