Solar cells based on the poly(N-vinylcarbazole):porphyrin: tris(8-hydroxyquinolinato) aluminium blend system

Organic solar cells based on poly(N-vinylcarbazole)(PVK):porphyrin:tris(8-hydroxyquinolinato) aluminium(Alq3) blend p-n junction systems have been fabricated in this work.The roles of the different components in the blend system and of the amount of porphyrin have been investigated.The 5,10,15,20-tetraphenylporphyrin(TPP) and 5,10,15,20-tetra(o-chloro)phenylporphyrinato-copper(CuTClPP) are used in the solar cells.The results show that TPP is better than CuTClPP in enhancing the performance of PVK:Alq3 solar cells.When the weight ratio of PVK:TPP:Alq3 is 1:1.5:1,the best performance of solar cell is obtained.The open circuit voltage(V oc) is 0.87 V,and the short circuit current(J sc) is 17.5 μA·cm 2.In the ternary bulk hereojunction system,the device may be regarded as a cascade of three devices of PVK:TPP,TPP:Alq3 and PVK:Alq3.PVK,TPP and Alq3 can improve the hole mobility,light absorption intensity and electron mobility of the ternary bulk hereojunction system,respectively.     

用于超热电子诊断的滤波荧光谱仪滤片厚度的优化设计

根据物质的吸收系数、散射截面、荧光截面的离散数据进行了二维插值,利用插值后的数据对前置滤片透射率、荧光体吸收截面、后置滤片透射率进行拟合,用文献[2]的滤波荧光谱仪的总响应函数(荧光响应函数和散射响应函数)以及探测器灵敏度和散射光、荧光光子数,对前置滤片、荧光片和后置滤片的不同厚度进行优化设计,得到了最大信噪比(荧光响应函数曲线的峰值面积与总响应函数面积的比值)及最大信噪比对应的前置滤片、荧光片、后置滤片厚度。在滤波荧光谱仪上应用优化厚度,减少了高能尾部对探测信号的影响,得到更加有效的硬X射线能谱,继而推算出更加精确超热电子信息。     

甲基丙烯酸类聚合物修饰的聚乙烯隔膜在锂离子电池中的应用

将环状碳酸酯基团引入到聚甲基丙烯酸甲酯(PMMA)侧链上, 制备了聚(2,3-环碳酸甘油酯)甲基丙烯酸酯(PDOMMA), 并用其修饰锂离子电池聚乙烯隔膜. 通过热重分析、 差示扫描量热分析及接触角和吸液率测试等研究了PDOMMA的热稳定性及其修饰的聚乙烯隔膜对电解液的浸润性和吸液率的影响, 并通过恒流充放电、 交流阻抗、 倍率性能测试及扫描电子显微镜观测等研究了修饰隔膜对锂离子电池性能的影响. 结果表明, 与未修饰隔膜相比, 修饰隔膜对电解液浸润性更优异(20 s内便完全浸润), 吸液率更高(440%), 电池循环性能更好(放电比容量提高了12.3%).     

金属镁与铵盐水溶液反应实验探究

镁与铵盐溶液反应的原理在中学化学中存在多种矛盾解释。通过测定镁与不同铵盐溶液、镁与不同阴离子溶液反应的速率和生成氢气的体积,得出镁与铵盐溶液的反应实质：铵根离子是镁与水反应生成氢气的催化剂;部分阴离子（Cl-,SO42-）催化了镁与水的反应。并从热力学和动力学2个方面探讨了铵盐溶液对镁与水反应的影响。     

