Fe和Co对Ni2MnGa合金(110)马氏体孪晶界面电子结构的影响

利用密度泛函理论研究了Fe,Co两种合金元素对Ni2MnGa合金(110)马氏体孪晶界面电子结构的影响.分别从界面能、偏聚能、磁矩、键序和电子态密度等角度对合金元素在界面处的掺杂效应进行了分析和比较.计算结果表明,在对界面的钉扎作用上,Co的界面掺杂效应较Fe的掺杂效应强;对于界面磁性的影响,Fe掺杂对界面磁结构的作用比Co掺杂显著.     

自制甲基硝基亚硝基胍诱发大鼠胃腺癌及其幽门腺区上皮细胞的改变

使非纯系大白鼠饮自制甲基硝基亚硝基胍溶液,并给每鼠每周加灌饱和食盐溶液1毫升,18个月期间,在实验组18只大白鼠中出现胃腺癌5例,12指肠腺癌2例,此外尚有少数前胃乳头状瘤及肺癌.在对照组17例中则未见肿瘤.显微镜下,可见实验组幽门腺区胃小凹深部上皮细胞有显著增生,癌变亦起自该处.电镜下可见幽门腺区胃小凹上皮细胞增生者仅有核浆比例略增大,有不典型增生者的核形状、基底膜和细胞间联接等的改变接近癌细胞.文中认为增大致癌剂浓度及加长接触时间,可在不敏感动物中诱发出癌变.     

1,4-二取代苯基-3-酰氨基-2-吖啶酮类化合物的80兆~1H-NMR谱及构型研究

本文报道了在FT-80A NMR波谱仪上测定的22个新标题化合物的80兆~1H-NMR谱,进行了谱线归属,确定了该系列化合物均为顺式构型,讨论了不同溶剂对谱峰和化学位移的影响。     

n个平面分割空间的块数

一、问题的提出 　　某大学一研究生向我校老师提出这样一个问题:空间n个平面最多可把空间分成几块? 　　1个平面分成2块,2个平面分成4块,3个平面分成8块,4个平面或更多时就很难想象得出了.必须用科学的方法才行.为此,我们确定了由简到繁,由特殊到一般的思路,即先降维,再升维.……     

微量仪器非水滴定法测定硫酸铵

利用自行研制的微量容量仪器,采用非水滴定法测定硫酸铵的含量。对微型滴定法与常量滴定法的平行测定结果进行了比较。     

Electronic Transport of the Adsorbed Trigonal Graphene Flake： A First Principles Calculation

In recent years, electronic transport through molecular devices has attracted much attention due to the progress in experimental techniques for ma- nipulating individual molecules and the availabil- ity of the first-principles method to describe the elec- trical properties of devices. Graphene, a two- dimensional （2D） network of sp2 hybridized carbon atoms, has stimulated great research interest due to its unique electronic transport properties and its pro- found potential for future device applications. Chemical doping with foreign atoms is generally cho- sen to modify the electronic transport properties of carbon materials. The possibility of functionalizing graphene with radicals such as O, F, and H atoms has been experimentally demonstrated. One- dimensional GNRs and zero-dimensional graphene quantum dots （GQDs）, including triangular, rectangular and hexagonal shapes, which can be ob- tained through the geometry cutting method, pro- vide the possibility to explore low-dimensional trans- port properties for carbon-based nanoelectronics. The trigonal graphene flake （TGF）, a kind of representa- tive zero-dimensional GQD, is prominent in electronic and magnetic properties due to its n-fold degenerated half-filled zero-energy states. This novel property was revealed by both experimental and theoretical studies.     

Hadronic Decays of the Spin-Singlet Heavy Quarkomium under the Principle of Maximum Conformality

The principle of maximum conformality （PMC） provides a way to eliminate the conventional renormalization scale ambiguity in a systematic way. By applying the PMC scale setting, all non-conformal terms in a perturbative series are summed into the running coupling, and one obtains a unique, scale-fixed prediction at any finite order. In this study, we make a detailed PMC analysis for the spin-singlet heavy quarkoniums decay （into light hadrons） at the next-to-leading order. After applying the PMC scale setting, the decay widths for all those cases are ahnost independent of the initial renormalization scales. The PMC scales for ηc and he decays are below 1 GeV; to achieve a confidential pQCD estimation, we adopt several low-energy running coupling models to carry out the estimation. By taking the MPT model, we obtain Г（ηc → LH） = 25.09 -4.28^＋5.52 MeV, F（ηb →LH） 14.34-0.84^＋0.92 feV, Г（hc →LH） = 0.54-0.04^＋0.06 MeV and Г（hb →LH） = 39.89-0.46^＋0.28 keV, where the errors are calculated by taking mc E[1.4OGeV, 1.60GeV] and mb C[4.50GeV, 4.70GeV]. These decay widths agree with the principle of minimum sensitivity estimations, in which the decay widths of ηc,b are also consistent with the measured ones.     

CdS-ZnSe和CdSe-ZnS量子点的合成和F(o)rster能量转移研究

采用分步合成法成功合成了CdS-ZnSe(Ⅰ型)和CdSe-ZnS(Ⅱ型)核-壳结构量子点.并首次构建了CdS-ZnSe/CdSe-ZnS结构F(o)rster能量转移对.利用吸收光谱(UV-Vis),光致发光谱(PL),时间分辨光致发光谱(TRPL),透射电子显微镜(TEM)对比研究了不同配比的CdS-ZnSe/CdSe-ZnS结构Fö rster能量转移.分析结果表明:在能量转移发生时,CdS-ZnSe荧光强度显著下降,荧光寿命明显缩短,F(o)rster能量转移确实存在于CdS-ZnSe/CdSe-ZnS量子点之间.     

几种金属盐催化剂对苯甲醛肟重排生成苯甲酰胺的催化作用

考察了SnCl2,CdCl2,Cr(CH3COO)3,Cr(NO3)3四种金属盐对苯甲醛肟重排生成苯甲酰胺反应的催化作用;以SnCl2作为模型催化剂,探讨了催化剂用量、反应温度及反应时间等因素对产率的影响,确定了最佳反应条件.结果表明,SnCl2对苯甲醛肟重排生成苯甲酰胺反应的催化效率最高;最佳反应条件为:n(SnCl2)∶n(苯甲醛肟)=2∶5,反应温度110℃,反应时间19h,相应的苯甲酰胺产率达57.6%.     

利用傅里叶变换研究阔叶材纤维细胞尺寸

利用傅里叶变换图像处理技术测量阔叶材纤维细胞尺寸。把每一个纤维细胞都用其中心的一个长九个像素点,宽两个像素点的线段点图(LCDM)来表示,进行傅里叶变换(FFT),其能量光谱图(PSP)在水平和垂直方向上的频率分布,除零值以外的最大值,即为细胞径向、弦向直径。实验结果表明,该方法与光学显微镜、图像处理软件的结果基本相同,说明该方法也适用于阔叶材纤维细胞尺寸的测定,扩大了其应用领域,为木材的微观分析提供新方法和新的研究方向。