溶液反应笼效应的改进

将溶剂压的概念引入溶液反应的笼效应中,不仅能用来说明溶剂的极性对溶液反应速率的影响,而且还能说明在何种溶剂下溶液反应速率会出现扩散控制和活化控制等动力学现象。     

环保型乳聚丁苯橡胶的研发进展

介绍了国内外关于乳聚丁苯橡胶的欧盟REACH法规、轮胎燃料标签法和美国国家燃油效率政策等环保法规;概述了乳聚丁苯橡胶的结构特征,进而说明了橡胶填充油对乳聚丁苯橡胶的作用及环保机理;详细介绍了引发剂、终止剂、硫化促进剂和防老剂等助剂的作用及其环保化的研发进展,并阐述了橡胶填充油的种类及其研发进展;综述了环保型乳聚丁苯橡胶产品的基本牌号及研发现状,并从助剂、填充油和橡胶产品等方面对环保型乳聚丁苯橡胶的发展提出了建议。     

低温下自旋为1/2的一维亚铁磁棱型链系统的元激发谱

利用不变本征算符法计算了低温下自旋为1/2的一维亚铁磁棱型链系统的元激发谱,并讨论了在此系统中不同的特殊情形下的元激发能量及不变本征算符法的优点与不足.     

On problems of optimal design of shallow shell with double curvature on elastic foundation

The present paper discusses a method of optimal design of the shallow shell with double curvature on the elastic foundation Substantially we take the initial flexural function as the control function or design variable which will be found and the potential energy of the external loads as the criterion of quality of the optimal design of the shallow shell with double curvature, therefore the functional of the potential energy will be aim function. The optimal conditions and the isoperimetric conditions belong to the constrained conditions. thus we obtain the necessary conditions of the optimal design for the given problems, at the same time the conjugate function is introduced, then the problems are reduced to the solutions of two boundary value problems for the differential equation of conjugate function and the initial flexual function.     

Back-n波形数字化模块的数据实时读出方法

Back-n是中国散裂中子源（CSNS）的反角中子束线,适用于精密核数据的测量。该装置的谱仪读出电子学采用共性化设计方法,利用高速波形数字化技术精密采集探测器输出信号波形。为完成对两通道、1 GSps,12 bit采样数据的读出和板载外设的控制,可以使用一种基于FPGA的高速数据实时读出方法。该方法不仅实现了数据接收、缓存上传等通用需求,还通过软件配置满足了实时触发处理等针对特定物理实验的特性需求。此外,FPGA的灵活使通过固件更新支持新实验或添加新功能成为可能。测试结果表明,该方法能够适应Back-n波形数字化模块高速数据读出的需求,峰值处理能力可达24 Gbps,符合物理实验需求。目前,基于实时读出方法实现的波形数字化模块已完成中子源谱仪实验现场的安装,工作稳定。Back-n is a back-streaming beam line at China Spallation Neutron Source, which is suitable for measure nuclear data precisely. The readout electronics of the spectrometers at this facility adopts general-propose design method, using high-speed waveform digitizing technology to record the detector output signal accurately. To read out two channels, 1 GSps, 12 bit sample data and control on-board devices, the real-time readout method of high-speed data based on FPGA technology can be considered. The method not only realizes the general requirements of the data upload, but also processes real-time triggers according to experiments via configuration. In addition, due to the flexibility of FPGAs, new experiments or new features can be supported through firmware updates. The test results show that the method is suitable for the high-speed data readout of field digitizing module at Back-n and peak capacity reaches up to 24 Gbps, which meets the requirements of the physical experiment. The field digitizing modules based on this method were installed at Back-n and work normally.     

哒嗪酮衍生物的合成和生物活性研究

以4,5-二氯-3(2H)-哒嗪酮和2-溴-1-苯乙酮或2-溴-1-苯-1-丁酮反应合成了中间体4,5-二氯-2-(2-苯基-2-氧代-乙基))-3(2H)哒嗪酮,再与吗啉和哌啶反应合成了标题化合物.所有化学物的结构通过1 HNMR、IR和元素分析确证.初步生物活性测定表明,部分化合物在200mg·L-1对东方粘虫有一定的生物活性.     

碱金属助催合成氨铁催化剂的研究(Ⅴ)——氯离子的效应

本文指出,氯离子是碱金属助催的合成氨催化剂Fe-AC(活性炭)-K(金属钾)体系的毒物。通过对含氯催化刑的活性测试,配合气相色谱、穆斯堡尔谱以及X-射线衍射图的研究,所得实验結果指出,KCl使催化剂中毒的机制是氯离子引起了高分散的小颗粒α-Fe的聚结,本文还讨论了氯离子对Fe体系和Ru体系催化剂的不同影响,归之于Fe系合成氨催化剂的结构敏感性。     

Vibrations of rectangular plates supported at corner points

This paper discusses by energy Theorem the method of approximate compulation for the lowest eigenfrequcncies of rectangular plates, on which there are symmetrical concentrated masses, supported at corner points. In the case of several concentrated masses, by using the principle of superposition we may find the reduced coefficients of masses conveniently. Hence we can obtain the lowest eigenfrequencies of thin plates. In the paper a good many numerical calculating examples are illustrated.     

BCxN薄膜的紫外透过光谱研究

利用射频磁控溅射方法以不同的溅射功率(80～130 W)制备出具备紫外增透性能的BCN,BC2N和BC3N薄膜.傅里叶红外吸收光谱和X射线光电子能谱测量发现样品的组成原子之间均实现了原子级化合.溅射功率对薄膜的组分和紫外增透性能有很大影响,其通过改变薄膜组分而影响紫外增透性能,且碳原子数小的样品紫外增透性能好.以110 W条件下制备的BCN薄膜中碳原子数最小,它的紫外增透性能最好,在200～350 nm波段附近平均透过率比玻璃提高了将近40%.     

Spin Switch and Qubit Register from a Spin Particle Controlled by a Time-Dependent Magnetic Field

A spin particle subjected to any time-dependent magnetic field is investigated in detail at different magnetic field configurations. Spin flip probability, spin alignment, cyclic and noncyclic nonadiabatic geometric phases are calculated exactly and their analytical expressions are presented. Our theoretical study shows that a spin particle controlled by a resonant time-dependent magnetic field can be used as efficient controllable devices of spin switch or qubit register.