用数轴法快速书写质子守恒表达式

介绍了用数轴法书写质子守恒表达式的基本操作,分别对单一溶液、混合溶液进行了研究,阐述了化学教学中数形结合的重要性。     

Anisotropic self-diffusion of fluorinated poly(methacrylate) in metal-organic frameworks assessed with molecular dynamics simulation

Utilizing the periodically structured metal–organic framework(MOF) as the reaction vessel is a promising technique to achieve the aligned polymer molecular chains, where the diffusion procedure of the polymer monomer inside MOF is one of the key mechanisms. To investigate the diffusion mechanism of fluorinated polymer monomers in MOFs, in this paper the molecular dynamics simulations combined with the density functional theory and the Monte Carlo method are used and the all-atom models of TFMA(trifluoroethyl methacrylate) monomer and two types of MOFs, [Zn_2(BDC)_2(TED)]n and[Zn_2(BPDC)_2(TED)]n, are established. The diffusion behaviors of TFMA monomer in these two MOFs are simulated and the main influencing factors are analyzed. The obtained results are as follows. First, the electrostatic interactions between TFMA monomers and MOFs cause the monomers to concentrate in the MOF channel, which slows down the monomer diffusion. Second, the anisotropic shape of the one-dimensional MOF channel leads to different diffusion speeds of monomers in different directions. Third, MOF with a larger pore diameter due to a longer organic ligand, [Zn_2(BPDC)_2(TED)]n in this paper, facilitates the diffusion of monomers in the MOF channel. Finally, as the number of monomers increases, the self-diffusion coefficient is reduced by the steric effect.     

重量法测定高锡钨精矿中的钨

为消除重量法测定钨精矿中钨时锡的干扰,在溶解过程中用氢溴酸反复冒烟进行消除,利用ICP–OES法测定残渣和滤液中剩余钨量,再与传统重量法相结合进行钨的定量测定。结果表明,该方法的检出限为0.01μg/m L,测定结果的相对标准偏差为3.53%~5.26%(n=5),加标回收率为98.78%~100.93%。该分析方法不仅能够消除锡的干扰,而且可以相对快速得到稳定可靠的结果。     

络合-水热法制备碱式硫酸镁纳米线

以MgSO4·7H2 O和NaOH为原料,邻苯二甲酸氢钾(KHpht)作为络合剂,采用络合-水热法制备碱式硫酸镁(MOS)纳米线.考察了反应条件对MOS纳米线形貌的影响,并对产物进行了表征和分析.确定了制备MOS纳米线的较优条件:MgSO4浓度为0.3 mol/L,n(NaOH)/n(MgSO4)为2.5,n(KHpht)/n(MgSO4)为1.1,无水乙醇作为分散剂,水热合成温度160℃,反应时间10 h.所得到MOS纳米线形貌均匀,长度在10～20μm,直径在20～100 nm,纳米线沿[010]方向生长.     

一类运算图的匹配数

设G是一个简单图,把G的每条边e=(a,b)变换成一个三角形ae^*b而得到一个新图,记为R (G), 其中新增加的顶点e^*的度为2.本文证明R (G)的匹配数完全由图G的顶点度序列确定.     

一种基于H.264的立体视频编码中的视差估计快速算法

视差估计与补偿是立体视频图像压缩编码中的关键技术．本文分析了立体摄像系统视差分布的约束条件（外极线约束、方向性约束等）和视差矢量的相关性（帧内视差矢量的空域相关性和帧间视差矢量的时域相关性）,并结合H．264标准中的多种块选择模式之间的相关性,提出了基于H．264的立体视频编码的视差估计快速算法．实验结果表明,提出的快速算法能有效地降低视差估计的计算复杂度．     

Near-Field Enhancement and Absorption Properties of Metal-Dielectric-Metal Microcavities in the Mid-Infrared Range

An important property of optical metamaterials is the ability to concentrate light into extremely tiny volumes, so as to enhance their interaction with quantum objects. In this work, we numerically study the near-field en- hancement and absorption properties inside the cylindrical microcavities formed by a Au-GaAs-Au sandwiched structure. At normal incidence, the obtained reflection spectra show that the resonance wavelength of microcav- ities operates in the range of 5-5.S μm. We also calculate the contrast C （C = 1 - Rmln）, which can be increased to 97% by optimizing the structure＇s geometry parameters. Moreover, we demonstrate that the multilayer struc- ture with sub-wavelength electromagnetic confinement allows 10^3-10^4-fold enhancement of the electromagnetic energy density inside the cavities, which contains the most energy of the incident electromagnetic radiation and has a higher quality factor Q, indicating a narrower linewidth for surface enhanced molecular absorption spec- troscopy and the tracking of characteristic molecular vibrational modes in the mid-infrared region. The structure is insensitive to the polarization of the incident wave due to the symmetry of the cylindrical microcavities. The unique properties of the metal-dielectric-metal metamaterials will have potential applications in new plasmonic detectors, bio-sensing and solar cells, etc.     

具有植物激素活性的Schiff碱化合物的研究(Ⅲ)——噻二唑类Schiff碱的合成及其生物活性

含杂环的Schiff碱类化合物具有很高的植物生长激素的活性[1],近十几年来受到化学家的重视.前文[2]已报道了三唑类Schiff碱的合成及其生物活性.已发现含噻二唑环的化合物具有高的生物活性,1,3,4-噻二唑的衍生物可以作为杀菌剂、除草剂和植物生长调节剂[3～6],连有巯基(-SH)的噻二唑的席夫碱目前还未见报道.我们将2-氨基-5-巯基-1,3,4-噻二唑与芳醛或杂环醛作用,合成了12个新的Schiff碱化合物,发现其中一些化合物具有明显的植物激素活性,合成的反应式为:     

Windows应用程序动画界面的实现与优化

讨论了在Ｗｉｎｄｏｗｓ环境下,运用句柄和位图的处理,使应用程序界面实现了原样复制和变形动画两大类出场和离场方式,从而使应用程序的交互界面大为改观,视觉效果更加生动．     

On the Minimum Spanning Tree Determined by n Points in the Unit Square

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