基于正交调制的偏振光谱成像系统研究

为了同时获取目标的全偏振二维图像信息和其光谱信息,设计了一种基于正交调制的偏振光谱成像系统。该系统由光学接收模块、相位调制器、Wollaston棱镜、Savart偏光镜、检偏器以及成像模块组成。其可以将原始光信号分解成两束相互正交的偏振光,并且分别成像在CCD焦平面的上下两部分上,从而构成两幅偏振图像。两组图像的叠加可以将干涉条纹的数据相互抵消,从而获得目标的纯图像信息,两组图像的相减可以将目标灰度图像相互抵消,从而获得目标的纯干涉条纹。通过理论分析与计算得到了光强分布函数和光谱变化形式。实验在稳定的光源环境中采用高对比度目标与背景板,完成了全偏振图像的实时采集。经相位校正和切趾处理改善了干涉图像的畸变,又通过去低频滤波和阈值滤波抑制了图像中背景噪声的影响,从而实现了对目标图像的提取及偏振光谱的复原。该系统具有稳定性高、光谱分辨率可调、信噪比高、可识别能力强等特点,对在复杂背景中提取目标图像、光谱及偏振态信息具有重要意义。     

晶粒尺寸对软-硬磁性晶粒间交换耦合相互作用和有效各向异性的影响

以软磁性相α—Fe和硬磁性相Nd2Fe14B为例，研究了软、硬磁性晶粒间的交换耦合作用和有效各向异性随晶粒尺寸和软、硬磁性晶粒不同尺寸比例(Ds：Dh)的变化关系。当晶粒尺寸大于其铁磁交换长度时，晶粒的各向异性分为晶粒内部无交换耦合和晶粒表面有交换耦合部分，其各向异性常数为两部分的统计平均值。计算结果表明：软、硬磁性晶粒间的有效各向异性随晶粒尺寸的减小而下降，随软、硬磁性晶粒尺寸比值(Ds：Dh)的减小而增加。为使软、硬磁性晶粒间的有效各向异性常数Keff保持较高的值，应控制硬磁性晶粒大于30nm。软磁性晶粒在10nm左右。     

有机多孔高聚物石英PLOT柱的制备及性能评价

 采用原位聚合法，制备出了乙基乙烯苯与二乙烯苯的多孔球形石英ＰＬＯＴ柱，并对柱子的性能进行了评价。     

质谱法测定水中溶解氙的含量及其同位素组成

利用设计的一套水样中提取并分离Xe的装置,与稀有气体质谱仪Helix SFT联用,建立了高精度水中溶解Xe的含量及其同位素组成的分析方法。对该装置的密封性及本底进行检测,证明此方法可靠;循环升温-降温法分离Xe气中大量Ar的方法,可在短时间内除掉绝大部分Ar,减小其对Xe含量及同位素组成的测试影响。该方法的检出限可低至10-13~10-14 L/L;对空气饱和水进行测试, Xe 含量、129 Xe/131 Xe 和132 Xe/134 Xe的测试结果的相对标准偏差分别为1.00%,0.10%和0.20%,误差分别为0.93%,0.16%和0.50%;分析了造成测试误差的因素,明确了误差的来源。     

Design and performance study of the LEPD silicon tracker onboard the CSES satellite

The low energy particle detector (LEPD) is one of the main payloads onboard the China seismic electromagnetic satellite (CSES). The detector is designed to ascertain space electrons (0.1-10 MeV) and protons (2-50 MeV). It has the capability of identifying the electrons and protons, to measure the energy spectrum and the incident angle of the particles. The LEPD is made up of a silicon tracker system, a CsI (Tl) mini-calorimeter, an anti-coincidence system made by plastic scintillator, as well as electronics and a data acquisition system (DAQ). The tracker is also a kind of E-E telescope; it consists of two layers of double-sided silicon strip detectors (DSSD). The signals emerging from the silicon tracker can be read out by two pieces of application specific integrated circuit (ASIC), which also can generate an event trigger for the LEPD. The functions of the DSSD system in the LEPD for charged particles were tested by 241Am @5.486 MeV α particles. The results show that the DSSD system works well, and has high performance to detect charged particles and measure the position of incident particles.     

