广义de Sitter空间中的类时超曲面的切触性质

从切触几何及Legendrian奇点理论的角度研究了广义de sitter空间中的类时超曲面的切触性质及gdS-高斯像的奇点的分类和几何意义.     

锕系端基亚胺金属有机化合物研究进展

在过去的30多年中,锕系端基亚胺金属有机化合物因其具有独特的结构特征以及在基团转换与催化方面的潜在应用而受到人们的广泛研究,并取得了一些很好的成果.目前,锕系端基亚胺金属有机化合物已成为金属有机化学领域中一个引人注目的研究热点.这篇综述主要介绍了锕系端基亚胺金属有机化合物在合成及反应性能方面的研究进展.     

三个喹啉氧基乙酰胺镧系(Eu、Gd、Er)配合物的合成、结构及Eu配合物的荧光性质

合成并通过单晶衍射表征了3个稀土配合物Ln(L)(NO₃)₃(H₂O)(L=N-苯基-2-(5-氯-8-喹啉氧基)乙酰胺,Ln=Eu (1),Gd (2),Er (3)),结构与拥有相同有机配体的Pr,Nd和Sm配合物同构。在每个配合物中,十配位的稀土离子采取扭曲的双帽四方反棱柱配位构型,分别与来自1个配体L的2个氧原子和1个氮原子,2个双齿配位硝酸根和1个水分子配位。配合物1能够发射Eu(Ⅲ)离子特征荧光,荧光寿命为437 μs。     

发射层厚度对透射式GaAs光电阴极表面光电压谱的影响

通过求解一维稳态少子扩散方程,推导了含有后界面复合速率和发射层厚度的透射式GaAs光电阴极表面光电压谱理论方程.通过对发射层厚度分别为1.6 μm和2.0 μm,掺杂浓度为1×1019 cm－3的GaAs透射式阴极样品测试,理论曲线和实验曲线基本一致.通过引入表面光电压谱积分灵敏度公式,仿真探讨了表面光电压谱在一定体材料参量条件下,积分灵敏度受发射层厚度的影响|发现在体材料参量一定条件下,透射式GaAs光电阴极具有最佳厚度,同时最佳厚度受后界面复合速率的影响更大,同时GaAlAs窗口层也能很好降低发射层后界面复合速率.     

Deposition of hexagonal boron nitride thin films on silver nanoparticle substrates and surface enhanced infrared absorption

Silver nanoparticle thin films with different average particle diameters are grown on silicon substrates. Boron nitride thin films are then deposited on the silver nanoparticle interlayers by radio frequency （RF） magnetron sputtering. The boron nitride thin films are characterized by Fourier transform infrared spectra. The average particle diameters of silver nanoparticle thin films are 126.6, 78.4, and 178.8 nm. The results show that the sizes of the silver nanoparticles have effects on the intensities of infrared spectra of boron nitride thin films. An enhanced infrared absorption is detected for boron nitride thin film grown on silver nanoparticle thin film. This result is helpful to study the growth mechanism of boron nitride thin film.     

基于FCE-AHP的非物质文化遗产宜产性评估研究

通过对非物质文化遗产产业化存在的问题及其内涵与其发展规律的研究发现,并不是所有的非物质文化遗产都适宜于产业化,非物质文化遗产的产业化能力是可以评估的.通过德尔菲法建立非物质文化遗产宜产性评估指标体系,采用FCE-AHP法构建非物质文化遗产的多层次评估模型,并探讨该模型在实践中的应用和价值.     

