傅立叶变换离子回旋共振质谱进展

综述了傅立叶变换离子回旋共振质谱（ＦＴＩＣＲＭＳ）仪器特点和各种新技术。主要对紫外光解离技术、红外多光子解离技术、表面诱导解离、黑体红外辐射离、电子捕获解离等离子解离新方法进行了介绍。此外,应用多次激发碰撞活化技术、超低能量激发技术、持续偏共振激发、存储波形逆傅立叶变换技术等离子再测量技术能提高源内离子碰撞诱导解离效率,更好的实现ＭＳ＾n的产技术。文章最后阐述了ＦＴＭＳ在生物分析及气相分子离子反应     

马来酸酐与二苄基马来酸酯共存体系的荧光分析法研究

本实验测定了二苄基马来酸酯甲醇溶液的荧光光谱，并发现马来酸酐对该荧光体系有猝灭作用，通过对不同马来酸酐浓度与各种浓度的二苄基马来酸酯甲醇溶液在４００ｎｍ处荧光强度数据的分析，发现马来酸酐的浓度与荧光猝灭程度在一定范围内呈良好的线型关系。据此，提出了用荧光猝灭法对马来酸酐及二苄基马来酸酯的定量分析     

星载张力索网天线结构混合变量的多目标优化

以纵向拉索调整力大小和可调整的纵向拉索数目为设计变量,可调整的纵向拉索数目最少和网状反射面的均方根误差最小为目标函数,应力和频率为约束条件,建立了大型空间网状可展开天线的形面调整的多目标优化数学模型,并用遗传算法进行了优化求解。优化结果表明:该方法在提高天线表面精度的同时,能有效地减少可调整的纵向拉索数目,降低了工程人员在网面调整中的繁杂劳动。并且,网面调整的总次数也远少于实际工程中的调整,对工程应用具有一定的指导意义。     

TiN和Ti1-xSixNy薄膜的微观结构分析

使用x射线衍射(XRD)、x射线光电子谱(XPS)、高分辨透射电子显微镜(HRTEM)和原子力显微镜(AFM)多种观测手段分析了TiN薄膜和Ti1-xSixNy纳米复合薄膜的微观结构.实验分析证明Ti1-xSixNy薄膜是由直径为3-5nm的纳米晶TiN和非晶Si3N4相构成,并且Ti1-xSixNy薄膜的表面粗糙度小于相同条件下制备的TiN薄膜,在Ti1-xSixNy薄膜体系的自由能中引入界面能的概念,在此基础上分析了体系中TiN晶粒的取向问题.     

荧光光度法直接测定环境水中苯酚和十二烷基苯磺酸钠的含量

本文研究了用荧光分光光度法直接测定环境水中苯酚和十二烷基苯磺酸钠（ＳＤＢＳ）二种水中污染物。在ｐＨ〉１１直接测定ＳＤＢＳ含量，波长为λｅｘ／λｅｍ＝２３０／２９５ｎｍ，检出限４．４ｎｇ／ｍＬ，线性范围０￣２．２μｇ／ｍｌ。在ｐＨ＝６，波长为λｅｘ／λｅｍ＝２３０／２９５ｎｍ，测得二者合量，从合量中减去ＳＤＢＳ含量即得苯酚含量，检出限４．０ｎｇ／ｍｌ，线性范围０￣０．８５μｇ／ｍＬ，回收率达９９％￣     

Microwave reflection properties of planar anisotropy FesoNi50 powder/paraffin composites

The reflection properties of planar anisotropy Fe50Ni50 powder/paraffin composites have been studied in the microwave frequency range.The permeability of Fe50Ni50 powder/paraffin composites is greatly enhanced by introducing the planar anisotropy,and can be further enhanced by using a rotational orientation method.The complex permeability can be considered as the superposition of two types of magnetic resonance.The resonance peak at high frequency is attributed to the natural resonance,while the peak at low frequency is attributed to the domain-wall resonance.The simulated results of the microwave reflectivity show that the matching thickness,peak frequency,permeability,and permittivity are closely related to the quarter wavelength matching condition.The Fe50Ni50 powder/paraffin composites can be attractive candidates for thinner microwave absorbers in the L-band(1-2 GHz).     

超声提取/高效液相色谱法测定土壤中的4-壬基酚

在考察不同提取方法和有机溶剂提取效率的基础上,建立了土壤样品中内分泌干扰物4-壬基酚（4-NP）的超声提取/高效液相色谱(紫外检测器)分析方法。结果显示,以二氯甲烷作提取溶剂时超声提取对土壤中4-NP的提取效率高于索氏提取法;不同有机溶剂的超声提取效率依次为二氯甲烷-甲醇(9∶1)＞二氯甲烷＞甲醇≈丙酮。样品采用二氯甲烷-甲醇(9∶1)超声提取,经硅胶柱净化、高效液相色谱检测,土壤在4-NP的高、中、低3个加标水平下的平均回收率为91%~94%,相对标准偏差为4.3%~7.2%,方法的检出限为2.0 μg/kg。采用该方法对广东省部分土壤中的4.NP进行检测,得到其含量为5.3~16 μg/kg(干重),低于河北省污水灌溉土壤中的含量。该方法简便快捷、灵敏、重现性好,适用于土壤样品中4-NP的分析。     

Tris（2,2＇-bipyridyl） Ruthenium（Ⅱ） Doped Silica Film Modified Indium Tin Oxide Electrode and Its Electrochemiluminescent Properties

An approach was reported to synthesize silica hybridized ruthenium bipyridyl complex through amidation reaction by covalent attachment of bis（bipyridyl）-4,4＇-dicarboxy-2,2＇-bipyridyl-ruthenium to （3-aminopropyl）-triethoxysilane. The hybrid complex then was gelatinized through acid catalytic hydrolysis method and a sol-gel modified indium tin oxide electrode was prepared via spin coating technique. As prepared indium tin oxide electrode possesses good stability therein with excellent electrochemiluminescence behavior.     

二氯四(苯丙酮-1, 2, 4-三唑)合钴六水配合物晶体结构

0IntroductionRecently,thecompoundscontaining1H-1,2,4-tr-iazolegrouphaveattractedmuchinterestbecauseoftheirexhibitingsomefungicidalactivityandplantgrowthregulatingactivity犤1犦,andshowingantibacterialactivityagainstPucciniareconditeandrootsgrowthregulationforcucumber犤2犦.Also,suchcompoundsareincreasinglybeingstudiedbecauseofthecoordinationchemistryofazolesactingasligandsintransitionmetalcompounds.Asamatteroffact,thetriazolederivativeshavebeenextensivelyusedasterminalandbridgingligands,andthey…     

二(三苯基膦)水杨酸铜(Ⅰ)乙醇溶剂配合物的晶体结构

0IntroductionThestudyofcopper?complexesisinvestigatedinmanylaboratories.Amongthereasonsforcarryingouttheinvestigationofsuchspeciesaretheirstructuralfeatures犤1犦,theusefulnessofcopper?compoundsinorganicsyntheses犤2犦andthewell-documentedimpor-tanceofcopper?centersattheactivesitesofanumberofprotein犤3犦.Concerningcopper?carboxy-latesafurtherinterestexists,stemmingfromtheiruseinhomogeheouscatalysedhydrogenation犤4犦.Thecopper?bis(triphenylphosphine)cationisasoft,butflexi-bleacceptorionthatcanacc…