VERIFICATION OF SMOM AND QMOM POPULATION BALANCE MODELING IN CFD CODE USING ANALYTICAL SOLUTIONS FOR BATCH PARTICULATE PROCESSES

For many processes of industrial significance, due to the strong coupling between particle interactions and fluid dynamics, the population balance must be solved as part of a computational fluid dynamics （CFD） simulation. In this work, a CFD based population balance model is tested using a batch crystallization reactor. In this CFD model, the population balance is solved by the standard method of moments （SMOM） and the quadrature method of moments （QMOM）. The results of these simulations are compared to analytical solutions for the population balance in a batch tank where 1） nucleation, 2） growth, 3） aggregation, and 4） breakage are taking place separately. The results of these comparisons show that the first 6 moments of the population balance are accurately predicted for nucleation, growth, aggregation and breakage at all times.     

浮力对混合对流流动及换热特性的影响

用热线和冷线相结合的技术测量垂直圆管内逆混合对流流体的平均速度、 温度以及它们的脉动. 较详细地研究了浮力对逆混合对流的流动特性和传热特性的影响. 评 估了实验中采用的冷线测量温度补偿速度探头温度敏感的影响. 逆混合对流的传热结果用无 量纲参数Ω (Ω= Grd / Red2 )来表示，其中，基于管道直 径的雷诺数Red变化范围为900~18000, 浮力参数Ω变化范围为 0.004899~0.5047. 研究结果表明，浮力对逆混合对流的换热有强化作用. 随着葛拉晓夫数Grd的增加，温度脉动，流向雷诺正应力和流向温度通量增 大，并且在靠近壁面的流体区域尤其明显. 热线与冷线相结合的技术适合于研究非绝热的流 动测量，可以用于研究浮力对流动和换热特性的影响.     

沿垂等温平板的自然对流问题的近似解析解

本文用加权残值得到了沿垂等温平板的自然对流问题的近似解析解。和已有准确解的比较表明，在平板表面附近，近似解有很好的精度，而且速度场的精度比温度场更好一些。文末还对配域法的准收敛问题作了说明。     

LINEAR ACTIVE STRUCTURES AND MODES (Ⅱ) —DISCRETE SYSTEMS AND BEAMS

IntroductionThestudiedobjectintheclassicstructuredynamicsisthepassivestructureswhicharechangedintoactivestructurewhencontroldevicesorsmartmaterialsareintroducedintoandthecontrolfunctionisapplied .Anactivestructureisgenerallycalledactivesystem .Asforthedefinitionofactivestructure ,itistheconceptofworthydiscussion[1].Thedefinitionshouldbebecomingrigorouswiththestudyontheactivestructuraldynamics.Withincertaincategoryofactivestructuresinpaper (Ⅰ ) [2 ],someattributesaboutthemodesoflinearactivest…     

MICROMECHANICAL MODELLING OF STRAIN SOFTENING IN MICROCRACK-WEAKENED QUASI-BRITTLE MATERIALS

By using the concept of domain of microcrack growth(DMG),themicromechanisms of damage in quasi-brittle materials subjected to triaxial either tensileor compressive loading are investigated and the complete strew-strain relation includingfour stages is obtained from micromechanical analysis.The regime of pre-peaknonlinear hardening corresponds to the distributed damage,i.e.the stable propagationof microcracks.After the attainment of the ultimate strength of load-bearing capacity,some microcracks experience the second unstable growth and the distributed damage istransmitted to the localization of damage.These analyses improve our understanding ofthe hardening and softening behaviors of quasi-brittle materials.     