液液萃取中半挥发性有机物正辛醇/水分配系数与回收率相关性分析

该文讨论了水中目标有机物的回收率与正辛醇/水分配系数之间的联系,结果表明半挥发性有机污染物在水中的回收率与正辛醇/水分配系数(lg Kow)间存在一定的规律:当lg Kow5时,回收率为16.1%~56.1%,当lg Kow5时,回收率为59.5%~124.9%;用溶解度(lg S)与89种有机污染物的回收率进行分析,得出与正辛醇/水分配系数(lg Kow)一致的结论:当lg S-0.60时,回收率为59.5%~124.9%,当lg S-0.6时,回收率为16.1%~56.1%;采用实际水样的实验室空白加标结果对所得结论进行验证,其结果显示与上述结论一致,即当污染物的lg Kow5,或者lg S-0.6时,其液液萃取的回收率为85.3%~115.9%。     

双酚A在氧化石墨烯表面吸附的分子动力学模拟

双酚A(bisphenol A,BPA)是一种内分泌干扰物,会对机体多方面产生不良影响,包括生殖系统、神经系统、胚胎发育等.因此,在水环境中如何检测和去除BPA显得尤为重要.实验研究表明,氧化石墨烯(graphene oxide,GO)对BPA具有优异的吸附去除性能,但在分子层面的吸附机制尚不清楚.分子动力学模拟,能提供BPA在GO表面的动态吸附过程以及吸附构象等详细信息,可以弥补实验的不足.本文利用GROMACS分子动力学模拟软件,系统模拟了BPA在含GO的水溶液中的吸附过程,并计算了吸附自由能.结果显示:所有的BPA均被吸附在GO两侧,通过分析BPA的吸附构象以及与GO的相互作用,发现π-π疏水作用对吸附起主导作用,且显示出很好的稳定性,而静电和氢键作用增加了GO的吸附能力.通过自由能计算,BPA在GO表面的结合能达30 k J/mol,远大于水分子的5 k J/mol.这些结果进一步证实GO对BPA具有很强的吸附能力以及GO作为吸附剂在水溶液中去除BPA的可行性.     

Characteristics of paraxial propagation of a super Lorentz—Gauss SLG01 mode in uniaxial crystal orthogonal to the optical axis

Analytical propagation expression of a super Lorentz-Gauss（SLG） 01 mode in uniaxial crystal orthogonal to the optical axis is derived.The SLG 01 mode propagating in uniaxial crystal orthogonal to the optical axis mainly depends on the ratio of the extraordinary refractive index to the ordinary refractive index.The SLG 01 mode propagating in uniaxial crystals becomes an astigmatic beam.The beam spot of the SLG 01 mode in the uniaxial crystal is elongated in the x-or y-direction,which is determined by the ratio of the extraordinary refractive index to the ordinary refractive index.With the increase of the deviation of the ratio of the extraordinary refractive index to the ordinary refractive index from unity,the elongation of the beam spot also augments.In different observation planes,the phase distribution of an SLG 01 mode in the uniaxial crystal takes on different shapes.With the variation of the ratio of the extraordinary refractive index to the ordinary refractive index,the phase distribution is elongated in one transversal direction and is contracted in the other perpendicular direction.This research is beneficial to the practical applications of an SLG mode.     

Characteristics of paraxial propagation of a super Lorentz-Gauss SLG₀₁ mode in uniaxial crystal orthogonal to the optical axis

Analytical propagation expression of a super Lorentz-Gauss(SLG) 01 mode in uniaxial crystal orthogonal to the optical axis is derived.The SLG 01 mode propagating in uniaxial crystal orthogonal to the optical axis mainly depends on the ratio of the extraordinary refractive index to the ordinary refractive index.The SLG 01 mode propagating in uniaxial crystals becomes an astigmatic beam.The beam spot of the SLG 01 mode in the uniaxial crystal is elongated in the x-or y-direction,which is determined by the ratio of the extraordinary refractive index to the ordinary refractive index.With the increase of the deviation of the ratio of the extraordinary refractive index to the ordinary refractive index from unity,the elongation of the beam spot also augments.In different observation planes,the phase distribution of an SLG 01 mode in the uniaxial crystal takes on different shapes.With the variation of the ratio of the extraordinary refractive index to the ordinary refractive index,the phase distribution is elongated in one transversal direction and is contracted in the other perpendicular direction.This research is beneficial to the practical applications of an SLG mode.