球壳型V2O5的制备及电池材料性能研究

采用软模板法制备出球壳型五氧化二钒(V_2O_5),并对其作为LIB正极材料时的性能进行了测试,结果表明:材料具有较理想的比容量和充放电效率,第二次放电比容量高达288mAhg~(-1);但循环稳定性一般,需通过掺杂、锂化等方式来改进.     

非线性轴承转子系统稳定性准则的研究

目前对于非线性轴承转子系统，仍普遍采用其线性化系统的对数衰减率作为系统的稳定性判据，这造成了理论和实验结果相差较大。本文对［１］中提出的ＰＣＭ法作了改进，通过对无限长滑动轴承支承对称刚性单盘转子系统的非线性稳定性规律进行的分析，揭示了上述现象的非线性本质，为建立更适用于非线性轴承转子系统的稳定性准则提供参考。     

喹啉醛亚胺钴配合物催化丁二烯顺式-1,4选择性聚合

合成和表征了一系列以[NN]双齿喹啉醛亚胺为配体的二氯化钴配合物（1a~6a）。 以X射线单晶衍射技术分析了配合物2a、3a和4a的分子结构。 配合物2a和3a以单核四配位（2个氮原子和2个氯原子）的形式结晶,而配合物4a由于取代基空间位阻小,则以双核的形式结晶。 在倍半乙基氯化铝（EASC）的活化下,该催化体系引发丁二烯单体聚合,得到顺式-1,4结构含量高达98%的聚丁二烯。 催化剂催化活性随配体上取代基吸电子能力的增加而提高,但随取代基空间位阻的增加而降低。 所合成的聚丁二烯具有高相对分子质量(Mn约为2.0×105)和窄的相对分子质量分布（Mw/Mn＜2.7）。     

带有控制输入扰动和死区的混沌系统自适应模糊控制

针对带有非线性输入和控制增益矩阵扰动的未知时变时滞混沌系统,提出了一种自适应模糊变结构控制方法.设计的控制器可以保证跟踪误差收敛到原点的可调邻域内,并且闭环系统所有信号有界.该方法对系统扰动的变化能保持较好的鲁棒性.最后以多卷波混沌系统为例的仿真实验进一步验证了该方法的有效性.     

Mechanical properties of silicon nanobeams with undercut evaluated by combining dynamic resonance test and finite element analysis

Mechanical properties of silicon nanobeams are of prime importance in nanoelectromechanical system applications. A numerical experimental method of determining resonant frequencies and Young's modulus of nanobeams by combining finite element analysis and frequency response tests based on an electrostatic excitation and visual detection by laser Doppler vibrometer is presented in this paper. Silicon nanobeams test structures are fabricated from silicon-on-insulator wafers by using a standard lithography and anisotropic wet etching release process, which inevitably generates the undercut of the nanobeam clamping. In conjunction with three-dimensional finite element numerical simulations incorporating the geometric undercut, dynamic resonance tests reveal that the undercut significantly reduces resonant frequencies of nanobeams due to the fact that it effectively increases the nanobeam length by a correct value Δ L, which is a key parameter that is correlated with deviations in the resonant frequencies predicted from the ideal Euler-Bernoulli beam theory and experimentally measured data. By using a least-square fit expression including Δ L, we finally extract Young's modulus from the measured resonance frequency versus effective length dependency and find that Young's modulus of silicon nanobeam with 200-nm thickness is close to that of bulk silicon. This result supports that the finite size effect due to surface effect does not play a role in mechanical elastic behaviour of silicon nanobeams with the thickness larger than 200 nm.     

Adaptive fuzzy synchronization for a class of fractional-order neural networks

In this paper, synchronization for a class of uncertain fractional-order neural networks with external disturbances is discussed by means of adaptive fuzzy control. Fuzzy logic systems, whose inputs are chosen as synchronization errors,are employed to approximate the unknown nonlinear functions. Based on the fractional Lyapunov stability criterion, an adaptive fuzzy synchronization controller is designed, and the stability of the closed-loop system, the convergence of the synchronization error, as well as the boundedness of all signals involved can be guaranteed. To update the fuzzy parameters,fractional-order adaptations laws are proposed. Just like the stability analysis in integer-order systems, a quadratic Lyapunov function is used in this paper. Finally, simulation examples are given to show the effectiveness of the proposed method.     

波动数值模拟的一种显式方法——二维波动

将一维波动时域数值模拟的一种显式方法推广到二维,导出了二维非规则网格的节点递推公式.针对均匀正方形网格详细论述了时空精度皆为2M阶(M为正整数)的稳定递推公式的构建方法,并以构建二阶(M = 1)和四阶(M = 2)公式为例予以说明. 最后,通过算例检验了本文研究结果,特别是说明了高阶公式对提高计算效率的价值.      

一类自守L函数的零点密度估计

考虑了带特征的Mass形式的自守L函数的零点密度估计问题.证明了L(s,fχ)的零点密度估计具有下面的形式:∑χN(σ,T,χ)(qT)A(σ)(1－σ)+ε.     

三溴偶氮溴膦（4—BPA—TB）与铋显色反应研究及分析上应用

本文报道了三溴偶氮溴膦(4-BPA-TB)与Bi(Ⅲ)的显色反应.研究结果表明:在高氯酸介质中,乙醇存在下,该试剂与Bi(Ⅲ)形成稳定的蓝紫色配合物,配合比为1:2,其最大吸收波长为644nm,表观摩尔吸光系数为1.0×10~5,Bi(Ⅲ)0～20μg/25ml范围内符合比耳定律.将该方法用于铸铁及紫铜样品中微量铋的测定,获得了满意的结果.     

在线轨面伤损检测软件系统优化设计与实现

针对实际应用中轨面伤损检测系统检测速度较慢的问题,在保证检测精度的前提下,结合轨面图像特点及软件工程的思想,提出了面向算法、编程技术和存储介质3个层面的优化方法。算法优化通过重新设计算法流程,合理取舍步骤,实现算法到CPU的高效映射;编程技术优化使用多线程编程,通过并行运算充分利用处理器的多核优势;存储介质优化通过使用读写快、质量轻、能耗低、体积小的固态硬盘进行图像读写,有效地提升了硬件效率。实验结果表明,优化后平均每幅轨面图像检测耗时由17.94 ms降低到仅8.33 ms,速度提升了53.57%,在分辨率为1 mm的精度下换算成车速约为207 km/h,可以满足铁路轨面伤损在线检测需求。