全文获取类型
收费全文 | 105篇 |
免费 | 74篇 |
国内免费 | 33篇 |
专业分类
化学 | 64篇 |
晶体学 | 2篇 |
力学 | 2篇 |
综合类 | 6篇 |
数学 | 15篇 |
物理学 | 123篇 |
出版年
2023年 | 2篇 |
2022年 | 2篇 |
2021年 | 2篇 |
2020年 | 4篇 |
2019年 | 2篇 |
2018年 | 5篇 |
2017年 | 2篇 |
2016年 | 1篇 |
2015年 | 2篇 |
2014年 | 4篇 |
2013年 | 10篇 |
2012年 | 6篇 |
2011年 | 11篇 |
2010年 | 7篇 |
2009年 | 19篇 |
2008年 | 16篇 |
2007年 | 20篇 |
2006年 | 17篇 |
2005年 | 21篇 |
2004年 | 10篇 |
2003年 | 7篇 |
2002年 | 5篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1999年 | 5篇 |
1997年 | 3篇 |
1996年 | 4篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1988年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1979年 | 1篇 |
1961年 | 1篇 |
1960年 | 1篇 |
排序方式: 共有212条查询结果,搜索用时 15 毫秒
91.
A modification potential method of calculating total cross sections of electrons scattering from complex molecules C2H6, C2F6, C6H6 and C6F6 at 100 eV-5000 eV
下载免费PDF全文
![点击此处可从《中国物理》网站下载免费的PDF全文](/ch/ext_images/free.gif)
A complex optical model potential modified by
incorporating the concept of bonded atom, which takes into consideration the
overlapping effect of electron clouds between two atoms in a molecule, is
first employed to calculate the total cross sections for electrons
scattering from such complex molecules as C总交叉断面 电子散射 添加规则 原子分子碰撞 电子云 total cross section, electrons scattering, additivity
rule, atomic and molecular collision Project supported by the National Natural Science Foundation of China (Grant No 10574039). 2005-11-10 2005-11-102005-11-30 A complex optical model potential modified by incorporating the concept of bonded atom, which takes into consideration the overlapping effect of electron clouds between two atoms in a molecule, is first employed to calculate the total cross sections for electrons scattering from such complex molecules as C2H6, C2F6, C6H6 and C6F6 using the aclditivity rule model at Hartree-Fock level over the energy range from 100 eV to 5000 eV. The total cross sections are quantitatively compared with those obtained by experiments wherever available, and they are in good agreement with each other over a wide energy range. It is shown that the modified potential together with the additivity rule model is completely suitable for the calculation of total cross sections of electrons scattering from such complex molecules as C2H6, C2F6, C6H6 and C6F6 above 200 eV-300 eV. 相似文献
92.
Considering the changes of the geometric shielding effect in a molecule as the incident electron energy varing, an empirical fraction, which is dependent on the incident electron energy, is presented. Using this empirical fraction, the total cross sections (TCSs) for electrons scattering from complex polyatomic molecules C2F4 and SO2 are calculated over a wide energy range from 30 to 5000 eV together with the additivity rule model at Hartree-Fock level. In the TCS calculations, the atoms are presented by the spherical complex optical potential, which is composed of static, exchange, polarization and absorption contributions. The quantitative TCSs above 100 eV are in good agreement with those obtained by experiments and other theories. It is proved that the empirical fraction, which exhibits the TCS contributions of shielded atoms in a molecule at different energies, is reasonable. 相似文献
93.
Absolute Differential Cross Sections for Elastic Scattering of Electrons from CO at Intermediate and High Energies
下载免费PDF全文
![点击此处可从《中国物理快报》网站下载免费的PDF全文](/ch/ext_images/free.gif)
The additivity rule model together with the complex optical model potential correlated by the concept of bonded atoms, which considers the overlapping effect of electron clouds between two atoms in a molecule, is firstly employed to calculate the absolute differential cross sections for electrons scattered by carbon monoxide at intermediate and high energies at the Hartree-Fock level. A comparison of elastic differential cross section results, obtained by using the correlated complex optical model potential, with the available experimental data,shows a significant improvement over the uncorrelated ones. The differential cross sections obtained by using thecorrelated complex optical model potential are in very good agreement with the experimental data. It is shown that the additivity rule model together with the correlated complex optical model potential is suitable for the calculations of the absolute differential cross sections of e-CO scattering. 相似文献
94.
利用可加性规则,使用Roothaan-Hartree-Fock波函数,在100~5 000 eV下首次采用由束缚原子概念修正过的复光学势,对电子被等电子(Z=10)分子CH4、H2O、HF和NH3散射的总截面进行了计算.束缚原子不同于自由原子之处,是束缚原子考虑了在不同分子中电子云的不同重叠,将计算结果与实验及其它计算结果进行了比较.结果表明,利用被束缚原子概念修正过的复光学势及可加性规则进行计算,其结果的精度要比利用未被束缚原子概念修正过的复光学势及可加性规则进行计算得到的结果好. 相似文献
95.
96.
97.
We construct a number(n)-resolved master equation(ME)approach under self-consistent Born approximation(SCBA)for noise spectrum calculation.The formulation is essentially non-Markovian and incorporates properly the interlay of the multi-tunneling processes and many-body correlations.We apply this approach to the challenging nonequilibrium Kondo system and predict a profound nonequilibrium Kondo signature in the shot noise spectrum.The proposed n-SCBA-ME scheme goes completely beyond the scope of the Born-Markovian master equation approach,in the sense of being applicable to the shot noise of transport under small bias voltage,in non-Markovian regime,and with strong Coulomb correlations as favorably demonstrated in the nonequilibrium Kondo system. 相似文献
98.
99.
Investigations on molecular constants of the CD(X^2∏) radical and elastic collisions between ground-state C and D atoms at low temperatures
下载免费PDF全文
![点击此处可从《中国物理 B》网站下载免费的PDF全文](/ch/ext_images/free.gif)
The potential energy curve of the CD(X~2Π) radical is obtained using the coupled-cluster singles-doublesapproximate-triples [CCSD(T)] theory in combination with the correlation-consistent quintuple basis set augmented with diffuse functions,aug-cc-pV5Z.The potential energy curve is fitted to the Murrell-Sorbie function,which is used to determine the spectroscopic parameters.The obtained D0,De,Re,ωe,ωeχe,αe and Be values are 3.4971 eV,3.6261 eV,0.11197 nm,2097.661 cm 1,34.6963 cm 1,0.2083 cm 1 and 7.7962 cm 1,respectively,which conform almost perfectly to the available measurements.With the potential obtained at the UCCSD(T)/aug-cc-pV5Z level of theory,a total of 24 vibrational states have been predicted for the first time when J = 0 by solving the radial Schr¨odinger equation of nuclear motion.The complete vibrational levels,the classical turning points,the inertial rotation constants and centrifugal distortion constants are reproduced from the CD(X~2Π) potential when J = 0,and are in excellent agreement with the available measurements.The total and the various partial-wave cross sections are calculated for the elastic collisions between the ground-state C and D atoms at energies from 1.0×10 11 to 1.0×10 4 a.u.when the two atoms approach each other along the CD(X~2Π) potential energy curve.Only one shape resonance is found in the total elastic cross sections,and the resonant energy is 8.36×10 6 a.u.The results show that the shape of the total elastic cross section is mainly dominated by the s partial wave at very low temperatures.Because of the weak shape resonances coming from higher partial waves,most of them are passed into oblivion by the strong total elastic cross sections. 相似文献
100.