Antibiotic Silver Particles Coated Graphene Oxide/polyurethane Nanocomposites Foams and Its Mechanical Properties

Silver nanoparticles(AgNPs) are widely adopted in polyurethane foams(PUFs) as a type of antibacterial agent. However, due to its poor interfacial interaction, Ag NPs are difficult to be dispersed in the polymer matrix uniformly, which deteriorates the enhancement effect. In this paper, silver-coated graphene nanocomposite(Ag/GO) is prepared by an enzyme reductant which is efficient and non-toxic. Compared with traditional antibacterial agent, the Ag/GO nanoparticles can be uniformly dispersed in...     

紫外光和可见光对Fe3O4掺杂的TiO2催化降解有机物的影响

基于TiO2光催化剂的催化机理尚不明确, 因此发展一种具有不同波段的光催化材料对光催化机理的研究至关重要. 本文采用溶胶-凝胶方法合成了一个Fe3O4掺杂的金红石型TiO2复合物, 通过红外、粉末衍射以及扫描电镜对其结构进行了表征. 紫外-可见吸收光谱表明, 无论在可见光或者是紫外光的照射下, 它都表现出良好的光催化性能, 说明Fe3O4掺杂对改善TiO2的催化性能有一定影响.     

浙江信息服务业发展格局及其影响因素

信息服务业是伴随信息技术广泛应用逐渐兴起的新兴产业, 成为当今中国产业创新发展的重要方向. 文中系统阐释了信息服务业范畴, 厘清了信息服务业的经济地理学研究内容与方法体系. 运用主成分、多元回归、空间相关分析等方法分析浙江省2004年、2008年经济普查数据, 探究浙江信息服务业重点行业空间分布及其影响因素. 研究发现: (1)全省信息服务业重点行业空间分布格局趋于分散; 市域层面沿海及中部地区集聚水平高; 浙北、浙西南以及舟山的集聚水平较低. (2) 影响信息服务业发展因素中,人才、技术、政府支持等最为重要.     

Spatial heterogeneity in liquid–liquid phase transition

Molecular dynamics simulations are performed to investigate the liquid–liquid phase transition(LLPT) and the spatial heterogeneity in Al–Pb monotectic alloys. The results reveal that homogeneous liquid Al–Pb alloy undergoes an LLPT,separating into Al-rich and Pb-rich domains, which is quite different from the isocompositional liquid water with a transition between low-density liquid(LDL) and high-density liquid(HDL). With spatial heterogeneity becoming large, LLPT takes place correspondingly. The relationship between the cooling rate, relaxation temperature and percentage of Al and the spatial heterogeneity is also reported. This study may throw light on the relationship between the structure heterogeneity and LLPT, which provides novel strategies to control the microstructures in the fabrication of the material with high performance.     

Band structure of silicon and germanium thin films based on first principles

In nanomaterials, optical anisotropies reveal a fundamental relationship between structural and optical properties, in which directional optical properties can be exploited to enhance the performance of optoelectronic devices. First principles calculation based on density functional theory(DFT) with the generalized gradient approximation(GGA) are carried out to investigate the energy band gap structure on silicon(Si) and germanium(Ge) nanofilms. Simulation results show that the band gaps in Si(100) and Ge(111) nanofilms become the direct-gap structure in the thickness range less than 7.64 nm and7.25 nm respectively, but the band gaps of Si(111) and Ge(110) nanofilms still keep in an indirect-gap structure and are independent on film thickness, and the band gaps of Si(110) and Ge(100) nanofilms could be transferred into the direct-gap structure in nanofilms with smaller thickness. It is amazing that the band gaps of Si~((1-x)/2)Ge~xSi~((1-x)/2)sandwich structure become the direct-gap structure in a certain area whether(111) or(100) surface. The band structure change of Si and Ge thin films in three orientations is not the same and the physical mechanism is very interesting, where the changes of the band gaps on the Si and Ge nanofilms follow the quantum confinement effects.     

Structural,optical,and electrical properties of Cu-doped ZrO_2 films prepared by magnetron co-sputtering

Copper(Cu)-doped ZrO_2(CZO) films with different Cu content(0 at.%～ 8.07 at.%) are successfully deposited on Si(100) substrates by direct current(DC) and radio frequency(RF) magnetron co-sputtering. The influences of Cu content on structural, morphological, optical and electrical properties of CZO films are discussed in detail. The CZO films exhibit ZrO_2 monocline(ˉ111) preferred orientation, which indicates that Cu atoms are doped in ZrO_2 host lattice. The crystallite size estimated form x-ray diffraction(XRD) increases by Cu doping, which accords with the result observed from the scanning electron microscope(SEM). The electrical resistivity decreases from 2.63 ?.cm to 1.48 ?·cm with Cu doping content increasing, which indicates that the conductivity of CZO film is improved. However, the visible light transmittances decrease slightly by Cu doping and the optical band gap values decrease from 4.64 eV to 4.48 eV for CZO films.     

