阶梯电极离子阱质量分析器的结构与性能

本研究从理论上优化了一种新型结构的线型离子阱质量分析器-阶梯电极离子阱质量分析器,它是由2对阶梯电极与1对端盖电极组成。与传统平板电极矩形离子阱长阶梯电极离子阱相比,具有调节电场分布的优点,同时在几何结构设计上更接近于双曲面电极结构,但比双曲面电极更容易加工。通过改变阶梯电极结构的高度、宽度、场半径比例等几何参数,实现了对离子阱内部电场分布的优化,从而实现离子阱性能的优化。理论模拟研究结果表明,根据几何结构和电场分布优化获得的阶梯电极离子阱质量分析器(X0×Y0=9 mm×5 mm),可以在225 Da/ s 扫速下获得10150的质量分辨率。阶梯电极离子阱结构简单,分辨能力明显高于矩形离子阱。初步的实验结果表明,阶梯电极离子阱具有较好的串级质谱分析性能。     

节理抗剪强度综合评价的试验研究

选取不同吻合度自然节理试样,进行干燥状态和饱和状态的JRC-JCS模型和JRC-JMS模型试验研究。结果表明,在节理粗糙度系数的定向统计测量和尺寸效应分析,以及剪切过程衰减折减的基础上,运用JRC-JCS模型综合评价节理抗剪强度可靠性较好,考虑吻合度系数的JRC-JMC模型比JRC-JCS模型具更好的预测能力。     

CONFIGURATION OF VO(OR)_2Cl-Al(i-Bu)_3 CATALYST SYSTEM AND CHARGE DISTRIBUTION OF VANADIUM CENTRAL ION

According to the caiculation of quantum chemistry it come be deduced that conngurauons or the catalysts VO(OR)_2Cl-Al (i-Bu)_3, for the alternating Copolymerization of butadiene with propene, the highest reactive configuration was A. When the catalyst complex forms the configuration A, the energy of the system was the lowest; the central vanadium atom had relatively high positive charge and whose frontier orbital overlapped easily with the frontier orbital of butadiene to form coordination complex, so it was concluded from the experimental results and calculations that the configuration of the catalyst of relatively high activity was A.