聚氨酯泡沫无卤阻燃研究进展

聚氨酯泡沫塑料是用量最大的泡沫材料之一，具有低密度、高强度、耐腐蚀、高隔热等优点，广泛应用于防震、减震、软性衬垫材料和建筑隔热保温等多个领域.然而，聚氨酯泡沫高度易燃，燃烧时伴随大量热和有毒烟气释放，对人民生命财产安全造成严重威胁.传统的含卤阻燃由于生物毒性及环境累积性受到严重限制，无卤阻燃已成为聚氨酯泡沫阻燃的发展趋势.本文介绍了聚氨酯泡沫的燃烧特点及阻燃机理，从添加型、反应型和表面后处理的不同阻燃方式阐述了聚氨酯泡沫无卤阻燃的研究进展，并深入分析了这些研究对泡沫阻燃的贡献、作用机理及关键影响因素，最后对聚氨酯泡沫的阻燃研究前景进行了展望，环境友好、高效、高阻燃抑烟、可循环回收是聚氨酯泡沫阻燃未来发展的重要方向.     

Influence on photonic crystal fiber dispersion of the size of air holes in different rings within the cladding

The influence on photonic crystal fiber dispersion of the size of air holes in different rings within thecladding is investigated using a semivectorial finite difference method.Numerical results reveal that thephotonic crystal fiber dispersion is more sensitive to the variation of the air hole size in the first and secondrings,indicating that design of photonic crystal fibers with desirable dispersion properties requires moreprecise control of the paxameters of the air holes in the vicinity of the fiber core.     

基于图像处理的频域有限差分法用于实际光子晶体光纤的研究

提出了一种基于图像处理算法和频域有限差分法相结合研究实际光子晶体光纤的数值分析方法.该方法针对实际光子晶体光纤由于结构不规则难以进行数值分析的缺点.采取首先对光子品体光纤的电镜扫描图像使用阈值分割和维纳滤波等图像处理算法获得光纤截面的几何网像.然后使用图像插值及构造均值移动窗口滤波等方法实现了网格划分和介电系数平均等步骤,最后结合频域有限差分法对光纤特性进行分析计算.结果表明,该方法能够精确分析实际光子晶体光纤的色散特性.模拟得到的实际光子晶体光纤的模场分布与实验结果吻合很好.     

Generation of few-cycle laser pulses by coherent synthesis based on a femtosecond Yb-doped fiber laser amplification system

We demonstrate a coherent synthesis system based on femtosecond Yb-doped fiber laser technology. The output pulse of the amplification system is divided into two replicas and seeded into photonic crystal fibers of two parallel branches for nonlinear pulse compression. Because of the different nonlinear dynamics in the photonic crystal fibers, the compressed pulses show different spectra, which can be spliced to form a broad coherent spectrum. The integrated timing jitter between the pulses of two branches is less than one tenth of an optical cycle.By coherently synthesizing pulses from these two branches, 8 fs few-cycle pulses are produced.     

高电荷态类锂等电子序列(Z=31~40)1s22p态能级结构的理论计算

利用多组态Dirac-Fock方法,本文研究了高电荷态类锂等电子序列（Z=31~40）离子1s22p激发态的精细结构. 考虑高关联轨道的电子关联影响以及Breit相互作用、量子电动力学效应和原子核运动效应等高阶修正,计算了2P1/2和2P3/2精细能级的本征能量,能级劈裂结果与已有理论计算一致. 结果表明,类锂离子1s22p态精细结构劈裂满足高电荷态的等电子序列标度规律（~ Z4）;发现离子空间尺寸随着原子序数增加收缩,相对论轨道1s1/2和2p3/2的径向电荷密度分布趋向于原子核.     

舱内爆炸角隅汇聚反射冲击波超压特性研究

为研究密闭舱室内爆角隅汇聚反射冲击波超压特性,利用缩比模型进行了某典型舱室内爆试验,得到远离角隅、两面角隅和三面角隅处的冲击波载荷,结合数值模拟研究了3种特征位置处冲击波传播规律及载荷特征。研究结果表明:远离角隅处壁面反射冲击波超压曲线呈现单峰结构,反射冲击波以球面波传播;距两面角隅一定范围内冲击波超压曲线呈现双峰结构,两面角隅冲击波超压曲线呈现单峰结构,角隅汇聚反射冲击波以椭球状传播;距三面角隅一定范围内冲击波超压曲线呈现多峰结构,三面角隅冲击波超压曲线呈现单峰结构,角隅汇聚反射冲击波以球面波传播;在合理假设条件下,根据量纲分析及数值模拟结果,得到首次冲击时角隅汇聚反射冲击波载荷经验计算公式。     

光子晶体光纤中调制不稳定现象与超连续光谱的产生

研究了光子晶体光纤中调制不稳定性效应.从非线性薛定谔方程出发，计算和分析了光子晶体光纤中反常色散区以及正常色散区内的调制不稳定性现象，详细讨论了超短脉冲的脉宽、峰值功率、高阶色散和高阶非线性效应（如脉冲内喇曼散射、自陡峭效应）对调制不稳定性产生的影响.结果表明：二阶色散对调制不稳定性的影响要远大于三阶色散，同时也发现随着初始脉冲宽度的减小，调制不稳定性旁瓣增大但是强度有所降低.另外还发现高阶非线效应如自陡峭和喇曼效应会在不同程度上抑制调制不稳定性.     

Influence on photonic crystal fiber dispersion of the size of air holes in different rings within the cladding

The influence on photonic crystal fiber dispersion of the size of air holes in different rings within the cladding is investigated using a semivectorial finite difference method. Numerical results reveal that the photonic crystal fiber dispersion is more sensitive to the variation of the air hole size in the first and second rings, indicating that design of photonic crystal fibers with desirable dispersion properties requires more precise control of the parameters of the air holes in the vicinity of the fiber core.     

Numerical Simulation and Experimental Analysis of Photonic Band Gap in Hollow-Core Photonic Crystal Fibres

Based on the full-vector plane-wave method （FVPWM）, a hollow-core photonic crystal fibre （HC-PCF） fabricated by using the improved stack-and-draw technique is simulated. Under given propagation constants β, several effective photonie band gaps with different sizes emerge within the visible wavelength range from 575 to 720 nm. The fundamental mode and second-order mode lying in a part of PBGs are investigated. In the transmission spectrum tested, the positions of PBGs are discovered to be shifting to shorter wavelengths. The main reason is the existence of interstitial holes at nodes in the cladding region. In the later experiment, green light is observed propagating in the air-core region, and the result is more consistent with our theoretical simulation.     

亚百飞秒高功率掺镱大模面积光子晶体光纤飞秒激光放大器的实验研究

实验研究了掺镱双包层保偏大模面积光子晶体光纤飞秒激光放大器. 获得了平均功率达16W的飞秒激光放大输出,在50MHz重复频率下,对应的单脉冲能量达到320nJ. 增益光纤长3.5m,由于自相位调制效应,种子光脉冲光谱在放大过程中同时展宽,从而支持更窄的脉冲宽度. 经过光栅后,脉冲宽度压缩到了85fs. 系统中的振荡器和放大器基于同一种具有偏振结构的大模面积光子晶体光纤,具有很好的环境稳定性和进一步集成的可能. 关键词： 光子晶体光纤 大模场面积光纤 飞秒激光 光纤放大器