连续区间数的中位算子及其灵敏度分析

研究决策信息以区间数形式给出的方案决策问题。考虑到区间数非均匀分布的特点,为避免区间极端值在区间数确定中产生较大误差,本文将中位数概念运用到区间数的确定上,提出OIP(Ordered Interval Point)有序中位算子。取单位区间单调函数(BUM函数)为二分之一所表示的值为权重,将区间数确定为一个实数,并研究算子单调性和有界性的初等运算性质。通过比较OIP算子与COWA算子对态度参数和区间长度的反应灵敏度,获得了在一定条件下OIP算子对态度参数反应更稳健,对区间长度反应更灵敏的结论。最后用算例证明该算子的可行性和有效性。     

基于光谱合束技术的透射光栅模拟设计

半导体激光器光谱合束技术能够实现近衍射极限的高功率激光输出,已成为当前研究热点。衍射光栅的性能直接决定光谱合束的激光输出效果。模拟设计了一种针对940 nm波长、熔融石英材料的亚波长透射光栅。基于严格耦合波理论对光栅结构进行初步设计,运用Rsoft软件依次对光栅占空比、脊高和周期等参数进行优化确定,同时分析了各个参数对光栅衍射效率的影响。所设计的透射式光栅实现第-1级衍射级次的波分复用功能,衍射效率达到91.2%(TE模式),同时压缩其他衍射级次,使其衍射效率降到1.2%以下。同时在光栅入射角度59°±3°范围内保持90%以上的衍射效率,实现高功率激光输出的同时具有较高的误差容错率,易于调节,满足光谱合束技术的要求。     

一种新的磁传感器辅助弹载接收机跟踪环路的方法

针对弹载接收机高速旋转的特性,提出一种利用磁传感器测量弹体姿态,补偿旋转引起的载波多普勒频移和相位偏移的方法。首先,根据弹丸弹道学特征,推导弹体高速旋转引起的载波频移和相位偏移与弹体姿态的表达式;其次,研究了接收机载波跟踪环路的跟踪门限与弹体动态应力的关系;然后,给出弹体坐标系中,磁传感器测量弹体姿态的算法——极值比值法和积分比值法。仿真试验结果表明,磁传感器弹体姿态估计的方法能够有效降低弹载接收机跟踪环路的跟踪门限,其载噪比降低了3 dB·Hz,环路带宽减小了100 Hz以上,提高了弹载接收机GNSS信号跟踪能力。     

吡喃酮型花色苷衍生物的制备、光谱特性及抗氧化活性研究

吡喃酮型花色苷衍生物是一类具有非氧鎓离子结构和内酯型吡喃环结构的新型多酚类化合物。本研究以植物花色苷为原料,通过羧基吡喃花色苷形成及微氧化等两步反应法,结合柱色谱分离纯化技术,制备高纯度的吡喃酮花色苷衍生物A (Oxovitisin A)标准品;高效液相色谱-光电二极管阵列检测器-串联质谱法(HPLC-DAD-ESI-MS/MS)分析鉴定出纯化后反应产物Oxovitisin A的纯度达99%以上。利用荧光光谱仪、紫外可见光谱仪及超微弱化学发光光谱仪研究了Oxovitisin A及其前体物质花色苷(锦葵素-3-葡萄糖苷,Mv-3-gluc)与羧基吡喃花色苷A(Vitisin A))的光谱特性、色泽稳定性及抗氧化活性。结果表明：Oxovitisin A在440 nm激发波长下有最大荧光峰,最大发射波长490 nm,而具有氧鎓离子结构的两种前体物质无荧光特性。紫外光谱结合LAB色泽空间表征参数显示Oxovitisin A在不同pH值条件下具有不同的结构稳定性和色泽稳定性。Mv-3-gluc,VitisinA和Oxovitisin A在不同体系中均表现出良好的抗氧化活性,清除超氧阴离子自由基的IC₅₀值分别为71.4,30.7和19 μg·mL-1(抗坏血酸28 μg·mL-1),清除羟自由基的IC₅₀值分别为1.68,3.524,2.854 μg·mL-1(抗坏血酸8.441 μg·mL-1),对双氧水清除率的IC₅₀值分别为1.311,0.4098和0.288 μg·mL-1(抗坏血酸3.265 μg·mL-1),表明Oxovitisin A清除自由基和抗氧化的能力均高于反应前体物Mv-3-gluc和VitisinA及抗坏血酸。