秒的定义与变迁

一切物体都在不停地变化和运动着,这些变化和运动都是在一定的时间内进行的.为了定量描述具有广泛性和抽象性的时间,人们总是利用一些周期性的运动,并为了使时间测量准确统一,所选定的运动周期既要尽可能稳定,又要容易获得和复现.据此,本文就介绍秒的定义和变迁.     

丰中子Z=96—102同位素链的N=184闭壳

在相对论平均场理论框架下, 首先证明了对力强度存在明显的壳效应, 然后用此方法研究了Z=96—102区域内超重同位素链中中子壳封闭问题, 证明了在超重元素中,N=184处确实存在壳封闭. 并据此给出了一种检验壳封闭的新方法.     

合成磺胺增效剂(TMP)缩合工艺的改进研究

磺胺增效剂三甲氧苄二氨嘧啶(TMP)的疗效显著,应用日益广泛,目前国内已有很多药厂生产.但在现行缩合工艺中存在着收率偏低(80%),反应时间长(15h)等缺点[1],新工艺针对此种情况进行了工艺改进,收率达90%.并确定出新的合成条件为:当TMB的投料量为20g时,甲醇钠体积50mL,乙酸乙酯体积为2.36 mL,后处理过程中所用冰水量80 mL;甲氧丙腈生成温度20～25℃,生成时间50～60 min;缩合反应温度25℃,反应时间8h.     

Magnetic-Field-Induced Strains of Bonded Ni-Mn-Ga Melt-Spun Ribbons

Non-stoichiometric Ni50Mn27 Ga23 polycrystalline ribbons are prepared by melt-spinning technique. The magneticfield-induced strain （MFIS） of Ni-Mn-Ga bulk alloy prepared by bonding the melt-spun ribbons is obtained. The experimental results show that Ni50Mn27Ga23 bonded ribbons exhibit a typical thermal-elastic shape memory effect in the thickness direction. The martensitic transformation strain of bonded ribbons is an expansive strain of about 0.3% without the magnetic field and a contractive strain of about -0.46% at the magnetic field of 1 T. The field can not only enhance the value of the martensitic transformation strain of the bonded ribbons, but can also change the direction of the strain. The bonded ribbons alloy presents negative MFIS and obtains a larger value of the strain though influenced by the adhesive between the ribbons. Therefore, the preparation technique of the Ni-Mn-Ga bulk alloy by bonding melt-spun ribbons is helpful to get rid of the size restriction of the ribbon and to broaden the applications of the ribbons.     

时间变换过程的 Revuz 测度

文证明 Markov过程的能量泛函与 Revuz 测度在时间变换下保持不变, 并通过直接计算的方法导出时间变换过程的 L\’evy 系统和跳跃测度.     

Determination of aerosol extinction coefficient and mass extinction efficiency by DOAS with a flashlight source

With the method of differential optical absorption spectroscopy （DOAS）, average concentrations of aerosol particles along light path were measured with a flashlight source in Chiba area during the period of one month. The optical thickness at 550 nm is compared with the concentration of ground-measured suspended particulate matter （SPM）. Good correlations are found between the DOAS and SPM data, leading to the determination of the aerosol mass extinction efficiency （MEE） to be possible in the lower troposphere. The average MEE value is about 7.6m^2.g^-1 , and the parameter exhibits a good correlation with the particle size as determined from the wavelength dependence of the DOAS signal intensity.     

大质量分子云核和恒星形成活动

用国家台紫金山天文台13.7米望远镜的三谱线系统对23个有线翼特征的大质量恒星形成区进行了观测.获得了12个云核,发现其中5个具有外向流,2个有系统的速度变化,1个可能有塌缩,这些核的质量分布在9.4*10e2到2.2*10e5个太阳质量,氢分子密度从每立方厘米3.4*10e2到1.2*10e4.外向流的质量大于3.5个太阳质量,动能高于9*10e37焦耳,比低质量年轻星体附近的外向流大很多,每个核往往包含着几十个2mass源,其色指数和亮度各不相同,但最红的那个总是在IRAS源的误差椭圆内,可能就是IRAS源的对应体.     

纳米银粒子表面吸附染料分子的荧光增强及荧光猝灭现象

本文通过阴、阳离子型染料分子荧光素钠(FS)及若丹明6G(Rh6G)吸附在银胶体系内纳米银颗粒表面上,首次发现了FS的荧光增强谱及Rh6G的荧光猝灭谱.引起荧光增强及荧光猝灭的因素,除局域场和分子到金属表面能量转移这两个方面外,还与纳米银表面与被吸附分子之间的距离有关.     

一类含参积分的连续性定理

本首先研究同等连续函数列所具有的性质，并利用所得到同等连续函数列的性质证明了一类含参积分的连续性定理。     

Time-Dependent Quantum Dynamics of Dissociation for CH4 on an Ni（100） Surface

The semirigid vibrating rotor target (SVRT) model proposed by Zhang [J.Chem. Phys. 111 (1999) 3929] is applied to study the dynamics of dissociative adsorption for CH4 on a fiat and static Ni(100) surface. The molecule CH4 is treated as a semirigid vibrating rotor CH3-H, and the London-Eyring-Polanyi-Sato potential