固体润滑透平轴承 第三部分:在316℃下与陶瓷对摩的复合材料的发展

将以前与M-50钢对摩进行过评价的三维石墨纤维编织物增强的聚酰亚胺基自润滑保持架复合材料,在316℃下与热压氮化硅对摩进行了摩擦磨损试验,以确定其与陶瓷材料对摩时在摩擦学性能方面的变化。这些材料将应用在固体润滑的采用高比强度陶瓷滚动元件的高速透平轴承中。试验结果表明,这些复合材料与热压氮化硅对摩时的摩擦和磨损都急剧增大。这是由于从氮化硅环上发生了细小磨屑的物理和(或)化学转移,以及这些磨屑转移到复合材料表面上的缘故。调整复合材料中纤维和聚合物基体的比例,以及用所研究过的两种固体润滑剂混合物之一都可以降低摩擦与磨损。     

应用超临界温度氢吸附数据表征活性炭结构

为准确研究氢在活性炭上的吸附平衡,本文对比分析了由氮和氢在活性炭上吸附数据确定的活性炭的孔径分布(PSD)。首先,应用容积法,在0～12.5MPa压力范围、3个温度(113.15K、193.15K、273.15K)下测定氢在K05活性炭上的吸附平衡数据,并由引入系统内氢的质量衡算确定吸附池内氢的总量。其次,以77K氮吸附数据确定的PSD为初值、以吸附池内氢的总量为基准,通过优化非局域密度泛函理论(NDFT)计算值确定活性炭的PSD,进而比较表征介质、温度及平衡压力对PSD的影响。研究表明,应用氢吸附数据表征孔宽小于0.8nm的超细微孔的微分容积较大;平衡压力较高时,由不同温度氢吸附数据确定的超细微孔的PSD相近;孔宽大于1.2nm时,不同温度氢吸附数据确定的PSD间有明显偏差。须应用超临界温度高压氢或氢在亚临界温度区域的吸附数据,同时结合77K氮吸附等温线来表征吸附剂在超细微孔和微孔范围的PSD。     

Determination of captopril in patient human urine using ferrocenemonocarboxylic acid modified carbon nanotubes paste electrode

<正>In this work,we describe a new strategy for the electrochemical determination of captopril(CA) using ferrocenemonocarboxylic acid as a mediator and multiwall carbon nanotubes as sensors in aqueous solution at pH 7.0.The diffusion coefficient(D),and the kinetic parameters such as electron transfer coefficient(α).and heterogeneous rate constant(k_h),for CA were also determined using electrochemical approaches.Under the optimized conditions,the electrocatalytic oxidation peak current of captopril showed two linear dynamic ranges with a detection limit of 0.3×10~(-6) mol L~(-1) captopril.The linear calibration range was 0.8×10~(-6) to 65×10~(-6) mol L~(-1) using cyclic voltammetry.Finally,this modified electrode was also examined as a selective,simple and precise new electrochemical sensor for the determination of captopril in real samples such as drug and patient human urine.     

7-Deazapurines:Synthesis of new pyrrolo[2,3d]pyrimidin-4-onescatalyzed by a Brφnsted-acidic ionic liquid as a green and reusable catalyst

<正>Some new 2-aryl-3,7-dihydro-4H-pyrrolo[2,3-d]pyrimidin-4-ones have been prepared through cyclocondensation of 2-amino 1H-pyrrole-3-carboxamides with aromatic aldehydes followed by air oxidation in the presence of 3-methyl-1-(4-sulfonic acid)butylimidazolium hydrogen sulfate[(CH_2)_4SO_3HMIM][HSO_4],a Br(?)nsted-acidic ionic liquid,as a green and reusable catalyst in solvent-free conditions.     

Cocos nucifera L. water as green corrosion inhibitor for acid corrosion of aluminium in HCl solution

<正>The ability of Cocos nucifera L.water(CW) as non-toxic corrosion inhibitor for acid corrosion of aluminium in 0.5 mol/L HCl has been studied using chemical technique.CW shows significant inhibition as corrosion inhibitor,with 93%efficiency at the highest concentration of the inhibitor.The inhibitive action is attributed to the adsorption of the inhibitor molecules on metal surface following Langmuir adsorption isotherm.