527nm激光辐照盘靶背向散射能量测量

在星光Ⅱ激光装置上,测量了脉宽1ns、能量40-110J的527nm激光在不同条件下辐照Au盘靶、Al盘靶的背向散射能量。结果表明:激光辐照Au盘靶时．在聚焦条件下背向散射能量约占打靶激光能量的7．8％;在束匀滑条件下背向散射能量份额下降到6.2％左右,证明了束匀滑可有效抑制背向散射。对比Au盘靶、Al盘靶背反能量与打靶激光能量关系曲线,可以看出背向散射能量与打靶激光能量基本上成线性关系。 Au and Al disk target were irradiated with -1 ns, 40-110 J, 527 nm laser at Xingguang-Ⅱ facility. The backscattered lights by laser-produced plasma were studied experimentally. The results are in troduced in this paper. Backscattered light energy is 7.8% of laser energy when laser is focused on Au disk target; when laser beam is smoothed, it is 6.2%. The comparison shows that laser smoothing can restrain backscattered light efficiency. The experimental results :also show that there is a linear relation between backscattered light energy and the laser energy.     

有机太阳能电池材料研究新进展

介绍了有机太阳能电池研究的背景、基本原理、分类,并对有机太阳能电池材料进行了全面综述,包括小分子太阳能电池材料、大分子太阳能电池材料、D-A体系材料和有机无机杂化体系材料.     

Synthesis of thermally stable HfO_xN_y as gate dielectric for AlGaN/GaN heterostructure field-effect transistors

In this paper, we adopted thermally stable HfO_xN_y as gate dielectric for TiN/HfO_xN_y/AlGaN/GaN heterostructure field-effect transistors(HFETs) application. It demonstrated that the surface morphologies, composition, and optical properties of the HfO_xN_y films were dependent on oxygen flow rate in the O_2/N_2/Ar mixture sputtering ambient. The obtained metal–oxide–semiconductor heterostructure field-effect transistors by depositing HfO_2 and HfO_xN_y dielectric at different oxygen flow rates possessed a small hysteresis and a low leakage current. After post deposition annealing at 900℃, the device using HfO_xN_y dielectric operated normally with good pinch-off characteristics, while obvious degradation are observed for the HfO_2 gated one at 600℃. This result shows that the HfO_xN_y dielectric is a promising candidate for the self-aligned gate process.     

基于修正的局部应力应变法估算连接件疲劳寿命

飞机机体结构疲劳裂纹的萌生与扩展几乎都发生在紧固件连接处,预测结构连接件的疲劳寿命具有重要意义.为了准确计算连接件疲劳寿命,提出了一种修正的局部应力应变法,该方法首先采用应力严重系数法和修正Neuber法分析连接件高应力区的应力、应变,然后利用Manson-Coffin方程计算疲劳寿命,此外考虑到在中、高周疲劳里表面加工和尺寸因素的影响是不能忽略的,对应变-寿命曲线的弹性段作了修正以使其同时适用于高、低周疲劳寿命的估算.以搭接件为算例进行疲劳寿命计算,并使用MTS Landmark试验机对搭接件进行疲劳试验.结果表明,采用此方法估算的连接件疲劳寿命与试验结果相比误差小于16％,证明了此方法的有效性.     

双弹光调制广义偏振测量的数字锁相数据处理研究

针对高精度、快速实时的偏振测量需求,提出了一种双弹光差频调制的偏振参量测量方法。对偏振测量原理进行了详细分析,针对双弹光调制器工作控制及信号解调需求,设计了基于数字可编程逻辑门阵列(FPGA)的多通道数字锁相数据处理方案。FPGA提供一定频率占空比的脉冲宽度调制波(PWM),经高压谐振电路输出正弦高压驱动弹光调制器工作,与此同时,探测器探测到的调制光信号经模数转换器(ADC)采集后进入FPGA中。FPGA提供本地参考信号完成多个频率信号的同时解调,进而单次测量便可得到4个斯托克斯分量。搭建了实验系统进行了实验验证,利用旋转1/4波片法建立了偏振产生装置,实现了对线偏振光、圆偏振光、椭圆偏振光的测量。实验结果表明,系统测量的相对误差小于0.8%,重复性标准差小于0.2%,单次测量时间小于200ms,实现了高精度、重复性好、实时的偏振测量。