加速溶剂萃取-FMS净化-高分辨气相色谱-高分辨质谱(HRGC-HRMS)定量测定鱼组织中二(噁)英类多氯联苯

多氯联苯(polychlorinated biphenyls,PCBs)是一类包括209种化合物的持久性有机污染物,是斯德哥尔摩公约中优先控制的12类持久性有机污染物之一,曾经大量生产用于变压器和电容器内的绝缘介质、热交换剂、润滑剂、增塑剂等[1],全球共生产150万吨多氯联苯[2-3]。在209种PCBs中有1     

A geometric factor calculation method based on the isotropic flux assumption

One of the instruments onboard the China Seismic Electromagnetic Satellite （CSES） is the Low Energy Particle Detector （LEPD）. The primary objective of LEPD is to provide measurements of the fluxes, energy spectra and pitch angles of 100 keV to 10 MeV electrons and protons from 2 to 50 MeV in the Earth＇s magnetosphere. The geometric factor is one of the principle parameters of a detector, which converts the physical quantity-count rate to the particle quantity-flux. In this paper, we calculated the geometric factor of LEPD via computer modeling of an isotropic radiation environment. It was first demonstrated that the radiation intensity related should obey a cosine-law, then a general sampling method of generating this distribution via GPS of GEANT4 was explained. Furthermore, combined with flux normalization, a comparison of the geometric factor calculation of a set of 2-layer detectors with different shapes （cylinder, truncated cone and rectangle） was performed. Results show a generally good agreement between simulation and analytical calculations for the cylinder and truncated cone detectors, and the result of the rectangular one, for which there is no accurate analytical formula, is consistent with the previous simulated results by others. As a practical instance of the 2-layer rectangle detector, the geometric factor of LEPD is 10.336±0.036 m cm2·sr for 10 MeV proton and 8.211±0.032 m cm2·sr for 8 MeV electron.     

铁铂硫原子簇化合物的合成与结构研究 V: [MoFe3S4]类立方烷簇合物的转化反应和[Et4N]3[Mo2Fe6S8(SC6H4CH3-m)3Cl6]的晶体结构

具[MoFe2S4]类立方烷结构单元的双类立方烷化合物[Et4N]4[Mo2Fe7S8(SR)12](1a,R=Ph; 1b, R=tolyl-m)或单类立方烷化合物[MoFe3S4(dteR2)5](2a, R=Me; 2b, R=Et)与酰氯在乙腈中反应, 分别得到不含Fe桥的双类立方烷化合物(Et4N)3[Mo2Fe6S8(SR)3Cl6](3a, R=Ph; 3b, R=toly-m)与[MoFe3S4]骨架支解后的Fe(dteR2)2Cl(4a, R=Me; 4b, R=Et)。说明在相同反应条件下, [MoFe3S4]单元在1中比在2中稳定, 本文首次将1型与3型结构通过一步化学反应连系起来。3型化合物的产生得到X射线衍射测定及^1H NMR谱的证实。本文报道3b的单晶结构及3的^!H NMR数据, 3b属六方晶系, P63/m, a=1.6827(3), c=1.5951(16)nm; V=3.91158nm^3; Dc=1.491g/cm^3;Z=2; F(000)=1780; 偏离因子R=0.048, 化合物2与酰氯反应产生4, 由红外及紫外可见光谱证实。     

148.5mm椭圆反射镜的加工

介绍１４８．５ｍｍ椭圆反射镜的光学加工方法，差重叙述粗磨成型工艺。     

气相色谱-离子阱二级质谱对照高分辨质谱对食品中二噁英类多氯联苯的测定

确定了气相色谱-离子阱二级质谱在分析食品中12种二噁英类多氯联苯残留的定性参数;优化了分析过程的质谱条件;研究了实际样品(河豚、鳗鱼、甜虾、鸡脂肪、奶粉、猪肠衣)离子阱串联质谱测定值与高分辨质谱值的准确度差异.样品采用加速溶剂萃取方法提取、流体控制系统净化及离子阱二级质谱和高分辨质谱测定.两种方法测定值之间的回归方程和相关系数分别为:4种非邻位取代二噁英类多氯联苯,y=0.781 5x,r=0.933 1;8种邻位取代二噁英类多氯联苯,y=0.807 3x,r=0.996;样品中12种多氯联苯总毒性当量(Total TEQ):y=0.518 1x 0.125 5,r=0.992.离子阱二级质谱和高分辨质谱的检出限分别为0.5ng/kg和0.1ng/kg,样品中同位素内标的回收率为41%～102%.