高阶非保守系统的2π-周期解

本文利用L~2-空间中的紧嵌入性质和 Schauder不动点原理,讨论了高阶n-维非保守系统: x~(k+1)+sum from j=1 to k (D_jx~(j)+g(t,x,x’,…,x~((m)))=p(t)2π-周期解的存在性问题。所得结果限制在k=1,m=0时,推广了文[1,2]中的相应结论。     

The interstellar methanol masers and their environments

To promote the understanding of massive star formation processes, we have studied the 6.6 GHz methanol (CH3OH) masers and their environments-- the dense cores and the outer regions of the molecular cloud. The physics of the CH3OH maser or the thermal emission formation region is studied by fitting the observational data of the 6.6 GHz 51-60 A+ and the 107 GHz 31-40 A+ CH3OH maser emission, using the radiative transfer calculations. The type II characteristics of the 6.6 GHz CH3OH maser are confirmed by the calculation results. A greater intensity of the radiation field leads to an increase in the peak intensity of the maser; however, high densities tend to turn off the maser. The calculation results show that to be a maser the 6.6 GHz CH3OH emission needs a radiation field of 150-300 K and a density not higher than 107cm-3, while the 107 GHz emission requires a radiation field of 210-300 K and a density not higher than 3×106 cm-3. The 6.6 GHz line is maser towards all six studied sources, while the 107 GHz line is maser towards Cep A only. Moreover, the former's intensity is much stronger than the latter. The radiative transfer calculations also indicate that the 6.6 GHz maser emission is so strong that the requirements of its formation (e.g. The radiation field, the density and the kinetic parameters) can only be satisfied at a certain stage of the processes of the massive star formation. Therefore it is often used as one of the most prominent tracers for the massive star formation regions. The calculation results of the simultaneous observations of (1,1) through (4,4) inversion lines of the ammonia (NH3) indicate that both the temperature and the density in the 6.6 GHz CH3OH maser formation regions are higher than that of the NH3 line formation regions. Furthermore, the common fact of |Vlsr(CO)| ＞ |Vlsr(NH3)| ＞ |Vlsr(CH3OH 6.6GHz maser)| in all six sources implies the ongoing developing trends of those gas flows driven by the masers.     

Synthesis of Covalently-linked Linear Donor-Acceptor Copolymers Containing Porphyrins and Oligothiophenes

The construction of macro-molecular system containing multiple redox centers or photosensitizers is aimportant subject in the design of molecular electronidevices.1,2 For such objectives, systematization of donor-redox center-acceptor triad molecules into largmolecular systems is one of the most feasible approaches, because the exquisite incorporation of thphotosensitizers and suitable electron donors and/oacceptors into a polymeric chain is useful for varioumolecular electronic systems.3-5 Th…     

豆荚内酯A的晶体结构和分子结构

本文报道软珊瑚提取物豆荚内酯 A 的晶体结构和分子结构.分子式为 C_(22)H_(30)O_5,M_r=374.5,晶体属正交晶系,空间群为,P2_12_12_1,a=8.753(2),b=8.887(3),c=54.247(14)(?),V=4220(2)(?)~3,Z=8,D_x=1.17Mg·m~(-3),F(000)=1616e.强度数据用 Cu Kα辐射、四圆衍射仪收集,结构用直接法解出.经最小二乘法修正,其偏离因子 R=0.064.分子骨架由无规则的[-+-+-++++-+--]型十三环二烯和“信封式”γ-内酯环组成,两者以顺式稠合.不对称单位两个分子构型基本相同.晶胞中分子堆积较疏松.     

大孔树脂分离纯化楮果总黄酮优化工艺研究

筛选适合分离纯化楮果总黄酮的大孔树脂并确定最优工艺条件。以静态吸附率和解吸率为指标对8种大孔树脂进行筛选,确定D101树脂的分离纯化效果最佳。通过动态吸附实验考察上样流速、上样溶液pH值、上样溶液浓度、乙醇浓度、洗脱流速、洗脱剂用量等工艺条件对分离纯化效果的影响,确定最优工艺条件如下:上样流速为2BV/h,pH值为6,上样溶液浓度为0.05mg/mL,80%乙醇作洗脱剂,洗脱流速为5BV/h,洗脱剂用量为7.5BV。采用最优工艺条件,楮果总黄酮含量提高至22.26%,产品精制倍数为4.79,表明D101树脂能有效纯化楮果总黄酮。     

分馏萃取分离稀土的数学模拟—HEH(EHP)-煤油-HNO3-(Sm-Gd)(NO3)3体系

进行了HEH(EHP)-煤油-HNO₃-(Sm-Gd)(NO₃)₃体系的萃取平衡实验与分馏萃取实验。串级实验得到了水相出口Sm的纯度为96.7%,有机相出口Gd的纯度>99%的结果。应用萃取平衡实验数据建立了计算简便、精度较高的半经验两相分配模型: H_i3^aXj_i4^aYj_i5^a(i,j=1,2)。给出了由各级平衡分配模型和物料衡算式组成的非线性方程组—串级模型。介绍了模拟计算所用的矩阵解法及其FORTRAN程序,计算所得各级金属离子浓度、水相酸度、以及自由萃取剂浓度的分布与实验值符合程度较高。     

光电联合催化的研究进展

近年来,温和、绿色的光化学和电化学反应在有机合成中得到了广泛的应用.为了进一步提升光、电反应潜力,有机化学家们致力于在单一反应体系中使用这两种策略来促进有机转化.一系列光电联合催化策略被开发出来,目前主要的光电联合催化策略是电化学介导的光氧化还原催化.此外,光激发辅助、电化学主导氧化还原的光电联合催化策略也逐渐展现出其...     

HEH(EHP)-煤油-HCl-RECl_3体系单一稀土的萃取平衡

HEH(EHP)(2-乙基己基膦酸单2-乙基己基酯)作为萃取剂,萃取分离稀土的研究结果表明,HEH(EHP)有较高的分离系数,是一种有效的稀土分离萃取剂。为深入了解HEH(EHP)对稀土元素的萃取性能,以便提供萃取分离工艺的设计参数,我们研究了HEH(EHP)-煤油-HCl-RECl_3体系在不同初始条件下,15个单一稀土的萃取平衡数据,