设计功能性多核配合物的一种重要桥基—1.2—二硫代草酸根

本文综述了１．２－二硫代草酸根（ｄｔＯ）的配位性质及其多核配合物的合成及结构特征，并讨论了ｄｔＯ配合物的光，电，磁性及应用。     

Tm~(3+) and Nd~(3+) singly doped LiYF_4 single crystals with 3-5 μm mid-infrared luminescence

Mid-infrared(MIR) emissions of 2.4 and 3.5 μm from Tm3+:LiYF4 single crystals attributed to3H4 →3H5 and3H5 →3F4 transitions as well as MIR emissions of 4.2,4.3,and 4.5 μm from Nd3+:LiYF4 lasers attributed to4I15/2 →4I13/2,4I13/2 →4I11/2,and4I11/2 →4I9/2 transitions,respectively,are observed.LiYF4 single crystals possess high transmittance of over 85% in the 2.5-6 μm range.The large emission crosssections of Tm-doped crystals at 2.4 μm(1.9×10-20cm2) and Nd-doped crystals at 4.2 μm(0.84×10-20 cm2) as well as the high rare-earth doping concentrations,excellent optical transmission,and chemicalphysical properties of the resultant samples indicate that Nd3+and Tm3+singly doped crystals may be promising materials for application in MIR lasers.     

多普勒测风激光雷达风场探测结果分析

为了验证自行研制的瑞利散射测风激光雷达的性能及应用价值,将激光雷达测量的风速风向廓线与探空气球测量结果进行对比,结果吻合得较好,高度10 km以下风速最大差距3.0 m/s,20 km以下最大差距4.5 m/s;风向除拐点外标准差最大32。连续探测结果显示了强劲的西风急流和风向转换特征,急流中心的高度一般在10~12 km,中心最大风速接近70 m/s,最小风速不低于30 m/s,20 km左右拐点最小风速不足1 m/s,20 km以上风速逐渐增加 ;在20 km以下风向为西风,在270左右变化,20 km以上为东风,在90左右变化。探测结果表明瑞利散射测风激光雷达既能跟踪大尺度季节性气候特征的变化规律,又能突出小尺度瞬态气候特征的形成、演化过程。